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Volume 47
Main Index

Issue 1


Multiple Charge-Transfer Emissions from Different Metal-Ligand Pairs in Ruthenium Diimines
José L. Zambrana, Jr., Elena X. Ferloni, Julie C. Colis, and Harry D. Gafney
pp 2 - 4; DOI:
10.1021/ic700837u
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Xenon Difluoride Induced Aryl Iodide Reductive Elimination: a Simple Access to Difluoropalladium(II) Complexes
Ariela W. Kaspi, Anette Yahav-Levi, Israel Goldberg, and Arkadi Vigalok
pp 5 - 7; DOI:
10.1021/ic701722f
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Diastereomerically Enriched Analogues of the Water-Soluble Phosphine PTA. Synthesis of Phenyl(1,3,5-triaza-7-phosphatricyclo[3.3.1.13,7]dec-6-yl)methanol (PZA) and the Sulfide PZA(S) and X-ray Crystal Structures of the Oxide PZA(O) and [Cp*IrCl2(PZA)]
Mikael Erlandsson, Luca Gonsalvi, Andrea Ienco, and Maurizio Peruzzini
pp 8 - 10; DOI:
10.1021/ic701795y
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Expanded Sodalite-Type Metal-Organic Frameworks: Increased Stability and H2 Adsorption through Ligand-Directed Catenation
Mircea Dinc, Anne Dailly, Charlene Tsay, and Jeffrey R. Long
pp 11 - 13; DOI:
10.1021/ic701917w
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First Correlation of Nanoparticle Size-Dependent Formation with the Ionic Liquid Anion Molecular Volume
Engelbert Redel, Ralf Thomann, and Christoph Janiak
pp 14 - 16; DOI:
10.1021/ic702071w
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Characterization of Platinum Anticancer Drug Protein-Binding Sites Using a Top-Down Mass Spectrometric Approach
Christian G. Hartinger, Yury O. Tsybin, Jens Fuchser, and Paul J. Dyson
pp 17 - 19; DOI:
10.1021/ic702236m
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A Three-Dimensional Open-Framework Indium Selenide: [C7H10N][In9Se14]
Paz Vaqueiro
pp 20 - 22; DOI:
10.1021/ic701995p
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Synthesis of a New Ligand for Transition Metal-Fullerene Supramolecular Systems
Joel R. Deye, Amber N. Shiveley, Sean M. Goins, Lauren Rizzo, Stuart A. Oehrle, and Keith A. Walters
pp 23 - 25; DOI:
10.1021/ic7018555
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Structural Characterization of Pu[N(SiMe3)2]3, a Synthetically Useful Nonaqueous Plutonium(III) Precursor
Andrew J. Gaunt, Alejandro E. Enriquez, Sean D. Reilly, Brian L. Scott, and Mary P. Neu
pp 26 - 28; DOI:
10.1021/ic701673e
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Experimental and Theoretical Comparison of Actinide and Lanthanide Bonding in M[N(EPR2)2]3 Complexes (M = U, Pu, La, Ce; E = S, Se, Te; R = Ph, iPr, H)
Andrew J. Gaunt, Sean D. Reilly, Alejandro E. Enriquez, Brian L. Scott, James A. Ibers, Perumal Sekar, Kieran I. M. Ingram, Nikolas Kaltsoyannis, and Mary P. Neu
pp 29 - 41; DOI:
10.1021/ic701618a
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Electron-Structure Calculations and Bond Order Analysis Using Density Functional Theory of Cationic Dinuclear Arene Ruthenium Complexes
Emmanuel Penka Fowe, Bruno Therrien, Georg Süss-Fink, and Claude Daul
pp 42 - 48; DOI:
10.1021/ic7007914
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Bluish-White Emission from Radical Carbonyl Impurities in Amorphous Al2O3 Prepared via the Pechini-Type Sol-Gel Process
Cuikun Lin, Min Yu, Ziyong Cheng, Cuimiao Zhang, Qingguo Meng, and Jun Lin
pp 49 - 55; DOI:
10.1021/ic700652v
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Mechanistic Investigation of -Galactosidase-Activated MR Contrast Agents
Lauren M. Urbanczyk-Pearson, Frank J. Femia, Jeffrey Smith, Giacomo Parigi, Joseph A. Duimstra, Amanda L. Eckermann, Claudio Luchinat, and Thomas J. Meade
pp 56 - 68; DOI:
10.1021/ic700888w
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Synthesis and Structural Characterization of a New Vapochromic Pt(II) Complex Based on the 1-Terpyridyl-2,3,4,5,6-pentaphenylbenzene (TPPPB) Ligand
Pingwu Du, Jacob Schneider, William W. Brennessel, and Richard Eisenberg
pp 69 - 77; DOI:
10.1021/ic700947g
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Epoxidation and 1,2-Dihydroxylation of Alkenes by a Nonheme Iron Model System - DFT Supports the Mechanism Proposed by Experiment
Peter Comba and Gopalan Rajaraman
pp 78 - 93; DOI:
10.1021/ic701161r
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Syntheses, Structure, and a Mössbauer and Magnetic Study of Ba4Fe2I5S4
Danielle L. Gray, Gary J. Long, Fernande Grandjean, Raphaël P. Hermann, and James A. Ibers
pp 94 - 100; DOI:
10.1021/ic701085c
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Zinc Carboxylate Cluster Formation in Conjugated Metallomacrocycles: Evidence for Templation
Peter D. Frischmann, Amanda J. Gallant, Jonathan H. Chong, and Mark J. MacLachlan
pp 101 - 112; DOI:
10.1021/ic701385m
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Molybdenum Oxo and Imido Complexes of -Diketiminate Ligands: Synthesis and Structural Aspects
Ganna Lyashenko, Regine Herbst-Irmer, Vojtech Jancik, Aritra Pal, and Nadia C. Mösch-Zanetti
pp 113 - 120; DOI:
10.1021/ic701534a
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Solventless Nanoparticles Synthesis under Low Pressure
Hyun Gil Cha, Don Keun Lee, Young Hwan Kim, Chang Woo Kim, Chung Sup Lee, and Young Soo Kang
pp 121 - 127; DOI:
10.1021/ic701570z
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Analysis of the Spin Lattice Model for the Spin-Gapped Layered Compounds Na3Cu2SbO6 and Na2Cu2TeO6 on the Basis of Electronic Structure Calculations
Hyun-Joo Koo and Myung-Hwan Whangbo
pp 128 - 133; DOI:
10.1021/ic701153z
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A Systematic Density Functional Study of the Zero-Field Splitting in Mn(II) Coordination Compounds
Samir Zein, Carole Duboc, Wolfgang Lubitz, and Frank Neese
pp 134 - 142; DOI:
10.1021/ic701293n
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Study of Neutral Fe(III) Complexes of Pyridoxal-N-Substituted Thiosemicarbazone with Desolvation-Induced Spin-State Transformation above Room Temperature
Eddy W. Yemeli Tido, Gert O. R. Alberda van Ekenstein, Auke Meetsma, and Petra J. van Koningsbruggen
pp 143 - 153; DOI:
10.1021/ic701695b
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Cobalt Coordination Induced Functionalized Molecular Clefts: Isolation of {CoIII-ZnII} Heterometallic Complexes and Their Applications in Beckmann Rearrangement Reactions
Anurag Mishra, Afsar Ali, Shailesh Upreti, and Rajeev Gupta
pp 154 - 161; DOI:
10.1021/ic7016424
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Self-Assembled Copper(II) Coordination Polymers Derived from Aminopolyalcohols and Benzenepolycarboxylates: Structural and Magnetic Properties
Alexander M. Kirillov, Yauhen Y. Karabach, Matti Haukka, M. Fátima C. Guedes da Silva, Joaquin Sanchiz, Maximilian N. Kopylovich, and Armando J. L. Pombeiro
pp 162 - 175; DOI:
10.1021/ic701669x
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Coordination "Oligomers" in Self-Assembly Reactions of Some "Tritopic" Picolinic Dihydrazone Ligands-Mononuclear, Dinuclear, Hexanuclear, Heptanuclear, and Nonanuclear Examples
Virginie Niel, Victoria A. Milway, Louise N. Dawe, Hilde Grove, Santokh S. Tandon, Tareque S. M. Abedin, Timothy L. Kelly, Elinor C. Spencer, Judith A. K. Howard, Julie L. Collins, David O. Miller, and Laurence K. Thompson
pp 176 - 189; DOI:
10.1021/ic7016787
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Hydrothermal Synthesis, Structures, and Photoluminescent Properties of Benzenepentacarboxylate Bridged Networks Incorporating Zinc(II)-Hydroxide Clusters or Zinc(II)-Carboxylate Layers
Jing Wang, Zhuojia Lin, Yong-Cong Ou, Nai-Liang Yang, Yue-Hua Zhang, and Ming-Liang Tong
pp 190 - 199; DOI:
10.1021/ic701721t
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Luminescent Biological Probes Derived from Ruthenium(II) Estradiol Polypyridine Complexes
Kenneth Kam-Wing Lo, Terence Kwok-Ming Lee, Jason Shing-Yip Lau, Wing-Lin Poon, and Shuk-Han Cheng
pp 200 - 208; DOI:
10.1021/ic701735q
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Helicates, Boxes, and Polymers from Simple Pyridine-Alcohol Ligands: the Impact of the Identity of the Transition Metal Ion
Shane G. Telfer, Nyree D. Parker, Reiko Kuroda, Takunori Harada, Julie Lefebvre, and Daniel B. Leznoff
pp 209 - 218; DOI:
10.1021/ic701757e
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Very Large Difference in Electronic Communication of Dimetal Species with Heterobiphenylene and Heteroanthracene Units
F. Albert Cotton, Carlos A. Murillo, Mark D. Young, Rongmin Yu, and Qinliang Zhao
pp 219 - 229; DOI:
10.1021/ic701937c
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Shorter Argentophilic Interaction than Aurophilic Interaction in a Pair of Dimeric {(NHC)MCl}2 (M = Ag, Au) Complexes Supported over a N/O-Functionalized N-Heterocyclic Carbene (NHC) Ligand
Lipika Ray, Mobin M. Shaikh, and Prasenjit Ghosh
pp 230 - 240; DOI:
10.1021/ic701830m
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Carbon Monoxide Coordination and Reversible Photodissociation in Copper(I) Pyridylalkylamine Compounds
H. Christopher Fry, Heather R. Lucas, Amy A. Narducci Sarjeant, Kenneth D. Karlin, and Gerald J. Meyer
pp 241 - 256; DOI:
10.1021/ic701903h
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High-Valent Technetium Complexes with the [99TcO3]+ Core from in Situ Prepared Mixed Anhydrides of [99TcO4]- and Their Reactivities
Yuji Tooyama, Henrik Braband, Bernhard Spingler, Ulrich Abram, and Roger Alberto
pp 257 - 264; DOI:
10.1021/ic701908q
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Lithium-Alkyl, -Aryl, and -Amido Ligand-Exchange Dynamics of Dianionic Zirconium(IV) Complexes with Chelating Amidophenolate Ligands
Karen J. Blackmore, Joseph W. Ziller, and Alan F. Heyduk
pp 265 - 273; DOI:
10.1021/ic701112x
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Synthesis, Characterization, and in Vitro Evaluation of a Potentially Selective Anticancer, Mixed-Metal [Ruthenium(III)-Platinum(II)] Trinuclear Complex
Amnon Herman, Joseph M. Tanski, Michael F. Tibbetts, and Craig M. Anderson
pp 274 - 280; DOI:
10.1021/ic062419h
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Halogen Exchange and Scrambling between C-X and M-X' Bonds in Copper, Nickel, and Cobalt Complexes of 6,6'-bis(bromo/ chloromethyl)-2,2'-bipyridine. Structural, Electrochemical, and Photochemical Studies
Meenakshi Ghosh, Papu Biswas, Ulrich Flörke, and Kamalaksha Nag
pp 281 - 296; DOI:
10.1021/ic7014786
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Ternary Rare-Earth Manganese Bismuthides: Structures and Physical Properties of RE3MnBi5 (RE = La-Nd) and Sm2Mn3Bi6
Oksana Ya. Zelinska and Arthur Mar
pp 297 - 305; DOI:
10.1021/ic701428p
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Heterometallic Cuboidal Clusters M3M'Q4 (M = Mo, W; M'= Sn, Pb, As, Sb; Q = S, Se): From Coordination Compounds to Supramolecular Adducts
Rita Hernández-Molina, Irina V. Kalinina, Pavel A. Abramov, Maxim N. Sokolov, Alexandr V. Virovets, Javier G. Platas, Rosa Llusar, Victor Polo, Cristian Vicent, and Vladimir P. Fedin
pp 306 - 314; DOI:
10.1021/ic701581u
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Structural Alternatives for the Formation of Halogenophosphine-Phosphenium Complexes
Sebastian Burck and Dietrich Gudat
pp 315 - 321; DOI:
10.1021/ic7017049
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Exchange Interactions and Electron Delocalization in the Mixed-Valence Cluster V4IVV2VO7(OC2H5)12
Maria A. Augustyniak-Jabokow, Charles Daniel, Hans Hartl, Johann Spandl, and Yurii V. Yablokov
pp 322 - 332; DOI:
10.1021/ic7006974
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Proton-Coupled Electron Transfer in Ruthenium(II)-Pterin Complexes: Formation of Ruthenium-Coordinated Pterin Radicals and Their Electronic Structures
Soushi Miyazaki, Takahiko Kojima, Taisuke Sakamoto, Tetsuya Matsumoto, Kei Ohkubo, and Shunichi Fukuzumi
pp 333 - 343; DOI:
10.1021/ic701759c
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Growth of (WO3)n Rectangular Structures through a LMO-Organic Precursor Route
Shuping Pang, Fangfang Jian, and Lei Wang
pp 344 - 348; DOI:
10.1021/ic701481z
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Comparative Studies on Exchange Reactions of Hexafluoroacetylacetonate in Bis(hexafluoroacetylacetonato)(dimethyl sulfoxide)dioxouranium(VI) in Nonaqueous Solvent and Supercritical CO2
Yoshihiro Kachi, Yoshihito Kayaki, Takehiko Tsukahara, Takao Ikariya, and Yasuhisa Ikeda
pp 349 - 359; DOI:
10.1021/ic701234q
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Preparation and Characterization of Dendrimer-Templated Ag-Cu Bimetallic Nanoclusters
Guoping Li and Yunjun Luo
pp 360 - 364; DOI:
10.1021/ic701090c
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Reactivity of Niobium and Tantalum Pentahalides with Cyclic Ethers and the Isolation and Characterization of Intermediates in the Polymerization of Tetrahydrofuran
Fabio Marchetti, Guido Pampaloni, and Stefano Zacchini
pp 365 - 372; DOI:
10.1021/ic7012254
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First-Row Transition Metal-Halide Complexes Supported by a Monoanionic [N2P2] Ligand
Wayne A. Chomitz, Seth F. Mickenberg, and John Arnold
pp 373 - 380; DOI:
10.1021/ic701670u
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Reactivity and Catalytic Activity of a Robust Ruthenium(II)-Triphos Complex
Adrian B. Chaplin and Paul J. Dyson
pp 381 - 390; DOI:
10.1021/ic701773a
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Issue 2


Facile Synthesis of Troilite
Nathalie M. Pedoussaut and Cora Lind
pp 392 - 394; DOI:
10.1021/ic701636h
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Coordination Chemistry of a Model for the GP Cofactor in the Hmd Hydrogenase: Hydrogen-Bonding and Hydrogen-Transfer Catalysis
Aaron M. Royer, Thomas B. Rauchfuss, and Scott R. Wilson
pp 395 - 397; DOI:
10.1021/ic7018692
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Synthesis of Ordered Ultrathin ZnO Nanowire Bundles on an Indium-Tin Oxide Substrate
Fang Fang, Dongxu Zhao, Dezhen Shen, Jiying Zhang, and Binghui Li
pp 398 - 400; DOI:
10.1021/ic7019236
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Highly Effective DNA Photocleavage by Novel "Rigid" Ru(bpy)3-4-nitro- and -4-amino-1,8-naphthalimide Conjugates
Gary J. Ryan, Susan Quinn, and Thorfinnur Gunnlaugsson
pp 401 - 403; DOI:
10.1021/ic700967y
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Outer-Sphere Oxidation of the Superoxide Radical Anion
Ira A. Weinstock
pp 404 - 406; DOI:
10.1021/ic701885q
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Influence of the d-Electron Count on CO Binding by Three-Coordinate [(tBu2PCH2SiMe2)2N]Fe, -Co, and -Ni
Michael J. Ingleson, Benjamin C. Fullmer, Drew T. Buschhorn, Hongjun Fan, Maren Pink, John C. Huffman, and Kenneth G. Caulton
pp 407 - 409; DOI:
10.1021/ic7023764
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Creation of a Nonsymmetric Dimethanolpyridine Ligand: A Rare Zn(salphen) Template Effect
Eduardo C. Escudero-Adán, Jordi Benet-Buchholz, and Arjan W. Kleij
pp 410 - 412; DOI:
10.1021/ic702225h
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Self-assembly of Ligands Designed for the Building of a New Type of [2 × 2] Metallic Grid. Anion Encapsulation and Diffusion NMR Spectroscopy
Blanca R. Manzano, Félix A. Jalón, Isabel M. Ortiz, M. Laura Soriano, Felipe Gómez de la Torre, José Elguero, Miguel A. Maestro, Kurt Mereiter, and Tim D. W. Claridge
pp 413 - 428; DOI:
10.1021/ic701117a
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RhCl3-Assisted C-H and C-S Bond Scissions: Isomeric Self-Association of Organorhodium(III) Thiolato Complex. Synthesis, Structure, and Electrochemistry
Kausikisankar Pramanik, Ujjwal Das, Basab Adhikari, Deepak Chopra, and Helen Stoeckli-Evans
pp 429 - 438; DOI:
10.1021/ic7016006
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Spectroscopic and Theoretical Study of a Mononuclear Manganese(III) Complex Exhibiting a Tetragonally Compressed Geometry
Quirin Scheifele, Christoph Riplinger, Frank Neese, Hgni Weihe, Anne-Laure Barra, Fanni Juranyi, Andrei Podlesnyak, and Philip L. W. Tregenna-Piggott
pp 439 - 447; DOI:
10.1021/ic701665u
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Origin of Compressed Jahn-Teller Octahedra in Sterically Strained Manganese(III) Complexes
Philip L. W. Tregenna-Piggott
pp 448 - 453; DOI:
10.1021/ic700968q
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Routes to New Hafnium(IV) Tetraaryl Porphyrins and Crystal Structures of Unusual Phosphate-, Sulfate-, and Peroxide-Bridged Dimers
Alexander Falber, Louis Todaro, Israel Goldberg, Michael V. Favilla, and Charles Michael Drain
pp 454 - 467; DOI:
10.1021/ic700840j
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Syntheses, Crystal Structures, and Spectral Properties of a Series of 3,8-Bisphenyl-1,10-phenanthroline Derivatives: Precursors of 3,8-Bis(4-mercaptophenyl)-1,10-phenanthroline and Its Ruthenium(II) Complex for Preparing Nanocomposite Junctions with Gold Nanoparticles between 1 m Gap Gold Electrodes
Wei Huang, Gou Masuda, Seisuke Maeda, Hirofumi Tanaka, Takami Hino, and Takuji Ogawa
pp 468 - 480; DOI:
10.1021/ic701295q
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Strongly Luminescent Palladium(0) and Platinum(0) Diphosphine Complexes
Taro Tsubomura, Yasuhiro Ito, Satoshi Inoue, Yu Tanaka, Kenji Matsumoto, and Toshiaki Tsukuda
pp 481 - 486; DOI:
10.1021/ic700475z
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Cooperative Iron(II) Spin Crossover Complexes with N4O2 Coordination Sphere
Birgit Weber, Eike Kaps, Jan Weigand, Chiara Carbonera, Jean-François Létard, Klaus Achterhold, and Fritz G. Parak
pp 487 - 496; DOI:
10.1021/ic070067o
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Synthesis and Structural and Magnetic Characterization of Cobalt(II) Phosphonate Cage Compounds
Stuart Langley, Madeleine Helliwell, Roberta Sessoli, Simon J. Teat, and Richard E. P. Winpenny
pp 497 - 507; DOI:
10.1021/ic700984r
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Structural Phase Stability Studies on MBeH3 (M = Li, Na, K, Rb, Cs) from Density Functional Calculations
P. Vajeeston, P. Ravindran, and H. Fjellvåg
pp 508 - 514; DOI:
10.1021/ic7015897
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An Application of the "Coloring Problem": Structure-Composition-Bonding Relationships in the Magnetocaloric Materials LaFe13-xSix
Mi-Kyung Han and Gordon J. Miller
pp 515 - 528; DOI:
10.1021/ic701311b
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Supramolecular Isomerism with Polythreaded Topology Based on [Mo8O26]4- Isomers
Ya-Qian Lan, Shun-Li Li, Xin-Long Wang, Kui-Zhan Shao, Zhong-Min Su, and En-Bo Wang
pp 529 - 534; DOI:
10.1021/ic701463h
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Synthesis and Characterization of the Cycloheptatrienyl Tantalum "Mixed-Sandwich" Compounds (C5R5)Ta(C7H7)
Wontae Noh and Gregory S. Girolami
pp 535 - 542; DOI:
10.1021/ic7015963
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Covalent-like Interactions between Artificial Atoms inside Silver Supercrystals
Xun Wang, Jing Zhuang, Ziyang Huo, Shi Hu, and Yadong Li
pp 543 - 547; DOI:
10.1021/ic701811f
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Influence of the Electronics of the Phosphine Ligands on the H-H Bond Elongation in Dihydrogen Complexes
Saikat Dutta, Balaji R. Jagirdar, and Munirathinam Nethaji
pp 548 - 557; DOI:
10.1021/ic7016769
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Structural Phase Transition of Gd3RuO7
Nobuo Ishizawa, Kenji Tateishi, Saki Kondo, and Tsuyoshi Suwa
pp 558 - 566; DOI:
10.1021/ic701732d
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Three New Organically Templated 1D, 2D, and 3D Vanadates: Synthesis, Crystal Structures, and Characterizations
Yan Xu, Guangpeng Zhou, and Dunru Zhu
pp 567 - 571; DOI:
10.1021/ic701725h
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Antiferromagnetic Behavior Based on Quasi-Orthogonal MOs: Synthesis and Charaterization of a Cu3 Oxidase Model
Boris Le Guennic, Sarah Petit, Guillaume Chastanet, Guillaume Pilet, Dominique Luneau, Nadia Ben Amor, and Vincent Robert
pp 572 - 577; DOI:
10.1021/ic701758x
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Ferrocenoyl Pyridine Arene Ruthenium Complexes with Anticancer Properties: Synthesis, Structure, Electrochemistry, and Cytotoxicity
Mathieu Auzias, Bruno Therrien, Georg Süss-Fink, Petr tpnika, Wee Han Ang, and Paul J. Dyson
pp 578 - 583; DOI:
10.1021/ic7018742
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Tetra- and Dinuclear Nickel(II)-Vanadium(IV/V) Heterometal Complexes of a Phenol-Based N2O2 Ligand: Synthesis, Structures, and Magnetic and Redox Properties
Debdas Mandal, Pabitra Baran Chatterjee, Rakesh Ganguly, Edward R. T. Tiekink, Rodolphe Clérac, and Muktimoy Chaudhury
pp 584 - 591; DOI:
10.1021/ic701925j
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Ag(I)-Based Tectons for the Construction of Helical and meso-Helical Hydrogen-Bonded Coordination Networks
David A McMorran
pp 592 - 601; DOI:
10.1021/ic701919r
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Rhenium(I) Polypyridine Biotin Isothiocyanate Complexes as the First Luminescent Biotinylation Reagents: Synthesis, Photophysical Properties, Biological Labeling, Cytotoxicity, and Imaging Studies
Kenneth Kam-Wing Lo, Man-Wai Louie, Ka-Shing Sze, and Jason Shing-Yip Lau
pp 602 - 611; DOI:
10.1021/ic701675c
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Insertion of CO2, Ketones, and Aldehydes into the C-Li Bond of 1,3,5-Triaza-7-phosphaadamantan-6-yllithium
Gene W. Wong, Wei-Chih Lee, and Brian J. Frost
pp 612 - 620; DOI:
10.1021/ic701936x
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Unusual Structural Types in Manganese Cluster Chemistry from the Use of N,N,N',N'-Tetrakis(2-hydroxyethyl)ethylenediamine: Mn8, Mn12, and Mn20 Clusters
Rashmi Bagai, Khalil A. Abboud, and George Christou
pp 621 - 631; DOI:
10.1021/ic701971d
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Coupling of CpCr(CO)3 and Heterocyclic Dithiadiazolyl Radicals. Synthetic, X-ray Diffraction, Dynamic NMR, EPR, CV, and DFT Studies
Hiu Fung Lau, Pearly Chwee Ying Ang, Victor Wee Lin Ng, Seah Ling Kuan, Lai Yoong Goh, Alexey S. Borisov, Paul Hazendonk, Tracey L. Roemmele, René T. Boeré, and Richard D. Webster
pp 632 - 644; DOI:
10.1021/ic702128f
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Synthesis, Characterization, and Study of Octanuclear Iron-Oxo Clusters Containing a Redox-Active Fe4O4-Cubane Core
Peter Baran, Roman Boa, Indranil Chakraborty, John Giapintzakis, Radovan Herchel, Qing Huang, John E. McGrady, Raphael G. Raptis, Yiannis Sanakis,O, and Athanasios SimopoulosO
pp 645 - 655; DOI:
10.1021/ic7020337
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Detailed Spectroscopic, Thermodynamic, and Kinetic Characterization of Nickel(II) Complexes with 2,2'-Bipyridine and 1,10-Phenanthroline Attained via Equilibrium-Restricted Factor Analysis
Douglas A. Vander Griend,, Daniel Kwabena Bediako, Michael J. DeVries, and Nathan A. DeJong
pp 656 - 662; DOI:
10.1021/ic700553d
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Structure of (NH4)3GaF6 Investigated by Multinuclear Magic-Angle Spinning NMR Spectroscopy in Comparison with Rietveld Refinement
Thoralf Krahl, Mike Ahrens, Gudrun Scholz, Detlef Heidemann, and Erhard Kemnitz
pp 663 - 670; DOI:
10.1021/ic700604s
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Template-Assisted Synthesis of Shape-Controlled Rh2P Nanocrystals
Amanda E. Henkes and Raymond E. Schaak
pp 671 - 677; DOI:
10.1021/ic701783f
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PbS Sub-micrometer Structures with Anisotropic Shape: Ribbons, Wires, Octapods, and Hollowed Cubes
M. Bashouti and E. Lifshitz
pp 678 - 682; DOI:
10.1021/ic700706a
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Synthesis and Thermal Chemistry of Copper (I) Guanidinates
Jason P. Coyle, Wesley H. Monillas, Glenn P. A. Yap, and Seán T. Barry
pp 683 - 689; DOI:
10.1021/ic701317y
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Lead and Aluminum Bonding in Pb-Al Metaphosphate Glasses
J. E. Tsuchida, J. Schneider, P. S. Pizani, and S. L. Oliveira
pp 690 - 698; DOI:
10.1021/ic701707a
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Lithography inside Cu(OH)2 Nanorods: A General Route to Controllable Synthesis of the Arrays of Copper Chalcogenide Nanotubes with Double Walls
Jun Xu, Weixin Zhang, Zeheng Yang, and Shihe Yang
pp 699 - 704; DOI:
10.1021/ic701448k
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Synthesis, Structure, and Infrared Spectroscopy of the First Np5+ Neptunyl Silicates, Li6(NpO2)4(H2Si2O7)(HSiO4)2(H2O)4 and K3(NpO2)3(Si2O7)
T. Z. Forbes and P. C. Burns
pp 705 - 712; DOI:
10.1021/ic701335j
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Photochemical Synthesis and Reactivity Studies of Dirhenacarboranes
Michael J. Carr, Thomas D. McGrath, and F. Gordon A. Stone
pp 713 - 722; DOI:
10.1021/ic701496x
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Interface Reaction Route to Two Different Kinds of CeO2 Nanotubes
Guozhu Chen, Caixia Xu, Xinyu Song, Wei Zhao, Yi Ding, and Sixiu Sun
pp 723 - 728; DOI:
10.1021/ic701867f
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Twofold Hydrogallation of CC Triple Bonds by H-GaCl2-Synthesis of Chelating Lewis Acids and Their Application in Adduct Formation
Werner Uhl and Michael Claesener
pp 729 - 735; DOI:
10.1021/ic701928s
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Study of Negative Thermal Expansion and Shift in Phase Transition Temperature in Ti4+- and Sn4+-Substituted ZrW2O8 Materials
Klaartje De Buysser, Isabel Van Driessche, Bart Vande Putte, Paul Vanhee, Joseph Schaubroeck, and Serge Hoste
pp 736 - 741; DOI:
10.1021/ic701660w
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Preparation of Benzyl Azide Complexes of Iridium(III)
Gabriele Albertin, Stefano Antoniutti, Daniela Baldan, Jesús Castro, and Soledad García-Fontán
pp 742 - 748; DOI:
10.1021/ic701907y
PDF
Nickel(II) Complexes Containing Bidentate Amido Phosphine Ligands Derived from -Iminophosphorus Ylides: Synthesis and Structural Characterization
Pei-Ying Lee and Lan-Chang Liang
pp 749 - 758; DOI:
10.1021/ic701836j
PDF

Issue 3


Azatricarbaborane 7-t-Bu-arachno-7,1,5,12-NC3B8H12 and Parent Tricarbaboranes nido-[5,6,9-C3B7H10]- and -5,6,9-C3B7H11
Josef Holub, Mario Bakardjiev, Drahomír Hnyk, Ivana Císaová, and Bohumil tíbr
pp 760 - 762; DOI:
10.1021/ic701568r
PDF
N-Oxides in Metal-Containing Multicomponent Molecular Complexes
Rupam Sarma, Anirban Karmakar, and Jubaraj B. Baruah
pp 763 - 765; DOI:
10.1021/ic701639n
PDF
Many Faces of Dipyrrins: from Hydrogen-Bonded Networks to Homo- and Heteronuclear Metallamacrocycles
Domingo Salazar-Mendoza, Stéphane A. Baudron, and Mir Wais Hosseini
pp 766 - 768; DOI:
10.1021/ic701949k
PDF
Doping-Induced Structure Variation of 1,3-Cyclohexane- Bis(methylamine)-Templated Zinc-Phosphorus Open Structures
Yang Yang, Yongnan Zhao, Jianguo Yu, Shizhen Wu, and Ruji Wang
pp 769 - 771; DOI:
10.1021/ic701825m
PDF
Multiferroic Homochiral Metal-Organic Framework
Qiong Ye, Da-Wei Fu, Hang Tian, Ren-Gen Xiong, Philip Wai Hong Chan, and Songping D. Huang
pp 772 - 774; DOI:
10.1021/ic701828w
PDF
A Luminescent and Magnetic Cyano-Bridged Tb3+-Mo5+ Coordination Polymer: toward Multifunctional Materials
Elena Chelebaeva, Joulia Larionova, Yannick Guari, Rute A. Sá Ferreira, Luis D. Carlos, Filipe A. Almeida Paz, Alexander Trifonov, and Christian Guérin
pp 775 - 777; DOI:
10.1021/ic702192k
PDF
Reversible Addition of Water to the High-Hydride-Content Cluster [Rh6(PiPr3)6H12][BArF4]2. Synthesis and Structure of [Rh6(PiPr3)6H11(OH)][BArF4]2
Thomas M. Douglas, Simon K. Brayshaw, Paul R. Raithby, and Andrew S. Weller
pp 778 - 780; DOI:
10.1021/ic702195b
PDF
Heterochiral Triangulo Nickel Complex as Evidence of a Large Positive Nonlinear Effect in Catalysis
John S. Fossey, Ryosuke Matsubara, Hiroshi Kiyohara, and Sh Kobayashi
pp 781 - 783; DOI:
10.1021/ic7017727
PDF
Reduction of CO2 to CO Using Low-Coordinate Iron: Formation of a Four-Coordinate Iron Dicarbonyl Complex and a Bridging Carbonate Complex
Azwana R. Sadique, William W. Brennessel, and Patrick L. Holland
pp 784 - 786; DOI:
10.1021/ic701914m
PDF
Six-Coordinate Nitrato Complexes of Iron(III) Porphyrins
Gurgen M. Gulyan, Tigran S. Kurtikyan, and Peter C. Ford
pp 787 - 789; DOI:
10.1021/ic702102j
PDF
Recipe for New Diorganostannates, [R2Sn(OS(O)2R1)4]2-, Bearing Alkanesulfonate Groups Using Dialkyl Sulfite as the Reagent
Ravi Shankar, Atul Pratap Singh, Mary F. Mahon, Kieran C. Molloy, Geeta Hundal, Monique Biesemans, and Rudolph Willem
pp 790 - 792; DOI:
10.1021/ic702099t
PDF
Colorimetric Fluoride Ion Sensing by Polyborylated Ferrocenes: Structural Influences on Thermodynamics and Kinetics
Joanna K. Day, Christopher Bresner, Natalie D. Coombs, Ian A. Fallis, Li-Ling Ooi, and Simon Aldridge
pp 793 - 804; DOI:
10.1021/ic701494p
PDF
The Role of Peripheral Alkyl Substituents: A Theoretical Study of Substituted and Unsubstituted Uranyl Isoamethyrin Complexes
Grigory A. Shamov and Georg Schreckenbach
pp 805 - 811; DOI:
10.1021/ic701192t
PDF
Synthesis, Structures, and Kinetics of Mixed-Donor Amido-Amino-Siloxo Ligands from Symmetrical Diamidosilyl Ether Ligands via a Retro-Brook Rearrangement
Farzad Haftbaradaran, Angela M. Kuchison, Michael J. Katz, Gabriele Schatte, and Daniel B. Leznoff
pp 812 - 822; DOI:
10.1021/ic701267a
PDF
Hybrid Structures Formed by Lead 1,3-Cyclohexanedicarboxylates
A. Thirumurugan, R. A. Sanguramath, and C. N. R. Rao
pp 823 - 831; DOI:
10.1021/ic701323q
PDF
Molybdophosphonate Clusters as Building Blocks in the Oxomolybdate-Organodiphosphonate/Cobalt(II)-Organoimine System: Structural Influences of Secondary Metal Coordination Preferences and Diphosphonate Tether Lengths
N. Gabriel Armatas, Damian G. Allis, Andrew Prosvirin, Gabriel Carnutu, Charles J. O'Connor, Kim Dunbar, and Jon Zubieta
pp 832 - 854; DOI:
10.1021/ic701573r
PDF
Syntheses, Crystal and Band Structures, and Magnetic and Optical Properties of New CsLnCdTe3 (Ln = La, Pr, Nd, Sm, Gd-Tm, and Lu)
Yi Liu, Ling Chen, Li-Ming Wu,, George H. Chan, and Richard P. Van Duyne
pp 855 - 862; DOI:
10.1021/ic7016402
PDF
Conducting Dimerized Cobalt Complexes with Tetrathiafulvalene Dithiolate Ligands
Emiko Fujiwara, Kazumasa Hosoya, Akiko Kobayashi, Hisashi Tanaka, Madoka Tokumoto, Yoshinori Okano, Hideki Fujiwara, Hayao Kobayashi, Yuichi Fujishiro, Eiji Nishibori, Masaki Takata, and Makoto Sakata
pp 863 - 874; DOI:
10.1021/ic701100r
PDF
Synthesis, Stability, and Complexation Behavior of Isolable Salen-Type N2S2 and N2SO Ligands Based on Thiol and Oxime Functionalities
Shigehisa Akine, Ayako Akimoto, Takuya Shiga, Hiroki Oshio, and Tatsuya Nabeshima
pp 875 - 885; DOI:
10.1021/ic701525c
PDF
Synthesis and Characterization of Novel Ferrocene-Containing Pyridylamine Ligands and Their Ruthenium(II) Complexes: Electronic Communication through Hydrogen-Bonded Amide Linkage
Takahiko Kojima, Daisuke Noguchi, Tomoko Nakayama, Yuji Inagaki, Yoshihito Shiota, Kazunari Yoshizawa, Kei Ohkubo, and Shunichi Fukuzumi
pp 886 - 895; DOI:
10.1021/ic7016038
PDF
Multiple Pathways for Dinitrogen Activation during the Reduction of an Fe Bis(iminepyridine) Complex
Jennifer Scott, Indu Vidyaratne, Ilia Korobkov, Sandro Gambarotta, and Peter H. M. Budzelaar
pp 896 - 911; DOI:
10.1021/ic701643d
PDF
Reversible NO Motion in Crystalline [Fe(Porph)(1-MeIm)(NO)] Derivatives
Nathan J. Silvernail, Jeffrey W. Pavlik, Bruce C. Noll, Charles E. Schulz, and W. Robert Scheidt
pp 912 - 920; DOI:
10.1021/ic701700p
PDF
Strontium Superstoichiometry and Defect Structure of SrCeO3 Perovskite
Glenn C. Mather, Filipe M. Figueiredo, Julio Romero de Paz, and Susana García-Martín
pp 921 - 929; DOI:
10.1021/ic701703c
PDF
Cobalt, Zinc, and Nickel Complexes of a Diatopic Heteroscorpionate Ligand: Building Blocks for Coordination Polymers
Guillermo A. Santillan and Carl J. Carrano
pp 930 - 939; DOI:
10.1021/ic701718b
PDF
Heterospin Systems Constructed from [Cu2Ln]3+ and [Ni(mnt)2]1-,2- Tectons: First 3p-3d-4f Complexes (mnt = Maleonitriledithiolato)
Augustin M. Madalan, Narcis Avarvari, Marc Fourmigué, Rodolphe Clérac, Liviu F. Chibotaru, Sergiu Clima, and Marius Andruh
pp 940 - 950; DOI:
10.1021/ic701738z
PDF
Ruthenium(II) 2,2'-Bipyridyl Tetrakis Acetonitrile Undergoes Selective Axial Photocleavage
Agustín Petroni, Leonardo D. Slep, and Roberto Etchenique
pp 951 - 956; DOI:
10.1021/ic7018204
PDF
Strong Intra- and Intermolecular Aurophilic Interactions in a New Series of Brilliantly Luminescent Dinuclear Cationic and Neutral Au(I) Benzimidazolethiolate Complexes
Jacob Schneider, Young-A Lee, Javier Pérez, William W. Brennessel, Christine Flaschenriem, and Richard Eisenberg
pp 957 - 968; DOI:
10.1021/ic701763x
PDF
Formation of Unsaturated C3 Hydrocarbons by the Protolysis of Magnesium Sesquicarbide with Ammonium Halides
Sabrina Disch, Anthony K. Cheetham, and Uwe Ruschewitz
pp 969 - 973; DOI:
10.1021/ic701760s
PDF
Determination of Absolute Configuration of Chiral Hemicage Metal Complexes Using Time-Dependent Density Functional Theory
Frederick J. Coughlin, Karl D. Oyler, Robert A. Pascal, Jr., and Stefan Bernhard
pp 974 - 979; DOI:
10.1021/ic701804k
PDF
Synthesis, Characterization, and DFT/TD-DFT Calculations of Highly Phosphorescent Blue Light-Emitting Anionic Iridium Complexes
Davide Di Censo, Simona Fantacci, Filippo De Angelis, Cedric Klein, Nick Evans, K. Kalyanasundaram, Henk J. Bolink, Michael Grätzel, and Mohammad K. Nazeeruddin
pp 980 - 989; DOI:
10.1021/ic701814h
PDF
Ru(II) Complexes of Tetradentate Ligands Related to 2,9-Di(pyrid-2'-yl)-1,10-phenanthroline
Gang Zhang, Ruifa Zong, Huan-Wei Tseng, and Randolph P. Thummel
pp 990 - 998; DOI:
10.1021/ic701798v
PDF
Synthesis and Molecular and Electronic Structure of an Unusual Paramagnetic Borohydride Complex Mo(NAr)2(PMe3)2(2-BH4)
Andrey Y. Khalimon, Jason P. Holland, Radoslaw M. Kowalczyk, Eric J. L. McInnes, Jennifer C. Green, Philip Mountford, and Georgii I. Nikonov
pp 999 - 1006; DOI:
10.1021/ic701826v
PDF
Salts of Methylated 5-Aminotetrazoles with Energetic Anions
Konstantin Karaghiosoff, Thomas M. Klapötke, Peter Mayer, Carles Miró Sabaté, Alexander Penger, and Jan M. Welch
pp 1007 - 1019; DOI:
10.1021/ic701832z
PDF
Synthesis, Structure, and Bonding of Sc4MgxCu15 - xGa~7.5 (x = 0, 0.5). Two Incommensurately Modulated Scandium Substitution Derivatives of Cubic Mg2Cu6Ga5
Qisheng Lin, Sven Lidin, and John D. Corbett
pp 1020 - 1029; DOI:
10.1021/ic701853c
PDF
Neodymium, Gadolinium, and Terbium Complexes Containing Hexafluoroacetylacetonate and 2,2'-Bipyrimidine: Structural and Spectroscopic Characterization
Albert Fratini, Gregory Richards, Emily Larder, and Shawn Swavey
pp 1030 - 1036; DOI:
10.1021/ic701805t
PDF
Synthesis, Structures, and Magnetic Properties of Metal-Coordination Polymers with Benzenepentacarboxylate Linkers
Xin-Yi Wang and Slavi C. Sevov
pp 1037 - 1043; DOI:
10.1021/ic701893z
PDF
Toward Multifunctional Mo(VI-IV) Complexes: cis-Dioxomolybdenum(VI) Complexes Containing Hydrogen-Bond Acceptors or Donors
Lyndal M. R. Hill, Michelle K. Taylor, Victor Wee Lin Ng, and Charles G. Young
pp 1044 - 1052; DOI:
10.1021/ic701957b
PDF
Oxygen-Centered Hexatantalum Tetradecaimido Cluster Complexes
Jamin L. Krinsky, Laura L Anderson, John Arnold, and Robert. G. Bergman
pp 1053 - 1066; DOI:
10.1021/ic701920v
PDF
A Distorted Cubic Tetranuclear Copper(II) Phosphonate Cage with a Double-Four-Ring-Type Core
Vadapalli Chandrasekhar, Loganathan Nagarajan, Rodolphe Clérac, Surajit Ghosh, and Sandeep Verma
pp 1067 - 1073; DOI:
10.1021/ic701948g
PDF
Structure of the Molybdenum Site of Escherichia coli Trimethylamine N-Oxide Reductase
Limei Zhang, Kimberly Johnson Nelson, K. V. Rajagopalan, and Graham N. George
pp 1074 - 1078; DOI:
10.1021/ic701956f
PDF
All the Disorder Mechanisms in the 13:58 Phases Come Together. Out of the Modulated Confusion Rises the Remarkable Phase Ce12.60Cd58.68(2)
Shu Ying Piao, Lukas Palatinus, and Sven Lidin
pp 1079 - 1086; DOI:
10.1021/ic701962b
PDF
Counterions Influence Reactivity of Metal Ions with Cysteinyldopa Model Compounds
Yohannes T. Tesema, David M. Pham, and Katherine J. Franz
pp 1087 - 1095; DOI:
10.1021/ic701889w
PDF
Versatile Coordinative Abilities of a New Hybrid Pteridine-Thiosemicarbazone Ligand: Crystal Structure, Spectroscopic Characterization, and Luminescent Properties
Sonia B. Jiménez-Pulido, Fátima M. Linares-Ordóñez, Miguel N. Moreno-Carretero, and Miguel Quirós-Olozábal
pp 1096 - 1106; DOI:
10.1021/ic701994s
PDF
Synthesis, Structure, and Physicochemical Properties of Dinuclear NiII Complexes as Highly Efficient Functional Models of Phosphohydrolases
Alessandra Greatti, Marciela Scarpellini, Rosely A. Peralta, Annelise Casellato, Adailton J. Bortoluzzi, Fernanado R. Xavier, Rafael Jovito, Marcos Aires de Brito, Bruno Szpoganicz, Zbigniew Tomkowicz, Michal Rams, Wolfgang Haase, and Ademir Neves
pp 1107 - 1119; DOI:
10.1021/ic702132t
PDF
Double-Stranded Monohelical Complexes from an Unsymmetrical Chiral Schiff-Base Ligand
Azadeh Lalehzari, John Desper, and Christopher J. Levy
pp 1120 - 1126; DOI:
10.1021/ic702015u
PDF
Nickel(II) Chain with Alternating End-On/End-to-End Single Azido Bridges: A Combined Structural, Magnetic, and Theoretical Study
Marie-Laure Bonnet, Christophe Aronica, Guillaume Chastanet, Guillaume Pilet, Dominique Luneau, Corine Mathonière, Rodolphe Clérac, and Vincent Robert
pp 1127 - 1133; DOI:
10.1021/ic702012r
PDF
Employment of 2,6-Diacetylpyridine Dioxime as a New Route to High Nuclearity Metal Clusters: Mn6 and Mn8 Complexes
Theocharis C. Stamatatos, Brian S. Luisi, Brian Moulton, and George Christou
pp 1134 - 1144; DOI:
10.1021/ic7020269
PDF
N-Heterocyclic Carbenes with Inorganic Backbones: Electronic Structures and Ligand Properties
Anna Kausamo, Heikki M. Tuononen, Kelly E. Krahulic, and Roland Roesler
pp 1145 - 1154; DOI:
10.1021/ic7020929
PDF
Thermodynamic and Spectroscopic Studies of Lanthanides(III) Complexation with Polyamines in Dimethyl Sulfoxide
P. Di Bernardo, P. L. Zanonato, A. Melchior, R. Portanova, M. Tolazzi, G. R. Choppin, and Z. Wang
pp 1155 - 1164; DOI:
10.1021/ic701337u
PDF
Synthesis, Characterization, and Reactivity of Iron Trisamidoamine Complexes That Undergo Both Metal- and Ligand-Centered Oxidative Transformations
Remle Çelenligil-Çetin, Patrina Paraskevopoulou, Rupam Dinda, Richard J. Staples, Ekkehard Sinn, Nigam P. Rath, and Pericles Stavropoulos
pp 1165 - 1172; DOI:
10.1021/ic702154z
PDF
The Mechanism of Carbon Dioxide Catalysis in the Hydrogen Peroxide N-Oxidation of Amines
Bharathi Balagam and David E. Richardson
pp 1173 - 1178; DOI:
10.1021/ic701402h
PDF
Ruthenium(II) Polypyridyl Complexes: Potential Precursors, Metalloligands, and Topo II Inhibitors
Sanjeev Sharma, Sanjay K. Singh, and Daya S. Pandey
pp 1179 - 1189; DOI:
10.1021/ic701518e
PDF
Synthesis, Characterization, and Reactivity of [Li(N6,N9-Me2Ade-H)]: A Structurally Characterized Lithiated Adenine
Thomas Krüger, Tobias Rüffer, Heinrich Lang, Christoph Wagner, and Dirk Steinborn
pp 1190 - 1195; DOI:
10.1021/ic701569j
PDF
A Convenient Preparative Method for Cyclic Triphosphenium Bromide and Chloride Salts
Erin L. Norton, Kara L. S. Szekely, Jonathan W. Dube, Paolo G. Bomben, and Charles L. B. Macdonald
pp 1196 - 1203; DOI:
10.1021/ic701342u
PDF
Tetraalkoxyaluminates of Nickel(II), Copper(II), and Copper(I)
Michael Veith, Kroum Valtchev, and Volker Huch
pp 1204 - 1217; DOI:
10.1021/ic701729y
PDF
Electrochemiluminescence of Ruthenium(II) Complexes Functionalized with Crown Ether Pendants and Effects of Cation Binding
Mei-Jin Li, Zuofeng Chen, Nianyong Zhu, Vivian Wing-Wah Yam, and Yanbing Zu
pp 1218 - 1223; DOI:
10.1021/ic7019582
PDF
Direct Oxidation of L-Cysteine by [FeIII(bpy)2(CN)2]+ and [FeIII(bpy)(CN)4]-
Xiaoguang Wang and David M. Stanbury
pp 1224 - 1236; DOI:
10.1021/ic701891m
PDF
Simple Preparations of Pd6Cl12, Pt6Cl12, and Qn[Pt2Cl8+n], n = 1, 2 (Q = TBA+, PPN+) and Structural Characterization of [TBA][Pt2Cl9] and [PPN]2[Pt2Cl10]·C7H8
Daniela Belli Dell'Amico, Fausto Calderazzo, Fabio Marchetti, Stefano Ramello, and Simona Samaritani
pp 1237 - 1242; DOI:
10.1021/ic701932u
PDF

Issue 4


Tetrahedral Tellurate
Saki Konaka, Yoshiki Ozawa, and Atsushi Yagasaki
pp 1244 - 1245; DOI:
10.1021/ic701578p
PDF
Synthesis and Crystal Structure of Thorium Bis(hydrogenphosphate) Monohydrate
Miguel A. Salvadó, Pilar Pertierra, Germán R. Castro, Camino Trobajo, and José R. García
pp 1246 - 1248; DOI:
10.1021/ic702497x
PDF
Hydrothermal In Situ Synthesis and Characterization of Cu(II) Complexes
Danfeng Weng, Weihua Mu, Xiangjun Zheng, Decai Fang, and Linpei Jin
pp 1249 - 1251; DOI:
10.1021/ic702107e
PDF
From Coordinated Oxophosphinidene to O,O,P-Bound Arylhypophosphite(2−) To Build a Singular Mo2Sn2O4P2 Metallocycle
María Alonso, M. Angeles Alvarez, M. Esther García, and Miguel A. Ruiz
pp 1252 - 1254; DOI:
10.1021/ic702416z
PDF
One-Pot Synthesis and Self-Assembly of Copper Phthalocyanine Nanobelts through a Water-Chemical Route
Juan Li, Shuangqing Wang, Shayu Li, Qian Wang, Yan Qian, Xiuping Li, Min Liu, Yi Li, and Guoqiang Yang
pp 1255 - 1257; DOI:
10.1021/ic7018583
PDF
Platinum(II) Molecular Triangle with a Deep Intramolecular Cavity
Stuart A. Willison, Jeanette A. Krause, and William B. Connick
pp 1258 - 1260; DOI:
10.1021/ic7020066
PDF
Low-Temperature Approach to Synthesize Iron Nitride from Amorphous Iron
Yi Han, Huamin Wang, Minghui Zhang, Ming Su, Wei Li, and Keyi Tao
pp 1261 - 1263; DOI:
10.1021/ic702171s
PDF
Specific Colorimetric Detection of Cyanide Triggered by a Conformational Switch in Vitamin B12
Felix H. Zelder
pp 1264 - 1266; DOI:
10.1021/ic702368b
PDF
Facile Synthesis of the Tridecameric Al13 Nanocluster Al133-OH)62-OH)18(H2O)24(NO3)15
Jason T. Gatlin, Zachary L. Mensinger, Lev N. Zakharov, David MacInnes, and Darren W. Johnson
pp 1267 - 1269; DOI:
10.1021/ic7020808
PDF
Synthesis and Characterization of QD-3: The First Organically Templated Aluminoborate with 11-, 12-, and 14-Ring Intersecting Channels
Guo-Ming Wang, Jin-Hua Li, Zeng-Xin Li, Hai-Lan Huang, Shu-Yun Xue, and Hui-Luan Liu
pp 1270 - 1272; DOI:
10.1021/ic702448g
PDF
Unusual Reactivity of Methylphosphaalkyne (PCMe) toward Digermenes and Distannenes: Stepwise Formations of Bridged 2,3,5,6-Tetraphospha-1,4-dimethylidenecyclohexanes
Cameron Jones, Christian Schulten, and Andreas Stasch
pp 1273 - 1278; DOI:
10.1021/ic700926u
PDF
Synthesis and Characterization of 3-Cyano- and 3-Nitroformazans, Nitrogen-Rich Analogues of β-Diketimine Ligands
Joe B. Gilroy, Peter O. Otieno, Michael J. Ferguson, Robert McDonald, and Robin G. Hicks
pp 1279 - 1286; DOI:
10.1021/ic7019445
PDF
Transition Metal Complexes of 3-Cyano- and 3-Nitroformazans
Joe B. Gilroy, Brian O. Patrick, Robert McDonald, and Robin G. Hicks
pp 1287 - 1294; DOI:
10.1021/ic7019846
PDF
Electrochemical Synthesis, Structural Characterization, and Decomposition of Rhenium Oxoethoxide, Re4O4(OEt)12. Ligand Influence on the Structure and Bonding in the High-Valent Tetranuclear Planar Rhenium Alkoxide Clusters
Olesya A. Nikonova, Kjell Jansson, Vadim G. Kessler, Margareta Sundberg, Alexei I. Baranov, Andrei V. Shevelkov, Dmitrii V. Drobot, and Gulaim A. Seisenbaeva
pp 1295 - 1300; DOI:
10.1021/ic701781k
PDF
Dinuclear Cp* Cobalt Complexes of the 1,2,4,5-Benzenetetrathiolate Bischelating Ligand
Mitsushiro Nomura and Marc Fourmigué
pp 1301 - 1312; DOI:
10.1021/ic700778b
PDF
Alkaline-Earth Metal Mercury Intermetallics A11−xHg54+x (A = Ca, Sr)
Andriy V. Tkachuk and Arthur Mar
pp 1313 - 1318; DOI:
10.1021/ic7015148
PDF
Side-On Bound Dinitrogen Complex of Zirconium Supported by a P2N2 Macrocyclic Ligand
Lara Morello, Maria João Ferreira, Brian O. Patrick, and Michael D. Fryzuk
pp 1319 - 1323; DOI:
10.1021/ic701599t
PDF
Iron(II) Complexes of Sterically Bulky α-Ketocarboxylates. Structural Models for α-Ketoacid-Dependent Nonheme Iron Halogenases
Seth J. Friese, Benjamin E. Kucera, Victor G. Young Jr., Lawrence Que Jr., and William B. Tolman
pp 1324 - 1331; DOI:
10.1021/ic701823y
PDF
Planar Tetracoordinate Carbon Species Involving Beryllium Substituents
Zhi-Xiang Wang, Cheng-Gen Zhang, Zhongfang Chen, and Paul von Ragué Schleyer
pp 1332 - 1336; DOI:
10.1021/ic7017709
PDF
Pyridine−tert-Nitrogen−Phenol Ligands: N,N,O-Type Tripodal Chelates for the [M(CO)3]+ Core (M = Re, Tc)
Nathaniel C. Lim, Charles B. Ewart, Meryn L. Bowen, Cara L. Ferreira, Cheri A. Barta, Michael J. Adam, and Chris Orvig
pp 1337 - 1345; DOI:
10.1021/ic701822n
PDF
Porous Metal−Organic Framework Based on μ4-oxo Tetrazinc Clusters: Sorption and Guest-Dependent Luminescent Properties
Lei Hou, Yan-Yong Lin, and Xiao-Ming Chen
pp 1346 - 1351; DOI:
10.1021/ic702085x
PDF
Importance of Platinum(II)-Assisted Platinum(IV) Substitution for the Oxidation of Guanosine Derivatives by Platinum(IV) Complexes
Sunhee Choi, Livia Vastag, Yuri C. Larrabee, Michelle L. Personick, Kurt B. Schaberg, Benjamin J. Fowler, Roger K. Sandwick, and Gulnar Rawji
pp 1352 - 1360; DOI:
10.1021/ic701868b
PDF
Single-Crystalline ZnGa2O4 Spinel Phosphor via a Single-Source Inorganic Precursor Route
Lu Zou, Xu Xiang, Min Wei, Feng Li, and David G. Evans
pp 1361 - 1369; DOI:
10.1021/ic7012528
PDF
Facile Synthesis and Relaxation Properties of Novel Bispolyazamacrocyclic Gd3+ Complexes: An Attempt towards Calcium-Sensitive MRI Contrast Agents
Anurag Mishra, Petra Fousková, Goran Angelovski, Edina Balogh, Anil K. Mishra, Nikos K. Logothetis, and Éva Tóth
pp 1370 - 1381; DOI:
10.1021/ic7017456
PDF
Formation of a Unique Zinc Carbamate by CO2 Fixation: Implications for the Reactivity of Tetra-Azamacrocycle Ligated Zn(II) Complexes
Johannes Notni, Stephan Schenk, Helmar Görls, Hergen Breitzke, and Ernst Anders
pp 1382 - 1390; DOI:
10.1021/ic701899u
PDF
Subtle Ring-Constraint Effects on the Formation of Metallacycles. Cyclodimer versus Cyclotrimer of Bis(chloro)-1,4-bis(dimethyl-3 or 4-pyridylsilyl)benzenepalladium(II) Complexes
Young Mee Na, Tae Hwan Noh, In Sung Chun, Young-A Lee, Jongki Hong, and Ok-Sang Jung
pp 1391 - 1396; DOI:
10.1021/ic701489p
PDF
Arylphosphanide Complexes of the Alkaline-Earth Metals Magnesium, Calcium, Strontium, and Barium of the Formula (THF)nM[P(H)Ph]2 and Formation of Potassium Diphenylphosphinomagnesiates
Martin Gärtner, Helmar Görls, and Matthias Westerhausen
pp 1397 - 1405; DOI:
10.1021/ic702148v
PDF
Solvation Effects on the Stability of Silver(I) Complexes with Pyridine-Containing Ligands Studied by Thermodynamics and DFT Methods
Silvia Del Piero, Rosalisa Fedele, Andrea Melchior*, Roberto Portanova, Marilena Tolazzi, and Ennio Zangrando
pp 1406 - 1406; DOI:
10.1021/ic800010g
PDF

Issue 5


Structure of a Crystalline Vapochromic Platinum(II) Salt
Levi J. Grove, Allen G. Oliver, Jeanette A. Krause, and William B. Connick
pp 1408 - 1410; DOI:
10.1021/ic701523e
PDF
Diffusion of a Highly Charged Supramolecular Assembly: Direct Observation of Ion Association in Water
Michael D. Pluth, Bryan E. F. Tiedemann, Herman van Halbeek, Rudi Nunlist, and Kenneth N. Raymond
pp 1411 - 1413; DOI:
10.1021/ic7020885
PDF
Oxyfluorotitanophosphate Cluster [Ti10P4O16F44]16−: Synthesis and Characterization of K16[Ti10P4O16F44]
Sihai Yang, Guobao Li, Alexander J. Blake, Junliang Sun, Ming Xiong, Fuhui Liao, and Jianhua Lin
pp 1414 - 1416; DOI:
10.1021/ic702214g
PDF
Kinetic Evidence for High Reactivity of 3-Nitrophenylboronic Acid Compared to Its Conjugate Boronate Ion in Reactions with Ethylene and Propylene Glycols
Chiaki Miyamoto, Kazunori Suzuki, Satoshi Iwatsuki, Masahiko Inamo, Hideo D. Takagi, and Koji Ishihara
pp 1417 - 1419; DOI:
10.1021/ic702317n
PDF
Internal and External Factors in the Structural Organization in Cocrystals of the Mixed-Metal Endohedrals (GdSc2N@Ih-C80, Gd2ScN@Ih-C80, and TbSc2N@Ih-C80) and Nickel(II) Octaethylporphyrin
Steven Stevenson, Christopher J. Chancellor, Hon Man Lee, Marilyn M. Olmstead, and Alan L. Balch
pp 1420 - 1427; DOI:
10.1021/ic701824q
PDF
Synthesis of Discrete and Dispersible MoS2 Nanocrystals
Hongtao Yu, Yi Liu, and Stephanie L. Brock
pp 1428 - 1434; DOI:
10.1021/ic701020s
PDF
Infrared Spectra and Electronic Structures of Agostic Uranium Methylidene Molecules
Jonathan T. Lyon, Lester Andrews, Han-Shi Hu, and Jun Li
pp 1435 - 1442; DOI:
10.1021/ic701786h
PDF
Systematic Investigation on Morphologies, Forming Mechanism, Photocatalytic and Photoluminescent Properties of ZnO Nanostructures Constructed in Ionic Liquids
Li Wang, Lixian Chang, Bin Zhao, Zhongyong Yuan, Gaosong Shao, and Wenjun Zheng
pp 1443 - 1452; DOI:
10.1021/ic701094a
PDF
Co[HO2C(CH2)3NH(CH2PO3H)2]2: A New Canted Antiferromagnet
Bing-Ping Yang, Andrey V. Prosvirin, Ya-Qin Guo, and Jiang-Gao Mao
pp 1453 - 1459; DOI:
10.1021/ic701351x
PDF
Unique Manganese Phosphorus Complex with a Mn5P7 Core: Synthesis, Molecular Structure, and Magnetic Properties
Carsten von Hänisch, Florian Weigend, and Rodolphe Clérac
pp 1460 - 1464; DOI:
10.1021/ic701694f
PDF
Crown Ether Inclusion Complexes of the Early Actinide Elements, [AnO2(18-crown-6)]n+, An = U, Np, Pu and n = 1, 2: A Relativistic Density Functional Study
Grigory A. Shamov, Georg Schreckenbach, Richard L. Martin, and P. Jeffrey Hay
pp 1465 - 1475; DOI:
10.1021/ic7015403
PDF
Highly Phosphorescent Iridium Complexes with Chromophoric 2-(2-Hydroxyphenyl)oxazole-Based Ancillary Ligands: Interligand Energy-Harvesting Phosphorescence
Youngmin You, Jangwon Seo, Se Hun Kim, Kil Suk Kim, Tae Kyu Ahn, Dongho Kim, and Soo Young Park
pp 1476 - 1487; DOI:
10.1021/ic701778f
PDF
Synthesis of CuII−RuII−CuII Trinuclear Complexes via Redox Reaction of Copper(I) Across Thiosemicarbazones Coordinated to Ruthenium(II)
Tarlok S. Lobana, Gagandeep Bawa, and Ray J. Butcher
pp 1488 - 1495; DOI:
10.1021/ic701780g
PDF
Vibrational Property Study of SrGa2H2 and BaGa2H2 by Inelastic Neutron Scattering and First Principles Calculations
Myeong H. Lee, Michael J. Evans, Luke L. Daemen, Otto F. Sankey, and Ulrich Häussermann
pp 1496 - 1501; DOI:
10.1021/ic7019318
PDF
Functionalized Tellurols: Synthesis, Spectroscopic Characterization by Photoelectron Spectroscopy, and Quantum Chemical Study
Brahim Khater, Jean-Claude Guillemin, Gábor Bajor, and Tamás Veszprémi
pp 1502 - 1511; DOI:
10.1021/ic701791h
PDF
Luminescence of Ln(III) Dithiocarbamate Complexes (Ln = La, Pr, Sm, Eu, Gd, Tb, Dy)
Michelle D. Regulacio, Michele H. Pablico, Joan Acay Vasquez, Peter N. Myers, Stuart Gentry, Michael Prushan, Suk-Wah Tam-Chang, and Sarah L. Stoll
pp 1512 - 1523; DOI:
10.1021/ic701974q
PDF
Palladium(II) and Platinum(II) Complexes with Heteroditopic 10-(Aryl)phenoxarsine (Aryl = 2-C6H4OR, R = H, Me, Pri) Ligands: Solvent-Oriented Crystallization of cis Isomers
Natalia Moldovan, Peter Lönnecke, Ioan Silaghi-Dumitrescu, Luminita Silaghi-Dumitrescu, and Evamarie Hey-Hawkins
pp 1524 - 1531; DOI:
10.1021/ic7021648
PDF
Platinum(II) Diimine Complexes with Catecholate Ligands Bearing Imide Electron-Acceptor Groups: Synthesis, Crystal Structures, (Spectro)Electrochemical and EPR studies, and Electronic Structure
Nail M. Shavaleev, E. Stephen Davies, Harry Adams, Jonathan Best, and Julia A. Weinstein
pp 1532 - 1547; DOI:
10.1021/ic701821d
PDF
Macrocyclic Eu3+ Chelates Show Selective Luminescence Responses to Anions
Christopher G. Gulgas and Theresa M. Reineke
pp 1548 - 1559; DOI:
10.1021/ic701916z
PDF
A Tungsten(VI) Nitride Having a W2(μ-N)2 Core
Zachary J. Tonzetich, Richard R. Schrock, Keith M. Wampler, Brad C. Bailey, Christopher C. Cummins, and Peter Müller
pp 1560 - 1567; DOI:
10.1021/ic701913q
PDF
Structural and Magnetic Studies of Two-Dimensional Solvent-Free Manganese(II) Complexes Prepared Via Ligand Exchange Reaction Under Solvothermal Conditions
Shengming Liu, M. T. Bremer, John Lovaasen, A. N. Caruso, Kevin O’Neill, Lin Simpson, Philip A. Parilla, Michael J. Heben, and Douglas L. Schulz
pp 1568 - 1575; DOI:
10.1021/ic7020879
PDF
Tetranuclear CoII, MnII, and CuII Complexes of a Novel Binucleating Pyrazolate Ligand Preorganized for the Self-Assembly of Compact [2 × 2]-Grid Structures
Jarl Ivar van der Vlugt, Serhiy Demeshko, Sebastian Dechert, and Franc Meyer
pp 1576 - 1585; DOI:
10.1021/ic701951a
PDF
Secondary Bonding Interactions in Biomimetic [2Fe−2S] Clusters
Joachim Ballmann, Sebastian Dechert, Eckhard Bill, Ulf Ryde, and Franc Meyer
pp 1586 - 1596; DOI:
10.1021/ic702095a
PDF
Mononuclear, Dinuclear, and Hexanuclear Gold(I) Complexes with (aza-15-crown-5)Dithiocarbamate
Javier Arias, Manuel Bardají, and Pablo Espinet
pp 1597 - 1606; DOI:
10.1021/ic702252j
PDF
Coordination Chemistry of Tetra- and Tridentate Ferrocenyl Polyphosphines: An Unprecedented [1,1′-Heteroannular and 2,3-Homoannular]-Phosphorus-Bonding Framework in a Metallocene Dinuclear Coordination Complex
D. A. Thomas, V. V. Ivanov, I. R. Butler, P. N. Horton, P. Meunier, and J.-C. Hierso
pp 1607 - 1615; DOI:
10.1021/ic7022105
PDF
Luminescent Gold(I) Carbenes from 2-Pyridylisocyanide Complexes: Structural Consequences of Intramolecular versus Intermolecular Hydrogen-Bonding Interactions
Camino Bartolomé, Marta Carrasco-Rando, Silverio Coco, Carlos Cordovilla, Jose M. Martín-Alvarez, and Pablo Espinet
pp 1616 - 1624; DOI:
10.1021/ic702201e
PDF
Singlet Diradical Complexes of Ruthenium and Osmium: Geometrical and Electronic Structures and their Unexpected Changes on Oxidation
Subhas Samanta, Priti Singh, Jan Fiedler, Stanislav Záliš, Wolfgang Kaim, and Sreebrata Goswami
pp 1625 - 1633; DOI:
10.1021/ic702301a
PDF
Coordination of a Uranium(IV) Sulfate Monomer in an Aqueous Solution and in the Solid State
Christoph Hennig, Werner Kraus, Franziska Emmerling, Atsushi Ikeda, and Andreas C. Scheinost
pp 1634 - 1638; DOI:
10.1021/ic701880h
PDF
Kinetics and Mechanisms of Chlorine Dioxide Oxidation of Tryptophan
David J. Stewart, Michael J. Napolitano, Ekaterina V. Bakhmutova-Albert, and Dale W. Margerum
pp 1639 - 1647; DOI:
10.1021/ic701761p
PDF
Ba2F2Fe2+0.5Fe3+S3: A Two-Dimensional Inhomogeneous Mixed Valence Iron Compound
Houria Kabbour and Laurent Cario
pp 1648 - 1652; DOI:
10.1021/ic702021s
PDF
Infrared Spectra of Methylidynes Formed in Reactions of Re Atoms with Methane, Methyl Halides, Methylene Halides, and Ethane: Methylidyne C−H Stretching Absorptions, Bond Lengths, and s Character
Han-Gook Cho and Lester Andrews
pp 1653 - 1662; DOI:
10.1021/ic701505w
PDF
Structural and NMR Spectroscopic Investigations of Chair and Twist Conformers of the P2Se82− Anion
Christiane Rotter, Michael Schuster, Mustafa Kidik, Oliver Schön, Thomas M. Klapötke, and Konstantin Karaghiosoff
pp 1663 - 1673; DOI:
10.1021/ic7015534
PDF
Transient Intermediates from Mn(salen) with Sterically Hindered Mesityl Groups: Interconversion between MnIV-Phenolate and MnIII-Phenoxyl Radicals as an Origin for Unique Reactivity
Takuya Kurahashi, Akihiro Kikuchi, Takehiko Tosha, Yoshitsugu Shiro, Teizo Kitagawa, and Hiroshi Fujii
pp 1674 - 1686; DOI:
10.1021/ic702061y
PDF
On the Anisotropy of the Magnetic Properties of CsYbZnSe3
George H. Chan, Changhoon Lee, Dadi Dai, Myung-Hwan Whangbo, and James A. Ibers
pp 1687 - 1692; DOI:
10.1021/ic701961f
PDF
Infrared Spectrum of Matrix Isolated Selenoformaldehyde, CH2Se, and CD2Se
Helmut Beckers, Yong Seol Kim, and Helge Willner
pp 1693 - 1696; DOI:
10.1021/ic702237v
PDF

Issue 6


Preface on Making Oxygen
Richard Eisenberg and Harry B. Gray
pp 1697 - 1699; DOI:
10.1021/ic800155g
PDF
Crystal Structure of the Oxygen-Evolving Complex of Photosystem II
James Barber
pp 1700 - 1710; DOI:
10.1021/ic701835r
PDF
Where Water Is Oxidized to Dioxygen: Structure of the Photosynthetic Mn4Ca Cluster from X-ray Spectroscopy
Junko Yano and Vittal K. Yachandra
pp 1711 - 1726; DOI:
10.1021/ic7016837
PDF
Mechanisms of Water Oxidation from the Blue Dimer to Photosystem II
Feng Liu, Javier J. Concepcion, Jonah W. Jurss, Thomas Cardolaccia, Joseph L. Templeton, and Thomas J. Meyer
pp 1727 - 1752; DOI:
10.1021/ic701249s
PDF
Mechanisms of Water Oxidation Catalyzed by Ruthenium Diimine Complexes
James K. Hurst, Jonathan L. Cape, Aurora E. Clark, Samir Das, and Changyong Qin
pp 1753 - 1764; DOI:
10.1021/ic700724h
PDF
In Search of Elusive High-Valent Manganese Species That Evaluate Mechanisms of Photosynthetic Water Oxidation
Vincent L. Pecoraro and Wen-Yuan Hsieh
pp 1765 - 1778; DOI:
10.1021/ic7017488
PDF
Theoretical Studies of O−O Bond Formation in Photosystem II
Per E. M. Siegbahn
pp 1779 - 1786; DOI:
10.1021/ic7012057
PDF
Water Oxidation by a Ruthenium Complex with Noninnocent Quinone Ligands: Possible Formation of an O−O Bond at a Low Oxidation State of the Metal
James T. Muckerman, Dmitry E. Polyansky, Tohru Wada, Koji Tanaka, and Etsuko Fujita
pp 1787 - 1802; DOI:
10.1021/ic701892v
PDF
Multifrequency Pulsed Electron Paramagnetic Resonance Study of the S2 State of the Photosystem II Manganese Cluster
Gregory J. Yeagle, M. Lane Gilchrist, Robert M. McCarrick, and R. David Britt
pp 1803 - 1814; DOI:
10.1021/ic701680c
PDF
Oxygen Evolution Catalysis by a Dimanganese Complex and Its Relation to Photosynthetic Water Oxidation
Ranitendranath Tagore, Robert H. Crabtree, and Gary W. Brudvig
pp 1815 - 1823; DOI:
10.1021/ic062218d
PDF
Ru Complexes That Can Catalytically Oxidize Water to Molecular Dioxygen
Isabel Romero, Montserrat Rodríguez, Cristina Sens, Joaquim Mola, Mohan Rao Kollipara, Laia Francàs, Elena Mas-Marza, Lluís Escriche, and Antoni Llobet
pp 1824 - 1834; DOI:
10.1021/ic700911y
PDF
Preparation and Study of a Family of Dinuclear Ru(II) Complexes That Catalyze the Decomposition of Water
Zeping Deng, Huan-Wei Tseng, Ruifa Zong, Dong Wang, and Randolph Thummel
pp 1835 - 1848; DOI:
10.1021/ic7010875
PDF
Electronic Design Criteria for O−O Bond Formation via Metal−Oxo Complexes
Theodore A. Betley, Qin Wu, Troy Van Voorhis, and Daniel G. Nocera
pp 1849 - 1861; DOI:
10.1021/ic701972n
PDF
Acid–Base-Driven Interconversion between a Mononuclear Complex and Supramolecular Coordination Polymers in a Terpyridine-Functionalized Dioxocyclam Ligand
Aurélien Gasnier, Jean-Michel Barbe, Christophe Bucher, Franck Denat, Jean-Claude Moutet, Eric Saint-Aman, Pierre Terech, and Guy Royal
pp 1862 - 1864; DOI:
10.1021/ic701584e
PDF
O/C Bond Cleavage of CO2 by NiI
Benjamin C. Fullmer, Hongjun Fan, Maren Pink, and Kenneth G. Caulton
pp 1865 - 1867; DOI:
10.1021/ic701843u
PDF
High-Pressure Synthesis, Structure, and Characterization of a Post-perovskite CaPtO3 with CaIrO3-Type Structure
Yoshiyuki Inaguma, Ken-ichiro Hasumi, Masashi Yoshida, Tomonori Ohba, and Tetsuhiro Katsumata
pp 1868 - 1870; DOI:
10.1021/ic701851e
PDF
Unexpected Formation of Ruthenium(II) Hydrides from a Reactive Dianiline Precursor and 1,2-(Ph2P)2-1,2-closo-C2B10H10
Jeramie J. Adams, Andrew S. Del Negro, Navamoney Arulsamy, and B. Patrick Sullivan
pp 1871 - 1873; DOI:
10.1021/ic701871t
PDF
On the 2-Electron 3-Center B−H−B Bond: Charge Density Determination of Tetraborane(10)
Diana Förster, Christian B. Hübschle, Peter Luger, Thomas Hügle, and Dieter Lentz
pp 1874 - 1876; DOI:
10.1021/ic701924r
PDF
Ligand- and Anion-Controlled Formation of Silver Alkynyl Oligomers from Soluble Precursors
Mei-Li Chen, Xue-Fei Xu, Ze-Xing Cao, and Quan-Ming Wang
pp 1877 - 1879; DOI:
10.1021/ic702023e
PDF
Catalytic Hydrolysis of Esters of 2-Hydroxypyridine Derivatives for Cu2+ Detection
János Kovács and Andriy Mokhir
pp 1880 - 1882; DOI:
10.1021/ic7022242
PDF
Metal-Mediated Transformation of a Triazinephenanthridinium Ligand Leading to a {Pd5} Coordination Complex Observed Crystallographically and by Cryospray Mass Spectrometry
Phil J. Kitson, Yu-Fei Song, Patrick Gamez, Paul de Hoog, De-Liang Long, Alexis D. C. Parenty, Jan Reedijk, and Leroy Cronin
pp 1883 - 1885; DOI:
10.1021/ic7022192
PDF
Syntheses of 2,4-Disubstituted 1,3,5-Triazapentadienyl Ligands Having Two Guanidinato Moieties and Their Use in the Isolation of Copper(I) Complexes
Meisu Zhou, Peng Li, Hongbo Tong, Yanping Song, Tao Gong, Jianping Guo, Linhong Weng, and Diansheng Liu
pp 1886 - 1888; DOI:
10.1021/ic702322n
PDF
Monovalent Iron in a Sulfur-Rich Environment
Michael T. Mock, Codrina V. Popescu, Glenn P. A. Yap, William G. Dougherty, and Charles G. Riordan
pp 1889 - 1891; DOI:
10.1021/ic7023378
PDF
Reactions of Tetrabromocatecholatomanganese(III) Complexes with Dioxygen
Clarence J. Rolle III, Kenneth I. Hardcastle, and Jake D. Soper
pp 1892 - 1894; DOI:
10.1021/ic702390q
PDF
Intramolecular Energy Transfer in a One-Dimensional Europium Tetracyanoplatinate
Branson A. Maynard, Katrina Kalachnikova, Kendra Whitehead, Zerihun Assefa, and Richard E. Sykora
pp 1895 - 1897; DOI:
10.1021/ic702386m
PDF
Grafting a Monolayer of Superparamagnetic Cyanide-Bridged Coordination Nanoparticles on Si(100)
Benoit Fleury, Florence Volatron, Laure Catala, Daniela Brinzei, Eric Rivière, Vincent Huc, Christophe David, Frédéric Miserque, Guillaume Rogez, Laurent Baraton, Serge Palacin, and Talal Mallah
pp 1898 - 1900; DOI:
10.1021/ic702328w
PDF
Synthesis of Ge2NiS4 Clusters and the Thermal Transformation to a Ge4Ni6S12 Cluster
Tsuyoshi Matsumoto, Yosuke Matsui, Mikinao Ito, and Kazuyuki Tatsumi
pp 1901 - 1903; DOI:
10.1021/ic702379y
PDF
Thermal Rearrangement of Phosphine−B(C6F5)3 Adducts
Gregory C. Welch, Thorsten Holtrichter-Roessmann, and Douglas W. Stephan
pp 1904 - 1906; DOI:
10.1021/ic702485r
PDF
Combination Effects of Cation and Anion of Ionic Liquids on the Cadmium Metal−Organic Frameworks in Ionothermal Systems
Ling Xu, Eun-Young Choi, and Young-Uk Kwon
pp 1907 - 1909; DOI:
10.1021/ic800071g
PDF
Rb2REGaSi4O12 (RE = Y, Eu, Gd, Tb): Luminescent Mixed-Anion Double Layer Silicates Containing Chains of Edge-Sharing REO7 Pentagonal Bipyramids
Cheng-Shiuan Lee, Yueh-Chun Liao, Jung-Tsung Hsu, Sue-Lein Wang, and Kwang-Hwa Lii
pp 1910 - 1912; DOI:
10.1021/ic7024445
PDF
Ligand- and Anion-Directed Assembly of Exo-Coordinated Mercury(II) Halide Complexes with O2S2-Donor Macrocycles
So Young Lee, Sunhong Park, Hyun Jee Kim, Jong Hwa Jung, and Shim Sung Lee
pp 1913 - 1915; DOI:
10.1021/ic702496e
PDF
[V16Sb4O42(H2O){VO(C6H14N2)2}4]: A Terminal Expansion to a Polyoxovanadate Archetype
Adam Wutkowski, Christian Näther, Paul Kögerler, and Wolfgang Bensch
pp 1916 - 1918; DOI:
10.1021/ic800042r
PDF
Zintl Phase Variations Through Cation Selection. Synthesis and Structure of A21Cd4Pn18 (A = Eu, Sr, Ba; Pn = Sb, Bi)
Sheng-Qing Xia and Svilen Bobev
pp 1919 - 1921; DOI:
10.1021/ic800242a
PDF
Cyclophosphazene-Supported Tetranuclear Copper Assembly Containing 15 Contiguous Inorganic Rings
Vadapalli Chandrasekhar, Gurusamy Thangavelu Senthil Andavan, Ramachandran Azhakar, and Balasubramanian Murugesa Pandian
pp 1922 - 1924; DOI:
10.1021/ic702500n
PDF
Mixed-Valence Tetra- and Hexanuclear Manganese Complexes from the Flexibility of Pyridine-Containing β-Diketone Ligands
Chen-I Yang, Wolfgang Wernsdorfer, Yu-Jhe Tsai, George Chung, Ting-Shen Kuo, Gene-Hsiang Lee, Minghuey Shieh, and Hui-Lien Tsai
pp 1925 - 1939; DOI:
10.1021/ic7013368
PDF
Single-Molecule Magnetism Properties of the First Strontium-Manganese Cluster [SrMn14O11(OMe)3(O2CPh)18(MeCN)2]
Abhudaya Mishra, Yulia Pushkar, Junko Yano, Vittal K. Yachandra, Wolfgang Wernsdorfer, Khalil A. Abboud, and George Christou
pp 1940 - 1948; DOI:
10.1021/ic701339p
PDF
Electronic Structure of CoIII Doped Bromo-Bridged Ni Complexes, [Ni1−xCox(chxn)2Br]Br2
Jimin Xie, Hashen Wu, Daisuke Kawakami, Hiroaki Iguchi, Shinya Takaishi, Masahiro Yamashita, Hiroyuki Matsuzaki, Hiroshi Okamoto, Hisaaki Tanaka, and Shin-ichi Kuroda
pp 1949 - 1952; DOI:
10.1021/ic7012232
PDF
Coordination Chemistry of Mercury(II) in Liquid and Aqueous Ammonia Solution and the Crystal Structure of Tetraamminemercury(II) Perchlorate
Kersti B. Nilsson, Mikhail Maliarik, Ingmar Persson, Andreas Fischer, Ann-Sofi Ullström, Lars Eriksson, and Magnus Sandström
pp 1953 - 1964; DOI:
10.1021/ic7013489
PDF
Disorder and Intermolecular Interactions in a Family of Tetranuclear Ni(II) Complexes Probed by High-Frequency Electron Paramagnetic Resonance
Jon Lawrence, En-Che Yang, Rachel Edwards, Marilyn M. Olmstead, Chris Ramsey, Naresh S. Dalal, Peter K. Gantzel, Stephen Hill, and David N. Hendrickson
pp 1965 - 1974; DOI:
10.1021/ic701416w
PDF
Phase Diagram of Mg Insertion into Chevrel Phases, MgxMo6T8 (T = S, Se). 3. The Crystal Structure of Triclinic Mg2Mo6Se8
E. Levi, A. Mitelman, O. Isnard, M. Brunelli, and D. Aurbach
pp 1975 - 1983; DOI:
10.1021/ic702311f
PDF
First Identification and Thermodynamic Characterization of the Ternary U(VI) Species, UO2(O2)(CO3)24−, in UO2−H2O2−K2CO3 Solutions
George S. Goff, Lia F. Brodnax, Michael R. Cisneros, Shane M. Peper, Stephanie E. Field, Brian L. Scott, and Wolfgang H. Runde
pp 1984 - 1990; DOI:
10.1021/ic701775g
PDF
Octachloro- and Octabromoditechnetate(III) and Their Rhenium(III) Congeners
Frederic Poineau, Alfred P. Sattelberger, Steven D. Conradson, and Kenneth R. Czerwinski
pp 1991 - 1999; DOI:
10.1021/ic701453k
PDF
Affinity of the Highly Preorganized Ligand PDA (1,10-Phenanthroline-2,9-dicarboxylic acid) for Large Metal Ions of Higher Charge. A Crystallographic and Thermodynamic Study of PDA Complexes of Thorium(IV) and the Uranyl(VI) ion
Nolan E. Dean, Robert D. Hancock, Christopher L. Cahill, and Mark Frisch
pp 2000 - 2010; DOI:
10.1021/ic701574j
PDF
An Unusual Asymmetric Polyoxomolybdate Containing Mixed-Valence Antimony and Its Derivatives: [Sb4VSb2IIIMo18O73(H2O)2]12− and {M(H2O)2[Sb4VSb2IIIMo18O73(H2O)2]2}22− (M = MnII, FeII, CuII or CoII)
Ganglin Xue, Xuemei Liu, Haisheng Xu, Huaiming Hu, Feng Fu, and Jiwu Wang
pp 2011 - 2016; DOI:
10.1021/ic7016648
PDF
Crystalline Alcoholamine Borates and the Triborate Monoanion
David M. Schubert, Mandana Z. Visi, and Carolyn B. Knobler
pp 2017 - 2023; DOI:
10.1021/ic7020098
PDF
Electron Transfer Mechanism and Photochemistry of Ferrioxalate Induced by Excitation in the Charge Transfer Band
Jie Chen, Hua Zhang, Ivan V. Tomov, and Peter M. Rentzepis
pp 2024 - 2032; DOI:
10.1021/ic7016566
PDF
MoV Electron Paramagnetic Resonance of Sulfite Oxidase Revisited: The Low-pH Chloride Signal
Christian J. Doonan, Heather L. Wilson, Brian Bennett, Roger C. Prince, K. V. Rajagopalan, and Graham N. George
pp 2033 - 2038; DOI:
10.1021/ic7017083
PDF
Synthesis, Separation, and Circularly Polarized Luminescence Studies of Enantiomers of Iridium(III) Luminophores
Frederick J. Coughlin, Michael S. Westrol, Karl D. Oyler, Neal Byrne, Christina Kraml, Eli Zysman-Colman, Michael S. Lowry, and Stefan Bernhard
pp 2039 - 2048; DOI:
10.1021/ic701747j
PDF
Solvent-Assisted Spontaneous Resolution of a 16-Membered Ring Containing Gold(I) Showing Short Au···Au Aurophilic Interaction and a Figure-Eight Conformation
Tünde Tunyogi, Andrea Deák, Gábor Tárkányi, Péter Király, and Gábor Pálinkás
pp 2049 - 2055; DOI:
10.1021/ic702059v
PDF
Electronic Effects of (N2S2)M(NO) Complexes (M = Fe, Co) as Metallodithiolate Ligands
Jennifer L. Hess, Harold L. Conder, Kayla N. Green, and Marcetta Y. Darensbourg
pp 2056 - 2063; DOI:
10.1021/ic7017874
PDF
Effect of Inorganic Ligands and Hydrogen Peroxide on ThO2 Dissolution. Behaviour of Th0.87Pu0.13O2 during Leaching Test
Solange Hubert, Guillaume Heisbourg, Nicolas Dacheux, and Philippe Moisy
pp 2064 - 2073; DOI:
10.1021/ic702065z
PDF
A Family of Cyanide-Bridged Molecular Squares: Structural and Magnetic Properties of [{MIICl2}2{CoII(triphos)(CN)2}2xCH2Cl2, M = Mn, Fe, Co, Ni, Zn
Ferdi Karadas, Eric J. Schelter, Michael Shatruk, Andrey V. Prosvirin, John Bacsa, Dmitry Smirnov, Andrew Ozarowski, J. Krzystek, Joshua Telser, and Kim R. Dunbar
pp 2074 - 2082; DOI:
10.1021/ic702084e
PDF
Mechanistic Aspects of the Reaction of Th+ and Th2+ with Water in the Gas Phase
Gloria Mazzone, Maria del Carmen Michelini, Nino Russo, and Emilia Sicilia
pp 2083 - 2088; DOI:
10.1021/ic701789n
PDF
RE(AuAl2)nAl2(AuxSi1−x)2: A New Homologous Series of Quaternary Intermetallics Grown from Aluminum Flux
Susan E. Latturner and Mercouri G. Kanatzidis
pp 2089 - 2097; DOI:
10.1021/ic701799z
PDF
Stabilization of an All-Metal Antiaromatic Molecule (Al4Li4) Using BH and C as Caps
Priyadarshi Satpati and K. L. Sebastian
pp 2098 - 2102; DOI:
10.1021/ic701040g
PDF
X-ray Crystal Structure and Magnetic and Photophysical Properties of Novel Copper(II) N-Oxide Adduct [(4-MPyO)2(CuCl2)2(H2O)(C2H5OH)] (4-MPyO = 4-(4-Methoxystyryl)pyridine N-Oxide)
Yakov P. Nizhnik, Anna Szemik-Hojniak, Irena Deperasińska, Lucjan B. Jerzykiewicz, Maria Korabik, Marek Hojniak, and Vladimir P. Andreev
pp 2103 - 2112; DOI:
10.1021/ic701413m
PDF
Ladders of a Magnetically Active Element in the Structure of the Novel Complex Boride Ti9Fe2Ru18B8: Synthesis, Structure, Bonding, and Magnetism
Boniface P. T. Fokwa, German D. Samolyuk, Gordon J. Miller, and Richard Dronskowski
pp 2113 - 2120; DOI:
10.1021/ic7020963
PDF
Zinc(II), Cadmium(II), Mercury(II), and Ethylmercury(II) Complexes of Phosphinothiol Ligands
P. Fernández, A. Sousa-Pedrares, J. Romero, J. A. García-Vázquez, A. Sousa, and P. Pérez-Lourido
pp 2121 - 2132; DOI:
10.1021/ic7005925
PDF
Thermodynamic, Kinetic, and Computational Study of Heavier Chalcogen (S, Se, and Te) Terminal Multiple Bonds to Molybdenum, Carbon, and Phosphorus
James E. McDonough, Arjun Mendiratta, John J. Curley, George C. Fortman, Serena Fantasia, Christopher C. Cummins, Elena V. Rybak-Akimova, Steven P. Nolan, and Carl D. Hoff
pp 2133 - 2141; DOI:
10.1021/ic701611p
PDF
Self-Assembly, Structures, and Photophysical Properties of 4,4′-Bipyrazolate-Linked Metallo-Macrocycles with Dimetal Clips
Qing-Fu Sun, Keith Man-Chung Wong, Li-Xia Liu, Hai-Ping Huang, Shu-Yan Yu, Vivian Wing-Wah Yam, Yi-Zhi Li, Yuan-Jiang Pan, and Kai-Chao Yu
pp 2142 - 2154; DOI:
10.1021/ic701344p
PDF
Interaction of Dichloride Iron(II) Clathrochelate with Dimercaptomaleodinitrile: Synthesis of the Precursor Monoribbed-Functionalized Phthalocyaninoclathrochelates and the Unexpected Formation of a New Thiophene-Containing Heterocyclic System in the Ribbed Chelate Fragment of the Clathrochelate Framework
Yan Z. Voloshin, Oleg A. Varzatskii, Alexander S. Belov, Zoya A. Starikova, Kyrill Y. Suponitsky, Valentin V. Novikov, and Yurii N. Bubnov
pp 2155 - 2161; DOI:
10.1021/ic701452g
PDF
Metal-Dependent Reactions of Bulky Metal(II) Amides M[N(SiMe3)2]2 with 3,3′-Disubstituted Binaphthols (HO)2C20H10(SiR3)2-3,3′: Selective Conversion of One Equivalent −OH Group to a Silyl Ether −OSiMe3
Anthony E. Wetherby Jr., Lindy R. Goeller, Antonio G. DiPasquale, Arnold L. Rheingold, and Charles S. Weinert
pp 2162 - 2170; DOI:
10.1021/ic7016984
PDF
Preparation of Ti(IV) Fluoride N-Heterocyclic Carbene Complexes
Grigory B. Nikiforov, Herbert W. Roesky, Peter G. Jones, Jörg Magull, Arne Ringe, and Rainer B. Oswald
pp 2171 - 2179; DOI:
10.1021/ic701751r
PDF
Stoichiometries and Thermodynamic Stabilities for Aqueous Sulfate Complexes of U(VI)
Thomas Vercouter, Pierre Vitorge, Badia Amekraz, and Christophe Moulin
pp 2180 - 2189; DOI:
10.1021/ic701379q
PDF
Factors Affecting the Selectivity of the Oxidation of Methyl p-Toluate by Cobalt(III)
Charles E. Sumner Jr., Kent A. Morrill, Jeff S. Howell, and James Little
pp 2190 - 2195; DOI:
10.1021/ic701634b
PDF
New Members of a Class of Dinitrosyliron Complexes (DNICs): Interconversion and Spectroscopic Discrimination of the Anionic {Fe(NO)2}9 [(NO)2Fe(C3H3N2)2] and [(NO)2Fe(C3H3N2)(SR)] (C3H3N2 = Deprotonated Imidazole; R = tBu, Et, Ph)
Hsiao-Wen Huang, Chih-Chin Tsou, Ting-Shen Kuo, and Wen-Feng Liaw
pp 2196 - 2204; DOI:
10.1021/ic702000y
PDF
Chlorine Dioxide Oxidation of Dihydronicotinamide Adenine Dinucleotide (NADH)
Ekaterina V. Bakhmutova-Albert, Dale W. Margerum, Jameson G. Auer, and Bruce M. Applegate
pp 2205 - 2211; DOI:
10.1021/ic7019022
PDF
Role of Axial Donors in the Ligand Isomerization Processes of Quadruply Bonded Dimolybdenum(II) Compounds
Moumita Majumdar, Sanjib K. Patra, Mukundamurthy Kannan, Kim R. Dunbar, and Jitendra K. Bera
pp 2212 - 2222; DOI:
10.1021/ic702298v
PDF
CuI Complexes with N,N′,S,S′ Scorpionate Ligands: Evidence for Dimer−Monomer Equilibria
Marcello Gennari, Matteo Tegoni, Maurizio Lanfranchi, Maria Angela Pellinghelli, Marco Giannetto, and Luciano Marchiò
pp 2223 - 2232; DOI:
10.1021/ic702108x
PDF

Issue 7


[(Zr6B)Cl12(MeCN)6][Ph4B]·1.6MeCN: An Easily-Accessible Starting Material for Zirconium Cluster Chemistry and [(Zr6B)Cl12(Pyr6)][Ph4B]·2{(PyrH)[Ph4B]}, a First Reaction Product
Henning W. Rohm and Martin Köckerling
pp 2234 - 2236; DOI:
10.1021/ic701684a
PDF
Photochemical Mineralization of Europium, Titanium, and Iron Oxyhydroxide Nanoparticles in the Ferritin Protein Cage
Michael T. Klem, Jesse Mosolf, Mark Young, and Trevor Douglas
pp 2237 - 2239; DOI:
10.1021/ic701740q
PDF
Metal-Assisted In Situ Formation of a Tridentate Acetylacetone Ligand for Complexation of fac-Re(CO)3+ for Radiopharmaceutical Applications
Paul D. Benny, Glenn A. Fugate, Adam O. Barden, Jennifer E. Morley, Elsa Silva-Lopez, and Brendan Twamley
pp 2240 - 2242; DOI:
10.1021/ic701996e
PDF
Stereocontrol by a Pair of Epimeric Sugar-Derived Ligands of the Coordination Sphere of Copper(II) Complexes
Federico Cisnetti, Régis Guillot, Michel Thérisod, Michel Desmadril, and Clotilde Policar
pp 2243 - 2245; DOI:
10.1021/ic702209g
PDF
Water-Soluble 3,7-Dimethyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane (dmoPTA) as a Polydentate Ligand: Synthesis of [RuClCp(PPh3)-μ-dmoPTA-1κP:2κ2N,N′-Co(acac-κ2O,O′)2]·H2O
Adrián Mena-Cruz, Pablo Lorenzo-Luis, Antonio Romerosa, and Manuel Serrano-Ruiz
pp 2246 - 2248; DOI:
10.1021/ic702239w
PDF
Synthesis and Magnetic Properties of a [NiII(TCNE)(NCMe)2−δ][BF4] Magnet (Tc = 40 K)
Konstantin I. Pokhodnya, Victor Dokukin, and Joel S. Miller
pp 2249 - 2251; DOI:
10.1021/ic702336j
PDF
A Coumarin-Derived Fluorescence Probe Selective for Magnesium
Debdas Ray and P. K. Bharadwaj
pp 2252 - 2254; DOI:
10.1021/ic702388z
PDF
Two Cuprous Cyanide Polymorphs: Diamond Net versus 3,4-Connected Net
Xian-Ming Zhang, Ying-Lian Qing, and Hai-Shun Wu
pp 2255 - 2257; DOI:
10.1021/ic702394w
PDF
Phosphaguanidines as Scaffolds for Multimetallic Complexes Containing Metal-Functionalized Phosphines
Joanna Grundy, Natalie E. Mansfield, Martyn P. Coles, and Peter B. Hitchcock
pp 2258 - 2260; DOI:
10.1021/ic7024457
PDF
Terminal Hydride in [FeFe]-Hydrogenase Model Has Lower Potential for H2 Production Than the Isomeric Bridging Hydride
Bryan E. Barton and Thomas B. Rauchfuss
pp 2261 - 2263; DOI:
10.1021/ic800030y
PDF
Diruthenium(II,III) Bis(tetramethyl-1,3-benzenedipropionate) as a Novel Catalyst for tert-Butyl Hydroperoxide Oxygenation
Julia E. Barker and Tong Ren
pp 2264 - 2266; DOI:
10.1021/ic800035w
PDF
Phenomenally High Molar Extinction Coefficient Sensitizer with “Donor−Acceptor” Ligands for Dye-Sensitized Solar Cell Applications
Chongchan Lee, Jun-Ho Yum, Hyunbong Choi, Sang Ook Kang, Jaejung Ko, Robin Humphry-Baker, Michael Grätzel, and Md. K. Nazeeruddin
pp 2267 - 2273; DOI:
10.1021/ic700996x
PDF
Theoretical Study on (Al2O3)n (n = 1–10 and 30) Fullerenes and H2 Adsorption Properties
Jiao Sun, Wen-Cai Lu, Wei Zhang, Li-Zhen Zhao, Ze-Sheng Li, and Chia-Chung Sun
pp 2274 - 2279; DOI:
10.1021/ic7011364
PDF
Molecular Architectures for Trimetallic d/f/d Complexes: Structural and Magnetic Properties of a LnNi2 Core
Cheri A. Barta, Simon R. Bayly, Paul W. Read, Brian O. Patrick, Robert C. Thompson, and Chris Orvig
pp 2280 - 2293; DOI:
10.1021/ic701612e
PDF
Molecular Architectures for Trimetallic d/f/d Complexes: Magnetic Studies of a LnCu2 Core
Cheri A. Barta, Simon R. Bayly, Paul W. Read, Brian O. Patrick, Robert C. Thompson, and Chris Orvig
pp 2294 - 2302; DOI:
10.1021/ic701613x
PDF
Nickel and Cobalt Hexamethylentetramine Complexes (NO3)2Me(H2O)6(HMTA)2·4H2O (Me = Co2+, Ni2+): New Molecular Precursors for the Preparation of Metal Dispersions
Pavel Afanasiev, Sandra Chouzier, Tivadar Czeri, Guillaume Pilet, Christophe Pichon, Magalie Roy, and Michel Vrinat
pp 2303 - 2311; DOI:
10.1021/ic7013013
PDF
Theoretical Studies on Structures and Spectroscopic Properties of Photoelectrochemical Cell Ruthenium Sensitizers, [Ru(Hmtcterpy)(NCS)3]n (m = 0, 1, 2, and 3; n = 4, 3, 2, and 1)
Ming-Xia Li, Xin Zhou, Bao-Hui Xia, Hong-Xing Zhang, Qing-Jiang Pan, Tao Liu, Hong-Gang Fu, and Chia-Chung Sun
pp 2312 - 2324; DOI:
10.1021/ic070139b
PDF
Cobalt(II)/Nickel(II)-Centered Keggin-Type Heteropolymolybdates: Syntheses, Crystal Structures, Magnetic and Electrochemical Properties
Guang-Gang Gao, Lin Xu, Wen-Ju Wang, Xiao-Shu Qu, Hong Liu, and Yan-Yan Yang
pp 2325 - 2333; DOI:
10.1021/ic700797v
PDF
Structure and Magnetic Properties of the Hybrid System Copper(II) μ2-2,2′-Bipyridine-3-carboxylate-N,N′:O2-phosphate-O,O
Y. Moreno, G. Cárdenas, A. Tissot, O. Peña, J.-Y. Pivan, and R. Baggio
pp 2334 - 2337; DOI:
10.1021/ic701137d
PDF
Homoleptic, Four-Coordinate Azadipyrromethene Complexes of d10 Zinc and Mercury
Thomas S. Teets, David V. Partyka, James B. Updegraff III, and Thomas G. Gray
pp 2338 - 2346; DOI:
10.1021/ic701190g
PDF
Effect of π-Conjugated Length of Bridging Ligand on the Optoelectronic Properties of Platinum(II) Dimers
Li-Li Shi, Yi Liao, Guo-Chun Yang, Zhong-Min Su, and Shan-Shan Zhao
pp 2347 - 2355; DOI:
10.1021/ic7018154
PDF
La6Br10Fe: A La6Fe Octahedron with a Mixed M6X12/M6X8 Type Environment
Chong Zheng, Hansjürgen Mattausch, Constantin Hoch, and Arndt Simon
pp 2356 - 2361; DOI:
10.1021/ic701229q
PDF
Characterization and Properties of Novel Infrared Nonlinear Optical Crystal CsGe(BrxCl1−x)3
Zhi-Guang Lin, Li-Chuan Tang, and Chang-Pin Chou
pp 2362 - 2367; DOI:
10.1021/ic7011777
PDF
Structural Characterization, Solution Studies, and DFT Calculations on a Series of Binuclear Gold(III) Oxo Complexes: Relationships to Biological Properties
Chiara Gabbiani, Angela Casini, Luigi Messori, Annalisa Guerri, Maria Agostina Cinellu, Giovanni Minghetti, Maddalena Corsini, Claudia Rosani, Piero Zanello, and Massimiliano Arca
pp 2368 - 2379; DOI:
10.1021/ic701254s
PDF
Refining the Active Site Structure of Iron−Iron Hydrogenase Using Computational Infrared Spectroscopy
Jesse W. Tye, Marcetta Y. Darensbourg, and Michael B. Hall
pp 2380 - 2388; DOI:
10.1021/ic7013732
PDF
Wavelength-Dependent Photofragmentation of a Mixed-Ligand Cyclometalated Platinum(II) Coordination Compound in a Molecular Beam
Franklin P. Ow, Peter I. Djurovich, Mark E. Thompson, and Jeffrey I. Zink
pp 2389 - 2395; DOI:
10.1021/ic701383y
PDF
Imidazole-Substituted Oxoverdazyl Radical As a Mediator of Intramolecular and Intermolecular Exchange Interaction
Lucie Norel, Fabrice Pointillart, Cyrille Train, Lise-Marie Chamoreau, Kamal Boubekeur, Yves Journaux, Aaron Brieger, and David J. R. Brook
pp 2396 - 2403; DOI:
10.1021/ic701400b
PDF
Characterization of the Piezochromic Behavior of Some Members of the CuMo1−xWxO4 Series
M. Gaudon, A. E. Thiry, A. Largeteau, P. Deniard, S. Jobic, J. Majimel, and A. Demourgues
pp 2404 - 2410; DOI:
10.1021/ic702282t
PDF
Photoregulated Fluorescence Switching in Axially Coordinated Tin(IV) Porphyrinic Dithienylethene
Hee Jung Kim, Joon Hee Jang, Hyunbong Choi, Taegweon Lee, Jaejung Ko, Minjoong Yoon, and Hee-Joon Kim
pp 2411 - 2415; DOI:
10.1021/ic701390m
PDF
Reactivity and Spectroscopy of the {Ru(DMAP)5} Fragment: An {Ru(NH3)5} Analogue
Melina B. Rossi, Oscar E. Piro, Eduardo E. Castellano, Pablo Alborés, and Luis M. Baraldo
pp 2416 - 2427; DOI:
10.1021/ic7016352
PDF
Identification of Bismuth-Thiolate-Carboxylate Clusters by Electrospray Ionization Mass Spectrometry
Heather A. Phillips and Neil Burford
pp 2428 - 2441; DOI:
10.1021/ic701657r
PDF
Self-Assembly of Organic–Inorganic Hybrid Materials Constructed from Eight-Connected Coordination Polymer Hosts with Nanotube Channels and Polyoxometalate Guests As Templates
Xiuli Wang, Yanfeng Bi, Baokuan Chen, Hongyan Lin, and Guocheng Liu
pp 2442 - 2448; DOI:
10.1021/ic7014513
PDF
Combined Ligand Field and Density Functional Theory Analysis of the Magnetic Anisotropy in Oligonuclear Complexes Based on FeIII−CN−MII Exchange-Coupled Pairs
Mihail Atanasov, Peter Comba, and Claude A. Daul
pp 2449 - 2463; DOI:
10.1021/ic701702x
PDF
Modulated Misfit Structure of the Thermoelectric [Bi0.84CaO2]2[CoO2]1.69 Cobalt Oxide
Hervé Muguerra, Dominique Grebille, Emmanuel Guilmeau, and Rudi Cloots
pp 2464 - 2471; DOI:
10.1021/ic701717f
PDF
Crystal Growth, Structure, and Physical Properties of SmCu4Ga8
Jung Young Cho, Cigdem Capan, D. P. Young, and Julia Y. Chan
pp 2472 - 2476; DOI:
10.1021/ic7017192
PDF
Hydrogen Storage in Mesoporous Titanium Oxide−Alkali Fulleride Composites
Xin Hu, Michel Trudeau, and David M. Antonelli
pp 2477 - 2484; DOI:
10.1021/ic701762e
PDF
Chiral Tetranuclear μ3-Alkoxo-Bridged Copper(II) Complex with 2 + 4 Cubane-Like Cu4O4 Core Framework and Ferromagnetic Ground State
Anja Burkhardt, Eike T. Spielberg, Helmar Görls, and Winfried Plass
pp 2485 - 2493; DOI:
10.1021/ic701777t
PDF
On the Performance of Ligand Field Molecular Mechanics for Model Complexes Containing the Peroxido-Bridged [Cu2O2]2+ Center
Christian Diedrich and Robert J. Deeth
pp 2494 - 2506; DOI:
10.1021/ic701803g
PDF
Highly Efficient Sensitized Red Emission from Europium (III) in Ir−Eu Bimetallic Complexes by 3MLCT Energy Transfer
Fang-Fang Chen, Zu-Qiang Bian, Zhi-Wei Liu, Dao-Bo Nie, Zhu-Qi Chen, and Chun-Hui Huang
pp 2507 - 2513; DOI:
10.1021/ic701817n
PDF
Simplified Speciation and Improved Phosphodiesterolytic Activity of Hydroxo Complexes of Trivalent Lanthanides in Aqueous DMSO
Irma Sánchez-Lombardo and Anatoly K. Yatsimirsky
pp 2514 - 2525; DOI:
10.1021/ic701846e
PDF
Incorporation of Substitutionally Labile [VIII(CN)6]3− into Prussian Blue Type Magnetic Materials
Kendric J. Nelson and Joel S. Miller
pp 2526 - 2533; DOI:
10.1021/ic701845p
PDF
Tris(phosphino)borato Silver(I) Complexes as Precursors for Metallic Silver Aerosol-Assisted Chemical Vapor Deposition
Matthew N. McCain, Sven Schneider, Michael R. Salata, and Tobin J. Marks
pp 2534 - 2542; DOI:
10.1021/ic701852x
PDF
Structural, Photophysical, and Catalytic Properties of Au(I) Complexes with 4-Substituted Pyridines
J. C. Y. Lin, S. S. Tang, C. Sekhar Vasam, W. C. You, T. W. Ho, C. H. Huang, B. J. Sun, C. Y. Huang, C. S. Lee, W. S. Hwang, A. H. H. Chang, and Ivan J. B. Lin
pp 2543 - 2551; DOI:
10.1021/ic701872f
PDF
Spin-Crossover Behavior in Cyanide-bridged Iron(II)−Gold(I) Bimetallic 2D Hofmann-like Metal−Organic Frameworks
Gloria Agustí, M. Carmen Muñoz, Ana B. Gaspar, and José A. Real
pp 2552 - 2561; DOI:
10.1021/ic701865k
PDF
Four Isomorphous Phosphates AM3P4O14 (A = Sr, Ba; M = Co, Mn) with Antiferromagnetic−Antiferromagnetic−Ferromagnetic Trimerized Chains, Showing 1/3 Quantum Magnetization Plateaus Only in the Manganese(II) System
Tao Yang, Yan Zhang, Sihai Yang, Guobao Li, Ming Xiong, Fuhui Liao, and Jianhua Lin
pp 2562 - 2568; DOI:
10.1021/ic702346e
PDF
An Experimental and Theoretical Study of the Variation of 4f Hybridization Across the La1−xCexIn3 Series
D. Gout, O. Gourdon, E. D. Bauer, F. Ronning, J. D. Thompson, and Th. Proffen
pp 2569 - 2575; DOI:
10.1021/ic701930j
PDF
Metal Effects on Electronic Structures of Directly Linked Tribenzotetraazachlorin-Fullerene Conjugates
Takamitsu Fukuda, Satoshi Masuda, Naoaki Hashimoto, and Nagao Kobayashi
pp 2576 - 2580; DOI:
10.1021/ic701840r
PDF
Thermochemistry of Gd2BaCuO5 and LuBa2Cu3Ox
Nata I. Matskevich, Thomas Wolf, and Yurii I. Pochivalov
pp 2581 - 2584; DOI:
10.1021/ic701875h
PDF
Synthesis, Characterization, and Reaction of Aluminum Halide Amides Supported by a Bulky β-Diketiminato Ligand
Ying Yang, Thomas Schulz, Michael John, Arne Ringe, Herbert W. Roesky, Dietmar Stalke, Jörg Magull, and Hongqi Ye
pp 2585 - 2592; DOI:
10.1021/ic701896r
PDF
Assessment of Macrocyclic Triamine Ligands As Synthons for Organometallic 99mTc Radiopharmaceuticals
Keisuke Suzuki, Naomi Shimmura, Khajadpai Thipyapong, Tomoya Uehara, Hiromichi Akizawa, and Yasushi Arano
pp 2593 - 2600; DOI:
10.1021/ic7019654
PDF
Convenient Route Leading to Neutral fac-M(CO)3(NNO) Complexes (M = Re, 99mTc) Coupled to Amine Pharmacophores
Aris Chiotellis, Charalambos Tsoukalas, Maria Pelecanou, Catherine Raptopoulou, Aris Terzis, Minas Papadopoulos, Zetta Papadopoulou-Daifoti, and Ioannis Pirmettis
pp 2601 - 2607; DOI:
10.1021/ic7019268
PDF
Migratory Insertion of the R2P Group into a Nitrogen−Nitrogen Bond − A Novel Type of Rearrangement in Phosphorus−Nitrogen Ligand Chemistry. 3. The Rearrangement of Triphosphinohydrazide Ligand −N(PPh2)−N(PPh2)2 to Triphosphazenide Anion {[(Ph2P−N]2PPh2} in the Coordination Sphere of Divalent Cobalt and Nickel
Vyacheslav V. Sushev, Natalia V. Belina, Georgy K. Fukin, Yuriy A. Kurskiy, Alexander N. Kornev, and Gleb A. Abakumov
pp 2608 - 2612; DOI:
10.1021/ic701954k
PDF
Complexities in the Ring-Opening Polymerization of Lactide by Chiral Salen Aluminum Initiators
Malcolm H. Chisholm, Judith C. Gallucci, Keith T. Quisenberry, and Zhiping Zhou
pp 2613 - 2624; DOI:
10.1021/ic7019704
PDF
Crystal Structures and Thermal and Electrical Properties of the New Silver (poly)Chalcogenide Halides Ag23Te12Cl and Ag23Te12Br
Stefan Lange, Melanie Bawohl, and Tom Nilges
pp 2625 - 2633; DOI:
10.1021/ic701988u
PDF
Evolution of the Crystal Structure of RVO3 (R = La, Ce, Pr, Nd, Tb, Ho, Er, Tm, Yb, Lu, Y) Perovskites from Neutron Powder Diffraction Data
M. J. Martínez-Lope, J. A. Alonso, M. Retuerto, and M. T. Fernández-Díaz
pp 2634 - 2640; DOI:
10.1021/ic701969q
PDF
Inosylyl(3′→5′)inosine (IpI). Acid–Base and Metal Ion-Binding Properties of a Dinucleoside Monophosphate in Aqueous Solution
Bernd Knobloch, Andrzej Okruszek, and Helmut Sigel
pp 2641 - 2648; DOI:
10.1021/ic701976v
PDF
Probing Variable Amine/Amide Ligation in NiIIN2S2 Complexes Using Sulfur K-Edge and Nickel L-Edge X-ray Absorption Spectroscopies: Implications for the Active Site of Nickel Superoxide Dismutase
Jason Shearer, Ahmad Dehestani, and Franklin Abanda
pp 2649 - 2660; DOI:
10.1021/ic7019878
PDF
Structure and Electrons in Mayenite Electrides
Luis Palacios, Aurelio Cabeza, Sebastián Bruque, Santiago García-Granda, and Miguel A. G. Aranda
pp 2661 - 2667; DOI:
10.1021/ic7021193
PDF
High-Pressure Studies of (Mg0.9Fe0.1)2SiO4 Olivine Using Raman Spectroscopy, X-ray Diffraction, and Mössbauer Spectroscopy
J. Rouquette, I. Kantor, C. A. McCammon, V. Dmitriev, and L. S. Dubrovinsky
pp 2668 - 2673; DOI:
10.1021/ic701983w
PDF
Computational Study of the Factors Controlling Enantioselectivity in Ruthenium(II) Hydrogenation Catalysts
Devis Di Tommaso, Samuel A. French, Antonio Zanotti-Gerosa, Fred Hancock, Erika J. Palin, and C. Richard A. Catlow
pp 2674 - 2687; DOI:
10.1021/ic701981v
PDF
Role of the Phosphine Ligands on the Stabilization of Monoadducts of the Model Nucleobases 1-Methylcytosine and 9-Methylguanine in Platinum(II) Complexes
Diego Montagner, Ennio Zangrando, and Bruno Longato
pp 2688 - 2695; DOI:
10.1021/ic7020319
PDF
Silver Delafossite Oxides
William C. Sheets, Evan S. Stampler, Mariana I. Bertoni, Makoto Sasaki, Tobin J. Marks, Thomas O. Mason, and Kenneth R. Poeppelmeier
pp 2696 - 2705; DOI:
10.1021/ic702197h
PDF
Ab Initio Study on the Electronic, Magnetic, and Mechanical Properties of CaCu3V4O12
Hongping Xiang and Zhijian Wu
pp 2706 - 2709; DOI:
10.1021/ic702042k
PDF
Spontaneous Resolution of a Racemic Nickel(II) Complex and Helicity Induction via Hydrogen Bonding: The Effect of Chiral Building Blocks on the Helicity of One-Dimensional Chains
Guang-Chuan Ou, Long Jiang, Xiao-Long Feng, and Tong-Bu Lu
pp 2710 - 2718; DOI:
10.1021/ic7021424
PDF
Synthesis and Characterization of a Novel Macrocyclic Chelator with 3-Hydroxy-4-Pyrone Chelating Arms and Its Complexes with Medicinally Important Metals
Chang-Tong Yang, Subramanya G. Sreerama, Wen-Yuan Hsieh, and Shuang Liu
pp 2719 - 2727; DOI:
10.1021/ic7022506
PDF
Dual Shell-like Magnetic Clusters Containing NiII and LnIII (Ln = La, Pr, and Nd) Ions
Xiang-Jian Kong, Yan-Ping Ren, La-Sheng Long, Zhiping Zheng, Gary Nichol, Rong-Bin Huang, and Lan-Sun Zheng
pp 2728 - 2739; DOI:
10.1021/ic702079e
PDF
Oxidation of an o-Iminobenzosemiquinone Radical Ligand by Molecular Bromine: Structural, Spectroscopic, and Reactivity Studies of a Copper(II) o-Iminobenzoquinone Complex
Chandan Mukherjee, Thomas Weyhermüller, Eberhard Bothe, and Phalguni Chaudhuri
pp 2740 - 2746; DOI:
10.1021/ic702256p
PDF
Design and Synthesis of A Caged Zn2+ Probe, 8-Benzenesulfonyloxy-5-N,N-dimethylaminosulfonylquinolin-2-ylmethyl-pendant 1,4,7,10-Tetraazacyclododecane, and Its Hydrolytic Uncaging upon Complexation with Zn2+
Shin Aoki, Kazusa Sakurama, Ryosuke Ohshima, Nanako Matsuo, Yasuyuki Yamada, Ryoko Takasawa, Sei-ichi Tanuma, Kei Takeda, and Eiichi Kimura
pp 2747 - 2754; DOI:
10.1021/ic702002m
PDF
A Highly Modular and Convergent Approach for the Synthesis of Stimulant-Responsive Heteroligated Cofacial Porphyrin Tweezer Complexes
Christopher G. Oliveri, SonBinh T. Nguyen, and Chad A. Mirkin
pp 2755 - 2763; DOI:
10.1021/ic702150y
PDF
Bi-, Tetra-, and Hexanuclear AuI and Binuclear AgI Complexes and AgI Coordination Polymers Containing Phenylaminobis(phosphonite), PhN{P(OC6H4OMe-o)2}2, and Pyridyl Ligands
Chelladurai Ganesamoorthy, Maravanji S. Balakrishna, Joel T. Mague, and Heikki M. Tuononen
pp 2764 - 2776; DOI:
10.1021/ic702133f
PDF
Phosphonate- and Ester-Substituted 2-Cyanoethylene-1,1-Dithiolate Clusters of Zinc: Aerial CO2 Fixation and Unusual Binding Patterns
Bijay Sarkar, Ben-Jie Liaw, Ching-Shiang Fang, and C. W. Liu
pp 2777 - 2785; DOI:
10.1021/ic702126k
PDF
Comparing Main Group and Transition-Metal Square-Planar Complexes of the Diselenoimidodiphosphinate Anion: A Solid-State NMR Investigation of M[N(iPr2PSe)2]2 (M = Se, Te; Pd, Pt)
Bryan A. Demko and Roderick E. Wasylishen
pp 2786 - 2797; DOI:
10.1021/ic7019999
PDF
Synthesis, Characterization and Stat3 Inhibitory Properties of the Prototypical Platinum(IV) Anticancer Drug, [PtCl3(NO2)(NH3)2] (CPA-7)
Shalyn L. Littlefield, Michael C. Baird, Aikaterini Anagnostopoulou, and Leda Raptis
pp 2798 - 2804; DOI:
10.1021/ic702057q
PDF
Visible Light-Driven Electron Transfer and Hydrogen Generation Catalyzed by Bioinspired [2Fe2S] Complexes
Yong Na, Mei Wang, Jingxi Pan, Pan Zhang, Björn Åkermark, and Licheng Sun
pp 2805 - 2810; DOI:
10.1021/ic702010w
PDF
Preparation, Characterization, and Photophysical Properties of Pt−M (M = Ru, Re) Heteronuclear Complexes with 1,10-Phenanthrolineethynyl Ligands
Yang Fan, Li-Yi Zhang, Feng-Rong Dai, Lin-Xi Shi, and Zhong-Ning Chen
pp 2811 - 2819; DOI:
10.1021/ic702055n
PDF
Conformer Distribution in (cis-1,4-DACH)bis(guanosine-5′-phosphate)platinum(II) Adducts: A Reliable Model for DNA Adducts of Antitumoral Cisplatin
Rosa Ranaldo, Nicola Margiotta, Francesco P. Intini, Concetta Pacifico, and Giovanni Natile
pp 2820 - 2830; DOI:
10.1021/ic702202x
PDF
Polyols as Scaffolds in the Development of Ion-Selective Polymer-Supported Reagents: The Effect of Auxiliary Groups on the Mechanism of Metal Ion Complexation
Spiro D. Alexandratos and Xiaoping Zhu
pp 2831 - 2836; DOI:
10.1021/ic702263x
PDF
Zinc, Cadmium, and Mercury 1,2-Benzenedithiolates with Intramolecular NH···S Hydrogen Bonds
Koji Baba, Taka-aki Okamura, Hitoshi Yamamoto, Tetsuo Yamamoto, and Norikazu Ueyama
pp 2837 - 2848; DOI:
10.1021/ic702037k
PDF
A [4Fe−4S] Cluster Dimer Bridged by Bis(2,2′:6′,2″-terpyridine-4′-thiolato)iron(II)
Erwin P. L. van der Geer, Gerard van Koten, Robertus J. M. Klein Gebbink, and Bart Hessen
pp 2849 - 2857; DOI:
10.1021/ic702062q
PDF
Size Matters: Room Temperature P−C Bond Formation Through C−H Activation in m-Terphenyldiiodophosphines
Armando A. Diaz, Bryan Buster, Daniel Schomisch, Masood A. Khan, J. Clayton Baum, and Rudolf J. Wehmschulte
pp 2858 - 2863; DOI:
10.1021/ic702105s
PDF
Unexpected C−H Activation of Ru(II)−Dithiomaltol Complexes upon Oxidation
Malin Backlund, Joseph Ziller, and Patrick J. Farmer
pp 2864 - 2870; DOI:
10.1021/ic7021962
PDF
Stereochemistry and Spin State in Four-Coordinate Transition Metal Compounds
Jordi Cirera, Eliseo Ruiz, and Santiago Alvarez
pp 2871 - 2889; DOI:
10.1021/ic702276k
PDF
Rhenium Complexes with Triazine Derivatives Formed from Semicarbazones and Thiosemicarbazones
Elena López-Torres and Ulrich Abram
pp 2890 - 2896; DOI:
10.1021/ic702326v
PDF
Tuning the Redox Properties of Manganese(II) and Its Implications to the Electrochemistry of Manganese and Iron Superoxide Dismutases
Martin Sjödin, Jessica Gätjens, Leandro C. Tabares, Pierre Thuéry, Vincent L. Pecoraro, and Sun Un
pp 2897 - 2908; DOI:
10.1021/ic702428s
PDF

Issue 8


Promoting the Formation and Stabilization of G-Quadruplex by Dinuclear RuII Complex Ru2(obip)L4
Shuo Shi, Jie Liu, Tianming Yao, Xiaoting Geng, Lingfeng Jiang, Qingyuan Yang, Lin Cheng, and Liangnian Ji
pp 2910 - 2912; DOI:
10.1021/ic7021209
PDF
Anion-Modulated Reversible Conversion of Molecular Assembly between a Macrocycle and a Linear Chain
Huaze Dong, Juan Yang, Xia Liu, and Shaohua Gou
pp 2913 - 2915; DOI:
10.1021/ic702157r
PDF
Model Studies of Azide Binding to Functional Analogues of CcO
James P. Collman, Abhishek Dey, Richard A. Decréau, and Ying Yang
pp 2916 - 2918; DOI:
10.1021/ic702294n
PDF
New Gadolinium Complex with Efficient Hydrolase-like Activity: A 100-Million-Fold Rate Enhancement in Diester Hydrolysis
Maryene A. Camargo, Ademir Neves, Adailton J. Bortoluzzi, Bruno Szpoganicz, Adriano Martendal, Michael Murgu, Franciele L. Fischer, Hernán Terenzi, and Patricia Cardoso Severino
pp 2919 - 2921; DOI:
10.1021/ic702167p
PDF
Extending the Coordination Chemistry of 1,3,5-Triaza-7-phosphaadamantane (PTA) to Cobalt Centers: First Examples of Co-PTA Complexes and of a Metal Complex with the PTA Oxide Ligand
Łukasz Jaremko, Alexander M. Kirillov, Piotr Smoleński, Tadeusz Lis, and Armando J. L. Pombeiro
pp 2922 - 2924; DOI:
10.1021/ic702373b
PDF
Versatile Approach toward the Self-Assembly of Heteromultimetallic Salen Structures
Sander J. Wezenberg, Eduardo C. Escudero-Adán, Jordi Benet-Buchholz, and Arjan W. Kleij
pp 2925 - 2927; DOI:
10.1021/ic800033v
PDF
Lanthanide-Loaded Paramagnetic Liposomes as Switchable Magnetically Oriented Nanovesicles
Daniela Delli Castelli, Enzo Terreno, Carla Carrera, Giovanni B. Giovenzana, Roberta Mazzon, Simona Rollet, Massimo Visigalli, and Silvio Aime
pp 2928 - 2930; DOI:
10.1021/ic702501y
PDF
Unprecedented Dinuclear Tin Derivative of Deprotonated β-Cyclodextrins
Shun-Li Li, Ya-Qian Lan, Jian-Fang Ma, Jin Yang, Min Zhang, and Zhong-Min Su
pp 2931 - 2933; DOI:
10.1021/ic8000784
PDF
Ultrasensitive SERS Nanoprobes for Hazardous Metal Ions Based on Trimercaptotriazine-Modified Gold Nanoparticles
Vitor M. Zamarion, Ronaldo A. Timm, Koiti Araki, and Henrique E. Toma
pp 2934 - 2936; DOI:
10.1021/ic800122v
PDF
V4O10: Spectroscopic Fingerprint of a Well-Defined, Molecular Metaloxo Aggregate
Christian Herwig and Christian Limberg
pp 2937 - 2939; DOI:
10.1021/ic8002146
PDF
Helical Supramolecular Assemblies of {2,4,6-[Cp∗Rh(E2-1,2-C2B10H10)(NC5H4CH2S)]3(triazine)} (E = S, Se) Shaped by Cp∗−Toluene−Cp∗ π-Stacking Forces and BH−Pyridine Hydrogen Bonding
Guo-Liang Wang, Yue-Jian Lin, Olivier Blacque, Heinz Berke, and Guo-Xin Jin
pp 2940 - 2942; DOI:
10.1021/ic800105h
PDF
First Structural Evidence of Actinide−Nitrite Coordination
Grigory B. Andreev, Nina A. Budantseva, Ivan G. Tananaev, and Boris F. Myasoedov
pp 2943 - 2945; DOI:
10.1021/ic800158f
PDF
Lewis Acid and Base Sensing by Platinum(II) Polypyridines
Robert McGuire Jr., Michael H. Wilson, John J. Nash, Phillip E. Fanwick, and David R. McMillin
pp 2946 - 2948; DOI:
10.1021/ic800220r
PDF
Ni[(EPiPr2)2N]2 Complexes: Stereoisomers (E = Se) and Square-Planar Coordination (E = Te)
Nikolaos Levesanos, Stuart D. Robertson, Dimitrios Maganas, Catherine P. Raptopoulou, Aris Terzis, Panayotis Kyritsis, and Tristram Chivers
pp 2949 - 2951; DOI:
10.1021/ic800272v
PDF
Phosphinoarsonium and Diarsonium Cations from Chloride-Abstraction-Induced Pnictogen Coupling
Eamonn Conrad, Neil Burford, Robert McDonald, and Michael J. Ferguson
pp 2952 - 2954; DOI:
10.1021/ic800287e
PDF
Photophysics of Diplatinum Polyynediyl Oligomers: Chain Length Dependence of the Triplet State in sp Carbon Chains
Richard T. Farley, Qinglin Zheng, John A. Gladysz, and Kirk S. Schanze
pp 2955 - 2963; DOI:
10.1021/ic701220t
PDF
Gold(I)−Dithioether Supramolecular Polymers: Synthesis, Characterization, and Luminescence
Mohamed Osman Awaleh, François Baril-Robert, Christian Reber, Antonella Badia, and François Brisse
pp 2964 - 2974; DOI:
10.1021/ic701275k
PDF
Structural Model Studies for the Peroxo Intermediate P and the Reaction Pathway from P → Q of Methane Monooxygenase Using Broken-Symmetry Density Functional Calculations
Wen-Ge Han and Louis Noodleman
pp 2975 - 2986; DOI:
10.1021/ic701194b
PDF
Species Distribution and Coordination of Uranyl Chloro Complexes in Acetonitrile
Christoph Hennig, Kelly Servaes, Peter Nockemann, Kristof Van Hecke, Luc Van Meervelt, Johan Wouters, Linda Fluyt, Christiane Görller-Walrand, and Rik Van Deun
pp 2987 - 2993; DOI:
10.1021/ic7014435
PDF
Novel Iron(III) Porphyrazine Complex. Complex Speciation and Reactions with NO and H2O2
Alexander Theodoridis, Joachim Maigut, Ralph Puchta, Evgeny V. Kudrik, and Rudi van Eldik
pp 2994 - 3013; DOI:
10.1021/ic702041g
PDF
Investigation of Primary Crystallite Sizes in Nanocrystalline ZnS Powders: Comparison of Microwave Assisted with Conventional Synthesis Routes
Thomas Rath, Birgit Kunert, Roland Resel, Gerhard Fritz-Popovski, Robert Saf, and Gregor Trimmel
pp 3014 - 3022; DOI:
10.1021/ic7017715
PDF
Molecular Structures of the Digermanes Me2XGeGeXMe2 (X = Me, Cl, and H): An Ab Initio Study Combined with Experimental Investigation by Raman Spectroscopy and Gas Electron Diffraction
Margit Hölbling, Sarah L. Masters (née Hinchley), Michaela Flock, Judith Baumgartner, Karl Hassler, Heather E. Robertson, and Derek A. Wann
pp 3023 - 3033; DOI:
10.1021/ic7018764
PDF
Ru and Os Complexes Containing a P,N-Donor Heterotopic Ligand: The Effect of Solvent on Stereochemistry
Serin L. Dabb, Barbara A. Messerle, Matthew K. Smith, and Anthony C. Willis
pp 3034 - 3044; DOI:
10.1021/ic7019044
PDF
Binuclear Iron Carbonyl Nitrosyls: Bridging Nitrosyls versus Bridging Carbonyls
Hongyan Wang, Yaoming Xie, R. Bruce King, and Henry F. Schaefer III
pp 3045 - 3055; DOI:
10.1021/ic702077s
PDF
Investigations of Acidity and Nucleophilicity of Diphenyldithiophosphinate Ligands Using Theory and Gas-Phase Dissociation Reactions
Christopher M. Leavitt, Garold L. Gresham, Michael T. Benson, Jean-Jacques Gaumet, Dean R. Peterman, John R. Klaehn, Megan Moser, Frederic Aubriet, Michael J. Van Stipdonk, and Gary S. Groenewold
pp 3056 - 3064; DOI:
10.1021/ic7020897
PDF
A New Approach to Synthesis of Layered Fluorites Containing Molecular Anions: Synthesis of Ln2O2CO3, K(LnO)CO3, and Ln2O2CrO4 via Metathesis Reactions
Dmitri O. Charkin, Roman O. Grischenko, Arman A. Sadybekov, Richard J. Goff, and Philip Lightfoot
pp 3065 - 3071; DOI:
10.1021/ic701558m
PDF
Electronic Structure and Metal−Metal Interactions in Trinuclear Face-Shared [M3X12]3− (M = Mo, W; X = F, Cl, Br, I) Systems
Germán Cavigliasso and Robert Stranger
pp 3072 - 3083; DOI:
10.1021/ic702070z
PDF
{[P(o-tolyl)3]Br}2[Cu2Br6](Br2)–An Ionic Compound Containing Molecular Bromine
Alexander Okrut and Claus Feldmann
pp 3084 - 3087; DOI:
10.1021/ic7021038
PDF
NiII-Mediated Coupling between Iminoisoindolinones and Nitriles Leading to Unsymmetrical 1,3,5-Triazapentadienato Complexes
Pavel V. Gushchin, Konstantin V. Luzyanin, Maximilian N. Kopylovich, Matti Haukka, Armando J. L. Pombeiro, and Vadim Yu. Kukushkin
pp 3088 - 3094; DOI:
10.1021/ic702131k
PDF
Synthesis and Characterization of Luminescent Zinc(II) and Cadmium(II) Complexes with N,S-Chelating Schiff Base Ligands
Tatsuya Kawamoto, Masato Nishiwaki, Yasutaka Tsunekawa, Koichi Nozaki, and Takumi Konno
pp 3095 - 3104; DOI:
10.1021/ic7020758
PDF
Highly Luminescent Lanthanide Complexes of 1-Hydroxy-2-pyridinones
Evan G. Moore, Jide Xu, Christoph J. Jocher, Ingrid Castro-Rodriguez, and Kenneth N. Raymond
pp 3105 - 3118; DOI:
10.1021/ic702144n
PDF
Synthesis, Redox, and Amphiphilic Properties of Responsive Salycilaldimine-Copper(II) Soft Materials
Sarmad Sahiel Hindo, Rajendra Shakya, N. S. Rannulu, Marco M. Allard, Mary Jane Heeg, M. T. Rodgers, Sandro R. P. da Rocha, and Claudio N. Verani
pp 3119 - 3127; DOI:
10.1021/ic702233n
PDF
SrAu4In4 and Sr4Au9In13: Polar Intermetallic Structures with Cations in Augmented Hexagonal Prismatic Environments
Andriy Palasyuk, Jing-Cao Dai, and John D. Corbett
pp 3128 - 3134; DOI:
10.1021/ic702145y
PDF
Formation of Indium Nitride Nanorods within Mesoporous Silica SBA-15
Shih-Chieh Chang and Michael H. Huang
pp 3135 - 3139; DOI:
10.1021/ic702155w
PDF
Fabrication of Hierarchical ZnO Architectures and Their Superhydrophobic Surfaces with Strong Adhesive Force
Yanbo Li, Maojun Zheng, Li Ma, Miao Zhong, and Wenzhong Shen
pp 3140 - 3143; DOI:
10.1021/ic7021598
PDF
3D Coordination Networks Based on Supramolecular Chains as Building Units: Synthesis and Crystal Structures of Two Silver(I) Pyridyldiethynides
Tianle Zhang, Jianxi Kong, Yuejie Hu, Xianggao Meng, Hongbing Yin, Dongshuang Hu, and Changpeng Ji
pp 3144 - 3149; DOI:
10.1021/ic702230h
PDF
Complexation of Uranium(VI) with Aromatic Acids in Aqueous Solution: A Combined Computational and Experimental Study
Jonas Wiebke, Anna Moritz, Maja Glorius, Henry Moll, Gert Bernhard, and Michael Dolg
pp 3150 - 3157; DOI:
10.1021/ic702162r
PDF
Anion Recognition of Chloride and Bromide by a Rigid Dicobalt(II) Cryptate
Jia-Mei Chen, Xiao-Mei Zhuang, Li-Zi Yang, Long Jiang, Xiao-Long Feng, and Tong-Bu Lu
pp 3158 - 3165; DOI:
10.1021/ic702143d
PDF
Reactivity of an Aminopyridine [LMnII]2+ Complex with H2O2. Detection of Intermediates at Low Temperature
Sihem Groni, Pierre Dorlet, Guillaume Blain, Sophie Bourcier, Régis Guillot, and Elodie Anxolabéhère-Mallart
pp 3166 - 3172; DOI:
10.1021/ic702238z
PDF
Influence of Volatile Chlorides on the Molten Salt Synthesis of Ternary Oxide Nanorods and Nanoparticles
Per Martin Rørvik, Tone Lyngdal, Ragnhild Sæterli, Antonius T. J. van Helvoort, Randi Holmestad, Tor Grande, and Mari-Ann Einarsrud
pp 3173 - 3181; DOI:
10.1021/ic702207a
PDF
An Effective Oxidation Route to Blue Emission CdSe Quantum Dots
Liping Liu, Qing Peng, and Yadong Li
pp 3182 - 3187; DOI:
10.1021/ic702203c
PDF
Heterometallic Integer-Spin Analogues of S = 9/2 Mn4 Cubane Single-Molecule Magnets
Patrick L. Feng, Christopher C. Beedle, Changhyun Koo, Wolfgang Wernsdorfer, Motohiro Nakano, Stephen Hill, and David N. Hendrickson
pp 3188 - 3204; DOI:
10.1021/ic702241m
PDF
[C6F5Xe]+ and [C6F5XeNCCH3]+ Salts of the Weakly Coordinating Borate Anions, [BY4] (Y = CN, CF3, or C6F5)
Karsten Koppe, Hermann-J. Frohn, Hélène P. A. Mercier, and Gary J. Schrobilgen
pp 3205 - 3217; DOI:
10.1021/ic702259c
PDF
Formation, Reactivity, and Photorelease of Metal Bound Nitrosyl in [Ru(trpy)(L)(NO)]n+ (trpy = 2,2′:6′,2′′-Terpyridine, L = 2-Phenylimidazo[4,5-f]1,10-phenanthroline)
Somnath Maji, Biprajit Sarkar, Malay Patra, Atanu Kumar Das, Shaikh M. Mobin, Wolfgang Kaim, and Goutam Kumar Lahiri
pp 3218 - 3227; DOI:
10.1021/ic702160w
PDF
Na5[MB24O34(OH)12nH2O (M = Cr3+, Al3+): Unprecedented Spherelike Polyborate Clusters from Boric Acid Flux Synthesis
Tao Yang, Junliang Sun, Lars Eriksson, Guobao Li, Xiaodong Zou, Fuhui Liao, and Jianhua Lin
pp 3228 - 3233; DOI:
10.1021/ic702244w
PDF
Synthesis, Morphology, Structure, and Magnetic Characterization of Layered Cobalt Hydroxyisocyanates
Yi Du and Dermot O’Hare
pp 3234 - 3242; DOI:
10.1021/ic702260s
PDF
Synthesis, NMR and Vibrational Spectroscopic Characterization, and Computational Study of the cis-IO2F32− Anion
Johnathan P. Mack, Jerry A. Boatz, and Michael Gerken
pp 3243 - 3247; DOI:
10.1021/ic702258x
PDF
Structure of the Hydrated Platinum(II) Ion and the cis-Diammineplatinum(II) Complex in Acidic Aqueous Solution: An EXAFS Study
Farideh Jalilehvand and Luke J. Laffin
pp 3248 - 3254; DOI:
10.1021/ic7022538
PDF
Acyclic Bis(N2O2 chelate) Ligand for Trinuclear d-Block Homo- and Heterometal Complexes
Shigehisa Akine, Takanori Taniguchi, and Tatsuya Nabeshima
pp 3255 - 3264; DOI:
10.1021/ic702255s
PDF
Low-Valent Vanadium Complexes of a Pyrrolide-Based Ligand. Electronic Structure of a Dimeric V(I) Complex with a Short and Weak Metal−Metal Bond
Sougandi Ilango, Balamurugan Vidjayacoumar, Sandro Gambarotta, and Serge I. Gorelsky
pp 3265 - 3273; DOI:
10.1021/ic702280g
PDF
Assembly of the Highest Connectivity Wells-Dawson Polyoxometalate Coordination Polymer: the Use of Organic Ligand Flexibility
Ai-xiang Tian, Jun Ying, Jun Peng, Jing-quan Sha, Zhan-gang Han, Jian-fang Ma, Zhong-min Su, Ning-hai Hu, and Heng-qing Jia
pp 3274 - 3283; DOI:
10.1021/ic7023082
PDF
Multipoint Anchoring of the [2.2.2.2]Metacyclophane Motif to a Gold Surface via Self-Assembly: Coordination Chemistry of a Cyclic Tetraisocyanide Revisited
Masaharu Toriyama, Tiffany R. Maher, Thomas C. Holovics, Kumar Vanka, Victor W. Day, Cindy L. Berrie, Ward H. Thompson, and Mikhail V. Barybin
pp 3284 - 3291; DOI:
10.1021/ic702401b
PDF
Palladium Nanoparticles Stabilized by an Ionic Polymer and Ionic Liquid: A Versatile System for C−C Cross-Coupling Reactions
Xue Yang, Zhaofu Fei, Dongbin Zhao, Wee Han Ang, Yongdan Li, and Paul J. Dyson
pp 3292 - 3297; DOI:
10.1021/ic702305t
PDF
Fluorinated Diarylamido Complexes of Lithium, Zirconium, and Hafnium
Wei-Ying Lee and Lan-Chang Liang
pp 3298 - 3306; DOI:
10.1021/ic702293d
PDF
Luminescent Osmium(II) Complexes with Functionalized 2-Phenylpyridine Chelating Ligands: Preparation, Structural Analyses, and Photophysical Properties
Kwun-Chi Hwang, Jing-Lin Chen, Yun Chi, Chun-Wei Lin, Yi-Ming Cheng, Gene-Hsiang Lee, Pi-Tai Chou, Sue-Yi Lin, and Ching-Fong Shu
pp 3307 - 3317; DOI:
10.1021/ic7023132
PDF
Unusual Structural Types in Polynuclear Iron Chemistry from the Use of N,N,N′,N′-Tetrakis(2-hydroxyethyl)ethylenediamine (edteH4): Fe5, Fe6, and Fe12 Clusters
Rashmi Bagai, Matthew R. Daniels, Khalil A. Abboud, and George Christou
pp 3318 - 3327; DOI:
10.1021/ic7024022
PDF
Rare-Earth Metal Complexes Supported by 1,ω-Dithiaalkanediyl-Bridged Bis(phenolato) Ligands: Synthesis, Structure, and Heteroselective Ring-Opening Polymerization of rac-Lactide
Haiyan Ma, Thomas P. Spaniol, and Jun Okuda
pp 3328 - 3339; DOI:
10.1021/ic702312b
PDF
Luminescent Cyclometalated RhIII, IrIII, and (DIP)2RuII Complexes with Carboxylated Bipyridyl Ligands: Synthesis, X-ray Molecular Structure, and Photophysical Properties
Jenny B. Waern, Christophe Desmarets, Lise-Marie Chamoreau, Hani Amouri, Andrea Barbieri, Cristiana Sabatini, Barbara Ventura, and Francesco Barigelletti
pp 3340 - 3348; DOI:
10.1021/ic702327z
PDF
Control of Structures and Sorption Properties of Ionic Crystals of A2[Cr3O(OOCC2H5)6(H2O)3]2[α-SiW12O40] (A = Na, K, Rb, NH4, Cs, TMA)
Aldes Lesbani, Ryosuke Kawamoto, Sayaka Uchida, and Noritaka Mizuno
pp 3349 - 3357; DOI:
10.1021/ic702333w
PDF
X-ray Crystal Structures, Electron Paramagnetic Resonance, and Magnetic Studies on Strongly Antiferromagnetically Coupled Mixed μ-Hydroxide-μ-N1,N2-Triazole-Bridged One Dimensional Linear Chain Copper(II) Complexes
Krzysztof Drabent, Zbigniew Ciunik, and Andrzej Ozarowski
pp 3358 - 3365; DOI:
10.1021/ic7023428
PDF
A New Class of Binuclear and Trinuclear Iron−Sulfur Clusters Derived from Bis[bis(trimethylsilyl)amido]iron(II)
Ruslan Pryadun and R. H. Holm
pp 3366 - 3370; DOI:
10.1021/ic7023742
PDF
Water Substitution on Iron Centers: from 0D to 1D Sandwich Type Polyoxotungstates
Anne Dolbecq, Jean-Daniel Compain, Pierre Mialane, Jérôme Marrot, Eric Rivière, and Francis Sécheresse
pp 3371 - 3378; DOI:
10.1021/ic7024186
PDF
Quantum Chemical Study of Trivalent Group 12 Fluorides
Sebastian Riedel, Martin Kaupp, and Pekka Pyykkö
pp 3379 - 3383; DOI:
10.1021/ic702384y
PDF
Arylthiolate Coordination and Reactivity at Pseudotetrahedral Nickel(II) Centers: Modulation by Noncovalent Interactions
Swarup Chattopadhyay, Tapash Deb, Huaibo Ma, Jeffrey L. Petersen, Victor G. Young Jr., and Michael P. Jensen
pp 3384 - 3392; DOI:
10.1021/ic702417w
PDF
Selectivity of Thiolate Ligand and Preference of Substrate in Model Reactions of Dissimilatory Nitrate Reductase
Amit Majumdar, Kuntal Pal, and Sabyasachi Sarkar
pp 3393 - 3401; DOI:
10.1021/ic7024268
PDF
New Approach to the Synthesis of an Organopolymolybdate Polymer in Aqueous Media by Linkage of Multicarboxylic Ligands
Guang-Gang Gao, Lin Xu, Xiao-Shu Qu, Hong Liu, and Yan-Yan Yang
pp 3402 - 3407; DOI:
10.1021/ic7025126
PDF
Synthesis and Photophysical Properties of Ruthenium-Based Dendrimers and Their Use in Dye Sensitized Solar Cells
Ali H. Younes and Tarek H. Ghaddar
pp 3408 - 3414; DOI:
10.1021/ic702432u
PDF
Preparations and Photophysical Properties of Fused and Nonfused Thienyl Bridged MM (M = Mo or W) Quadruply Bonded Complexes
Malcolm H. Chisholm, Pi-Tai Chou, Yi-Hsuan Chou, Yagnaseni Ghosh, Terry L. Gustafson, and Mei-Lin Ho
pp 3415 - 3425; DOI:
10.1021/ic800090n
PDF
VFe3S4 Single and Double Cubane Clusters: Synthesis, Structures, and Dependence of Redox Potentials and Electron Distribution on Ligation and Heterometal
Thomas A. Scott and R. H. Holm
pp 3426 - 3432; DOI:
10.1021/ic702372f
PDF
Synthesis and Selectivity in the Formation of Cyclophosphazene-Derived 1,3-Cyclohexadienes from Reactions of RCpCo(COD) [R = MeOC(O)] with Alkynes and Alkenes
Muthiah Senthil Kumar, Ram Prakash Gupta, and Anil J. Elias
pp 3433 - 3441; DOI:
10.1021/ic7024507
PDF
Blue or Green Glowing Crystals of the Cation [Au{C(NHMe)2}2]+. Structural Effects of Anions, Hydrogen Bonding, and Solvate Molecules on the Luminescence of a Two-Coordinate Gold(I) Carbene Complex
Daniel Rios, David M. Pham, James C. Fettinger, Marilyn M. Olmstead, and Alan L. Balch
pp 3442 - 3451; DOI:
10.1021/ic702481v
PDF
Coordination Chemistry of a π-Extended, Rigid and Redox-Active Tetrathiafulvalene-Fused Schiff-Base Ligand
Jin-Cai Wu, Shi-Xia Liu, Tony D. Keene, Antonia Neels, Valeriu Mereacre, Annie K. Powell, and Silvio Decurtins
pp 3452 - 3459; DOI:
10.1021/ic800138x
PDF
Facile Synthesis and Relaxation Properties of Novel Bispolyazamacrocyclic Gd3+ Complexes: An Attempt towards Calcium-Sensitive MRI Contrast Agents
Anurag Mishra, Petra Fousková, Goran Angelovski, Edina Balogh, Anil K. Mishra, Nikos K. Logothetis, and Éva Tóth
pp 3460 - 3460; DOI:
10.1021/ic800450v
PDF

Issue 9


Interpenetrating Networks of Three-Dimensional Penrose Tiles in CaAu3Ga, the Structurally Simplest Cubic Approximant of an Icosahedral Quasicrystal
Qisheng Lin and John D. Corbett
pp 3462 - 3464; DOI:
10.1021/ic800087q
PDF
Self-Assembly of an Azido-Bridged [NiII6] Cluster Featuring Four Fused Defective Cubanes
Debashree Mandal, Valerio Bertolasi, Jordi Ribas-Ariño, Guillem Aromí, and Debashis Ray
pp 3465 - 3467; DOI:
10.1021/ic800188j
PDF
Synthesis and Characterization of Linear and Square-Planar Nickel Complexes with Primary Amido Ligands
Jianfeng Li, Haibin Song, Chunming Cui, and Jin-Pei Cheng
pp 3468 - 3470; DOI:
10.1021/ic800288x
PDF
Novel Thermochromism Relating to Supramolecular Cuprophilic Interaction: Design, Synthesis, and Luminescence of Copper(I) Pyrazolate Trimer and Polymer
Jing-Xiang Zhang, Jun He, Ye-Gao Yin, Mei-Hong Hu, Dan Li, and Xiao-Chun Huang
pp 3471 - 3473; DOI:
10.1021/ic702189f
PDF
Three-Fold Intramolecular Ring-Closing Metatheses Involving Square-Planar Platinum Complexes with cis-Phosphorus Donor Ligands: Syntheses, Structures, and Properties of Parachute-like Complexes
Katrin Skopek, Michał Barbasiewicz, Frank Hampel, and John A. Gladysz
pp 3474 - 3476; DOI:
10.1021/ic702391m
PDF
Spectral Evidence and DFT Calculations on the Formation of Bis(2,2′-bipyridine)platinum(II)−N-Base Adducts
Yuji Kawanishi, Takashi Funaki, Tetsuo Yatabe, Yasuzo Suzuki, Seiko Miyamoto, Yukihiro Shimoi, and Shuji Abe
pp 3477 - 3479; DOI:
10.1021/ic702449k
PDF
Selenolate Complexes of CYP101 and the Heme-Bound hHO-1/H25A Proximal Cavity Mutant
Yongying Jiang and Paul R. Ortiz de Montellano
pp 3480 - 3482; DOI:
10.1021/ic800148a
PDF
Determination by High-Frequency and -Field EPR of Zero-Field Splitting in Iron(IV) Oxo Complexes: Implications for Intermediates in Nonheme Iron Enzymes
J. Krzystek, Jason England, Kallol Ray, Andrew Ozarowski, Dmitry Smirnov, Lawrence Que Jr., and Joshua Telser
pp 3483 - 3485; DOI:
10.1021/ic800411c
PDF
Assessment of the Anisotropy in the Molecule Mn19 with a High-Spin Ground State S = 83/2 by 35 GHz Electron Paramagnetic Resonance
Oliver Waldmann, Ayuk M. Ako, Hans U. Güdel, and Annie K. Powell
pp 3486 - 3488; DOI:
10.1021/ic800213w
PDF
Solvothermal Synthesis and Characterization of Two High-Nuclearity Mixed-Valent Manganese Phosphonate Clusters
Sanjit Konar and Abraham Clearfield
pp 3489 - 3491; DOI:
10.1021/ic8001493
PDF
Mixed-Valent Dodecanuclear Vanadium Cluster Encapsulating Chloride Anions and Its Reaction To Form a “Bowl”-Shaped Cluster
Sanjit Konar and Abraham Clearfield
pp 3492 - 3494; DOI:
10.1021/ic800013f
PDF
Three-Dimensional Homochiral Transition-Metal Camphorate Architectures Directed by a Flexible Auxiliary Ligand
Jian Zhang, Emily Chew, Shumei Chen, Jimmy T. H. Pham, and Xianhui Bu
pp 3495 - 3497; DOI:
10.1021/ic800195u
PDF
Structural Versatility of 5-Methyltetrazolato Complexes of (η5-Pentamethylcyclopentadienyl)iridium(III) Incorporating 2,2′-Bipyridine, N,N-Dimethyldithiocarbamate, or 2-Pyridinethiolate Ligands
Mai Kotera, Yusuke Sekioka, and Takayoshi Suzuki
pp 3498 - 3508; DOI:
10.1021/ic701631k
PDF
Binding of Catechols to Mononuclear Titanium(IV) and to 1- and 5-nm TiO2 Nanoparticles
Carol Creutz and Mei H. Chou
pp 3509 - 3514; DOI:
10.1021/ic701687k
PDF
Solution Dynamics and Gas-Phase Chemistry of Pd2@Sn184−
F. Sanem Kocak, Peter Zavalij, Yiu-Fai Lam, and Bryan W. Eichhorn
pp 3515 - 3520; DOI:
10.1021/ic701699d
PDF
Spin-Frustrated Trinuclear Cu(II) Clusters with Mixing of 2(S = 1/2) and S = 3/2 States by Antisymmetric Exchange. 1. Dzialoshinsky−Moriya Exchange Contribution to Zero-Field Splitting of the S = 3/2 State
Moisey I. Belinsky
pp 3521 - 3531; DOI:
10.1021/ic701796q
PDF
Spin-Frustrated Trinuclear Cu(II) Clusters with Mixing of 2(S = 1/2) and S = 3/2 States by Antisymmetric Exchange. 2. Orbital Origin of In-Plane Dzialoshinsky–Moriya Exchange Parameters
Moisey I. Belinsky
pp 3532 - 3539; DOI:
10.1021/ic701797m
PDF
Steric Influence on the Excited-State Lifetimes of Ruthenium Complexes with Bipyridyl−Alkanylene−Pyridyl Ligands
Maria Abrahamsson, Maria J. Lundqvist, Henriette Wolpher, Olof Johansson, Lars Eriksson, Jonas Bergquist, Torben Rasmussen, Hans-Christian Becker, Leif Hammarström, Per-Ola Norrby, Björn Åkermark, and Petter Persson
pp 3540 - 3548; DOI:
10.1021/ic7019457
PDF
New Fluorogenic Dansyl-Containing Calix[4]arene in the Partial Cone Conformation for Highly Sensitive and Selective Recognition of Lead(II)
Nicole M. Buie, Vladimir S. Talanov, Raymond J. Butcher, and Galina G. Talanova
pp 3549 - 3558; DOI:
10.1021/ic7018346
PDF
Luminescence and Mesogenic Properties in Crown-Ether-Isocyanide or Carbene Gold(I) Complexes: Luminescence in Solution, in the Solid, in the Mesophase, and in the Isotropic Liquid State
Javier Arias, Manuel Bardají, and Pablo Espinet
pp 3559 - 3567; DOI:
10.1021/ic701831v
PDF
1,2,4,5-Benzenetetracarboxylate- and 2,2′-Bipyrimidine-Containing Cobalt(II) Coordination Polymers: Preparation, Crystal Structure, and Magnetic Properties
Oscar Fabelo, Jorge Pasán, Francesc Lloret, Miguel Julve, and Catalina Ruiz-Pérez
pp 3568 - 3576; DOI:
10.1021/ic702187k
PDF
Preparation and Electrochemical and Optical Properties of Unsymmetrically Substituted Phthalocyanines with One or Two Trithiole Rings and Related Symmetric Derivatives
Takeshi Kimura, Nagisa Kanota, Kenji Matsui, Ichiro Tanaka, Takaaki Tsuboi, Yutaka Takaguchi, Akinori Yomogita, Takatsugu Wakahara, Shunsuke Kuwahara, Fumi Nagatsugi, and Takeshi Akasaka
pp 3577 - 3583; DOI:
10.1021/ic701841j
PDF
Modeling the Resting State of Oxalate Oxidase and Oxalate Decarboxylase Enzymes
Marciela Scarpellini, Jessica Gätjens, Ola J. Martin, Jeff W. Kampf, Suzanne E. Sherman, and Vincent L. Pecoraro
pp 3584 - 3593; DOI:
10.1021/ic701953g
PDF
Cation Substitution Effects in the System Sr2−xBaxBi3 (0 ≤ x ≤ 1.3): Structural Distortions Induced by Chemical Pressure
Sung-Jin Kim, Simeon Ponou, and Thomas F. Fässler
pp 3594 - 3602; DOI:
10.1021/ic7019439
PDF
Synthesis, Structure, and Optical Properties of the Quaternary Seleno-gallates NaLnGa4Se8 (Ln = La, Ce, Nd) and Their Comparison with the Isostructural Thio-gallates
Amitava Choudhury and Peter K. Dorhout
pp 3603 - 3609; DOI:
10.1021/ic701986j
PDF
Similar K@Au10Sn10 Polyhedra in the Markedly Different Structures of KAu4Sn6 and KAu3Sn3. Syntheses and Characterization
Bin Li and John D. Corbett
pp 3610 - 3616; DOI:
10.1021/ic701997x
PDF
Liquid Azide Salts
Stefan Schneider, Tommy Hawkins, Michael Rosander, Jeffrey Mills, Adam Brand, Leslie Hudgens, Greg Warmoth, and Ashwani Vij
pp 3617 - 3624; DOI:
10.1021/ic702068r
PDF
Complexation of Molybdenum(V) with Glycolic Acid: An Unusual Orientation of Glycolato Ligand in {Mo2O4}2+ Complexes
Barbara Modec, Darko Dolenc, and Marta Kasunič
pp 3625 - 3633; DOI:
10.1021/ic7020726
PDF
First-Principles Investigation of the Schrock Mechanism of Dinitrogen Reduction Employing the Full HIPTN3N Ligand
Stephan Schenk, Boris Le Guennic, Barbara Kirchner, and Markus Reiher
pp 3634 - 3650; DOI:
10.1021/ic702083p
PDF
Luminescent One- And Two-Dimensional Extended Structures and a Loosely Associated Dimer Based on Platinum(II)–Thallium(I) Backbones
Juan Forniés, Ana García, Elena Lalinde, and M. Teresa Moreno
pp 3651 - 3660; DOI:
10.1021/ic702180c
PDF
Synthesis and Molecular and Electronic Structures of a Series of Mo3CoSe4 Cluster Complexes with Three Different Metal Electron Populations
Antonio Alberola, Rosa Llusar, Cristian Vicent, Juan Andrés, Victor Polo, and Carlos J. Gómez-García
pp 3661 - 3668; DOI:
10.1021/ic7022083
PDF
(TAML)FeIV=O Complex in Aqueous Solution: Synthesis and Spectroscopic and Computational Characterization
Arani Chanda, Xiaopeng Shan, Mrinmoy Chakrabarti, W. Chadwick Ellis, Delia L. Popescu, Filipe Tiago de Oliveira, Dong Wang, Lawrence Que Jr., Terrence J. Collins, Eckard Münck, and Emile L. Bominaar
pp 3669 - 3678; DOI:
10.1021/ic7022902
PDF
The Classic Wells−Dawson Polyoxometalate, K6[α-P2W18O62]·14H2O. Answering an 88 Year-Old Question: What Is Its Preferred, Optimum Synthesis?
Christopher R. Graham and Richard G. Finke
pp 3679 - 3686; DOI:
10.1021/ic702295y
PDF
Electrochemical Behavior of Copper Complexes with Substituted Polypyridinic Ligands: An Experimental and Theoretical Study
Walter Cañon-Mancisidor, Evgenia Spodine, Diego Venegas-Yazigi, Darío Rojas, Jorge Manzur, and Santiago Alvarez
pp 3687 - 3692; DOI:
10.1021/ic702104u
PDF
Preparation and Comprehensive Characterization of [Hg6(Alanine)4(NO3)4]·H2O
Cheryl D. L. Saunders, Neil Burford, Ulrike Werner-Zwanziger, and Robert McDonald
pp 3693 - 3699; DOI:
10.1021/ic702321d
PDF
Structural and Luminescent Properties of Micro- and Nanosized Particles of Lanthanide Terephthalate Coordination Polymers
Carole Daiguebonne, Nicolas Kerbellec, Olivier Guillou, Jean-Claude Bünzli, Frederic Gumy, Laure Catala, Talal Mallah, Nathalie Audebrand, Yves Gérault, Kevin Bernot, and Guillaume Calvez
pp 3700 - 3708; DOI:
10.1021/ic702325m
PDF
Reporting a New Class of Divanadium(V) Compounds Connected by an Unsupported Hydroxo Bridge
Pabitra Baran Chatterjee, Debdas Mandal, Anandalok Audhya, Ki-Young Choi, Akira Endo, and Muktimoy Chaudhury
pp 3709 - 3718; DOI:
10.1021/ic702286h
PDF
Structure, Cytotoxicity, and DNA-Cleavage Properties of the Complex [CuII(pbt)Br2]
Palanisamy Uma Maheswari, Martijn van der Ster, Simon Smulders, Sharief Barends, Gilles P. van Wezel, Chiara Massera, Sudeshna Roy, Hans den Dulk, Patrick Gamez, and Jan Reedijk
pp 3719 - 3727; DOI:
10.1021/ic702306f
PDF
YF[MoO4] and YCl[MoO4]: Two Halide Derivatives of Yttrium ortho-Oxomolybdate: Syntheses, Structures, and Luminescence Properties
Thomas Schleid, Sabine Strobel, Peter K. Dorhout, Peter Nockemann, Koen Binnemans, and Ingo Hartenbach
pp 3728 - 3735; DOI:
10.1021/ic702350p
PDF
Cyanide-Bridged Os(II)/Ln(III) Coordination Networks Containing [Os(phen)(CN)4]2– as an Energy Donor: Structural and Photophysical Properties
Svetlana G. Baca, Simon J. A. Pope, Harry Adams, and Michael D. Ward
pp 3736 - 3747; DOI:
10.1021/ic702353c
PDF
Tuning the Coordination Sphere around Highly Luminescent Lanthanide Complexes
Loïc Charbonnière, Samir Mameri, Pascal Kadjane, Carlos Platas-Iglesias, and Raymond Ziessel
pp 3748 - 3762; DOI:
10.1021/ic702472n
PDF
Trithio-Chloro Molybdate [MoClS3]: A Versatile Precursor for Molybdenum Trisulfido Complexes
Jun-ichi Ito, Yasuhiro Ohki, Masatoshi Iwata, and Kazuyuki Tatsumi
pp 3763 - 3771; DOI:
10.1021/ic702397j
PDF
New Extended Magnetic Systems Based on Oxalate and Iron(III) Ions
Donatella Armentano, Teresa F. Mastropietro, Giovanni De Munno, Patrizia Rossi, Francesc Lloret, and Miguel Julve
pp 3772 - 3786; DOI:
10.1021/ic702403h
PDF
Copper Dioxygen Adducts: Formation of Bis(μ-oxo)dicopper(III) versus (μ-1,2)Peroxodicopper(II) Complexes with Small Changes in One Pyridyl-Ligand Substituent
Debabrata Maiti, Julia S. Woertink, Amy A. Narducci Sarjeant, Edward I. Solomon, and Kenneth D. Karlin
pp 3787 - 3800; DOI:
10.1021/ic702437c
PDF
In Situ Formation of Heterobimetallic Salen Complexes Containing Titanium and/or Vanadium Ions
Yuri N. Belokon′, William Clegg, Ross W. Harrington, Michael North, and Carl Young
pp 3801 - 3814; DOI:
10.1021/ic702451a
PDF
Fluxional Behavior of Platinum(0) Complexes: Intra vs Intermolecular Reaction Pathways
Olena V. Zenkina, Leonid Konstantinovski, Dalia Freeman, Linda J. W. Shimon, and Milko E. van der Boom
pp 3815 - 3822; DOI:
10.1021/ic702433s
PDF
In Search of the [PhB(μ-NtBu)2]2As Radical: Experimental and Computational Investigations of the Redox Chemistry of Group 15 Bis-boraamidinates
Jari Konu, Heikki M. Tuononen, Tristram Chivers, Andrea M. Corrente, René T. Boeré, and Tracey L. Roemmele
pp 3823 - 3831; DOI:
10.1021/ic702435e
PDF
A pH-Metric, UV, NMR, and X-ray Crystallographic Study on Arsenous Acid Reacting with Dithioerythritol
András Kolozsi, Andrea Lakatos, Gábor Galbács, Anders Østergaard Madsen, Erik Larsen, and Béla Gyurcsik
pp 3832 - 3840; DOI:
10.1021/ic7024439
PDF
Relative Axial Ligand Orientation in Bis(imidazole)iron(II) Porphyrinates: Are “Picket Fence” Derivatives Different?
Jianfeng Li, Smitha M. Nair, Bruce C. Noll, Charles E. Schulz, and W. Robert Scheidt
pp 3841 - 3850; DOI:
10.1021/ic702498c
PDF
Synthesis, Potentiometric, Kinetic, and NMR Studies of 1,4,7,10-Tetraazacyclododecane-1,7-bis(acetic acid)-4,10-bis(methylenephosphonic acid) (DO2A2P) and its Complexes with Ca(II), Cu(II), Zn(II) and Lanthanide(III) Ions
Ferenc K. Kálmán, Zsolt Baranyai, Imre Tóth, István Bányai, Róbert Király, Ernö Brücher, Silvio Aime, Xiankai Sun, A. Dean Sherry, and Zoltán Kovács
pp 3851 - 3862; DOI:
10.1021/ic7024704
PDF
Homoleptic 2-Mercapto Benzothiazolate Uranium and Lanthanide Complexes
Mathieu Roger, Thérèse Arliguie, Pierre Thuéry, and Michel Ephritikhine
pp 3863 - 3868; DOI:
10.1021/ic702474q
PDF
Homoleptic Mononuclear and Binuclear Osmium Carbonyls Os(CO)n(n = 3−5) and Os2(CO)n (n = 8, 9): Comparison with the Iron Analogues
Bing Xu, Qian-Shu Li, Yaoming Xie, R. Bruce King, and Henry F. Schaefer III
pp 3869 - 3878; DOI:
10.1021/ic800019n
PDF
Convenient Synthesis of Aluminum and Gallium Phosphonate Cages
Christian R. Samanamu, Marilyn M. Olmstead, Jean-Luc Montchamp, and Anne F. Richards
pp 3879 - 3887; DOI:
10.1021/ic800023d
PDF
The Effect of One Valence Electron: Contrasting (PNP)Ni(CO) with (PNP)Ni(NO) to Understand the Half-Bent NiNO Unit
Benjamin C. Fullmer, Maren Pink, Hongjun Fan, Xiaofan Yang, Mu-Hyun Baik, and Kenneth G. Caulton
pp 3888 - 3892; DOI:
10.1021/ic702503m
PDF
Insights into DNA Binding of Ruthenium Arene Complexes: Role of Hydrogen Bonding and π Stacking
Konstantinos Gkionis, James A. Platts, and J. Grant Hill
pp 3893 - 3902; DOI:
10.1021/ic702459h
PDF
Tetra-2,3-pyrazinoporphyrazines with Externally Appended Pyridine Rings. 5. Synthesis, Physicochemical and Theoretical Studies of a Novel Pentanuclear Palladium(II) Complex and Related Mononuclear Species
Maria Pia Donzello, Elisa Viola, Xiaohui Cai, Luisa Mannina, Corrado Rizzoli, Giampaolo Ricciardi, Claudio Ercolani, Karl M. Kadish, and Angela Rosa
pp 3903 - 3919; DOI:
10.1021/ic702430j
PDF
Synthesis and Ion-Binding Studies of a Platinum(II) Terpyridine Complex with Crown Ether Pendant. X-ray Crystal Structure of [Pt(trpy)(S-benzo-15-crown-5)]PF6
Vivian Wing-Wah Yam, Rowena Pui-Ling Tang, Keith Man-Chung Wong, Chi-Chiu Ko, and Kung-Kai Cheung
pp 3920 - 3920; DOI:
10.1021/ic8002965
PDF
Importance of Platinum(II)-Assisted Platinum(IV) Substitution for the Oxidation of Guanosine Derivatives by Platinum(IV) Complexes
Sunhee Choi, Livia Vastag, Yuri C. Larrabee, Michelle L. Personick, Kurt B. Schaberg, Benjamin J. Fowler, Roger K. Sandwick, and Gulnar Rawji
pp 3920 - 3920; DOI:
10.1021/ic8005713
PDF

Issue 10


New Framework Iodoargentates: M(en)3Ag2I4 (M = Zn, Ni) with Tridymite Topology
Yan-Si Jiang, Hua-Gang Yao, Shou-Hua Ji, Min Ji, and Yong-Lin An
pp 3922 - 3924; DOI:
10.1021/ic7025158
PDF
Kinetics and Mechanism of Nucleophilic Addition to Nitric Oxide: Secondary Amine Diazeniumdiolation
D. Scott Bohle and Kamilah N. Smith
pp 3925 - 3927; DOI:
10.1021/ic800027m
PDF
Spectroscopic Evidence for the Formation of Goldfingers
Matthew A. Franzman and Amy M. Barrios
pp 3928 - 3930; DOI:
10.1021/ic800157t
PDF
New Synthetic Routes to a Disulfidodinickel(II) Complex: Characterization and Reactivity of a Ni2(µ-η22-S2) Core
Jaeheung Cho, Katherine M. Van Heuvelen, Glenn P. A. Yap, Thomas C. Brunold, and Charles G. Riordan
pp 3931 - 3933; DOI:
10.1021/ic800321x
PDF
Lithium−Palladium Complex Supported by Phosphonatophosphine and Chloride Ligands
Adel Hamada and Pierre Braunstein
pp 3934 - 3936; DOI:
10.1021/ic800355m
PDF
Heterobismetal Complexes of [26]Hexaphyrin(1.1.1.1.1.1)
Shigeki Mori and Atsuhiro Osuka
pp 3937 - 3939; DOI:
10.1021/ic8004147
PDF
Organotitanoxanes with Unique Structure among Transition-Element Organometallic Oxide Derivatives
Olga Buitrago, Marta E. G. Mosquera, Gerardo Jiménez, and Tomás Cuenca
pp 3940 - 3942; DOI:
10.1021/ic8003646
PDF
Toluene-Sandwiched Trinuclear Copper(I) and Silver(I) Triazolates and Phosphine Adducts of Dinuclear Copper(I) and Silver(I) Triazolates
H. V. Rasika Dias, Shreeyukta Singh, and Charles F. Campana
pp 3943 - 3945; DOI:
10.1021/ic800396t
PDF
Rosamine-Based Fluorescent Chemosensor for Selective Detection of Silver(I) in an Aqueous Solution
Shohei Iyoshi, Masayasu Taki, and Yukio Yamamoto
pp 3946 - 3948; DOI:
10.1021/ic800442y
PDF
Cyclic (Amino)[bis(ylide)]carbene as an Anionic Bidentate Ligand for Transition-Metal Complexes
Matthew Asay, Bruno Donnadieu, Antoine Baceiredo, Michele Soleilhavoup, and Guy Bertrand
pp 3949 - 3951; DOI:
10.1021/ic800459p
PDF
Efficient Sensitization of Lanthanide Luminescence by Tetrazole-Based Polydentate Ligands
Marion Giraud, Eugen S. Andreiadis, Alexander S. Fisyuk, Renaud Demadrille, Jacques Pécaut, Daniel Imbert, and Marinella Mazzanti
pp 3952 - 3954; DOI:
10.1021/ic8005663
PDF
3D Metal−Organic Frameworks Based on Elongated Tetracarboxylate Building Blocks for Hydrogen Storage
Liqing Ma, Jeong Yong Lee, Jing Li, and Wenbin Lin
pp 3955 - 3957; DOI:
10.1021/ic8003855
PDF
Mechanism of Hydride Donor Generation Using a Ru(II) Complex Containing an NAD+ Model Ligand: Pulse and Steady-State Radiolysis Studies
Dmitry E. Polyansky, Diane Cabelli, James T. Muckerman, Takashi Fukushima, Koji Tanaka, and Etsuko Fujita
pp 3958 - 3968; DOI:
10.1021/ic702139n
PDF
Characterization of the Fe Site in Iron−Sulfur Cluster-Free Hydrogenase (Hmd) and of a Model Compound via Nuclear Resonance Vibrational Spectroscopy (NRVS)
Yisong Guo, Hongxin Wang, Yuming Xiao, Sonja Vogt, Rudolf K. Thauer, Seigo Shima, Phillip I. Volkers, Thomas B. Rauchfuss, Vladimir Pelmenschikov, David A. Case, Ercan E. Alp, Wolfgang Sturhahn, Yoshitaka Yoda, and Stephen P. Cramer
pp 3969 - 3977; DOI:
10.1021/ic701251j
PDF
Spectroscopic and Computational Investigation of Second-Sphere Contributions to Redox Tuning in Escherichia coli Iron Superoxide Dismutase
Laurie E. Grove, Juan Xie, Emine Yikilmaz, Anne-Frances Miller, and Thomas C. Brunold
pp 3978 - 3992; DOI:
10.1021/ic702412y
PDF
Spectroscopic and Computational Insights into Second-Sphere Amino-Acid Tuning of Substrate Analogue/Active-Site Interactions in Iron(III) Superoxide Dismutase
Laurie E. Grove, Juan Xie, Emine Yikilmaz, Anush Karapetyan, Anne-Frances Miller, and Thomas C. Brunold
pp 3993 - 4004; DOI:
10.1021/ic702414m
PDF
A Density Functional Theory Calculation of the Electronic Properties of Several High-Spin and Low-Spin Iron(II) Pyrazolylborate Complexes
Françoise Remacle, Fernande Grandjean, and Gary J. Long
pp 4005 - 4014; DOI:
10.1021/ic701367b
PDF
P123-Assisted Hydrothermal Synthesis and Characterization of Rectangular Parallelepiped and Hexagonal Prism Single-Crystalline MgO with Three-Dimensional Wormholelike Mesopores
Guozhi Wang, Lei Zhang, Hongxing Dai, Jiguang Deng, Caixin Liu, Hong He, and Chak Tong Au
pp 4015 - 4022; DOI:
10.1021/ic7015462
PDF
Binuclear Copper(II) Complexes with N4O3 Coordinating Heptadentate Ligand: Synthesis, Structure, Magnetic Properties, Density-Functional Theory Study, and Catecholase Activity
Atanu Banerjee, Sumana Sarkar, Deepak Chopra, Enrique Colacio, and Kajal Krishna Rajak
pp 4023 - 4031; DOI:
10.1021/ic7015935
PDF
Interaction of Molecular Hydrogen with Open Transition Metal Centers for Enhanced Binding in Metal-Organic Frameworks: A Computational Study
Rohini C. Lochan, Rustam Z. Khaliullin, and Martin Head-Gordon
pp 4032 - 4044; DOI:
10.1021/ic701625g
PDF
Ethene Insertion into Vanadium Hydride Intermediates Formed via Vanadium Atom Reaction with Water or Ethene: A Matrix Isolation Infrared Spectroscopic Study
Matthew G. K. Thompson and J. Mark Parnis
pp 4045 - 4053; DOI:
10.1021/ic701653v
PDF
Self-Assembly of Luminescent Sn(IV)/Cu/S Clusters Using Metal Thiolates as Metalloligands
Long-Sheng Wang, Tian-Lu Sheng, Xin Wang, Dong-Bo Chen, Sheng-Min Hu, Rui-Biao Fu, Sheng-Chang Xiang, and Xin-Tao Wu
pp 4054 - 4059; DOI:
10.1021/ic701741m
PDF
Ligand Structure, Conformational Dynamics, and Excited-State Electron Delocalization for Control of Photoinduced Electron Transfer Rates in Synthetic Donor-Bridge-Acceptor Systems
Heather A. Meylemans, Chi-Fong Lei, and Niels H. Damrauer
pp 4060 - 4076; DOI:
10.1021/ic701776k
PDF
A Two-Dimensional Iron(II) Carboxylate Linear Chain Polymer that Exhibits a Metamagnetic Spin-Canted Antiferromagnetic to Single-Chain Magnetic Transition
Yan-Zhen Zheng, Wei Xue, Ming-Liang Tong, Xiao-Ming Chen, Fernande Grandjean, and Gary J. Long
pp 4077 - 4087; DOI:
10.1021/ic701879y
PDF
Growth Mechanism and Optical Properties of Aligned Hexagonal ZnO Nanoprisms Synthesized by Noncatalytic Thermal Evaporation
Ahmad Umar, B. Karunagaran, S. H. Kim, E.-K. Suh, and Y. B. Hahn
pp 4088 - 4094; DOI:
10.1021/ic701929p
PDF
New Fe4, Fe6, and Fe8 Clusters of Iron(III) from the Use of 2-Pyridyl Alcohols: Structural, Magnetic, and Computational Characterization
Taketo Taguchi, Theocharis C. Stamatatos, Khalil A. Abboud, Candace M. Jones, Katye M. Poole, Ted A. O’Brien, and George Christou
pp 4095 - 4108; DOI:
10.1021/ic701756p
PDF
A Versatile Series of Nickel(II) Complexes Derived from Tetradentate Imine/Pyridyl Ligands and Various Pseudohalides: Azide and Cyanate Compared
Mohammad Habib, Tapan K. Karmakar, Guillem Aromí, Jordi Ribas-Ariño, Hoong-Kun Fun, Suchada Chantrapromma, and Swapan K. Chandra
pp 4109 - 4117; DOI:
10.1021/ic701754u
PDF
Cyclam κ4 to κ3 Ligand Denticity Change Upon Mono-N-Substitution with a Carboxypropyl Pendant Arm in a Ruthenium Nitrosyl Complex
Fábio G. Doro, Eduardo E. Castellano, Luiz A. B. Moraes, Marcos N. Eberlin, and Elia Tfouni
pp 4118 - 4125; DOI:
10.1021/ic702078p
PDF
Solution [Cu(amm)]2+ is a Strongly Solvated Square Pyramid: A Full Account of the Copper K-edge XAS Spectrum Within Single-Electron Theory
Patrick Frank, Maurizio Benfatto, Britt Hedman, and Keith O. Hodgson
pp 4126 - 4139; DOI:
10.1021/ic7021243
PDF
Intrinsic Carrier Doping in Antiferromagnetically Interacted Supramolecular Copper Complexes with (Pyrazino)tetrathiafulvalene (Pyra-TTF) as the Ligand, [CuIICl2(pyra-TTF)] and (Pyra-TTF)2[CuI3Cl4(pyra-TTF)]
Shun Ichikawa, Shinya Kimura, Kazuyuki Takahashi, Hatsumi Mori, Gosuke Yoshida, Yuichi Manabe, Masaki Matsuda, Hiroyuki Tajima, and Jun-ichi Yamaura
pp 4140 - 4145; DOI:
10.1021/ic7019632
PDF
ZnO Twin-Cones: Synthesis, Photoluminescence, and Catalytic Decomposition of Ammonium Perchlorate
Xuefei Sun, Xiaoqing Qiu, Liping Li, and Guangshe Li
pp 4146 - 4152; DOI:
10.1021/ic702348c
PDF
From Large 12-Membered Macrometallacycles to Ionic (NHC)2M+Cl Type Complexes of Gold and Silver by Modulation of the N-Substituent of Amido-Functionalized N-Heterocyclic Carbene (NHC) Ligands
Manoja K. Samantaray, Keliang Pang, Mobin M. Shaikh, and Prasenjit Ghosh
pp 4153 - 4165; DOI:
10.1021/ic702186g
PDF
Copper-Complex-Linked Polytungsto-Bismuthate (-Antimonite) Chain Containing Sandwich Cu(II) Ions Partially Modified with Imidazole Ligand
Hong Liu, Chao Qin, Yong-Ge Wei, Lin Xu, Guang-Gang Gao, Feng-Yan Li, and Xiao-Shu Qu
pp 4166 - 4172; DOI:
10.1021/ic7022264
PDF
F5SN(H)Xe+; a Rare Example of Xenon Bonded to sp3-Hybridized Nitrogen; Synthesis and Structural Characterization of [F5SN(H)Xe][AsF6]
Gregory L. Smith, Hélène P. A. Mercier, and Gary J. Schrobilgen
pp 4173 - 4184; DOI:
10.1021/ic702039f
PDF
Magnetic Circular Dichroism of Phthalocyanine (M = Mg, Zn) and Tetraazaporphyrin (M = Mg, Zn, Ni) Metal Complexes. A Computational Study Based on Time-Dependent Density Functional Theory
G. A. Peralta, Michael Seth, Hristina Zhekova, and Tom Ziegler
pp 4185 - 4198; DOI:
10.1021/ic7022117
PDF
New Attempt at Directly Generating Superbasicity on Mesoporous Silica SBA-15
Lin Bing Sun, Jia Hui Kou, Yuan Chun, Jing Yang, Fang Na Gu, Ying Wang, Jian Hua Zhu, and Zhi Gang Zou
pp 4199 - 4208; DOI:
10.1021/ic702223b
PDF
Synthesis, Raman Spectra and Crystal Structures of [Cu(XeF2)n](SbF6)2 (n = 2, 4)
Zoran Mazej and Evgeny Goreshnik
pp 4209 - 4214; DOI:
10.1021/ic702249u
PDF
Three New Cu−Azido Polymers and Their Systematic Interconversion: Role of the Amount of the Blocking Amine on the Structural Diversity and Magnetic Behavior
Kartik Chandra Mondal and Partha Sarathi Mukherjee
pp 4215 - 4225; DOI:
10.1021/ic702232d
PDF
Structure and White Luminescence of Eu-Activated (Ba,Sr)13−xAl22−2xSi10+2xO66 Materials
Grégoire Denis, Philippe Deniard, Eric Gautron, Frédéric Clabau, Alain Garcia, and Stéphane Jobic
pp 4226 - 4235; DOI:
10.1021/ic702240q
PDF
Nanosecond CO Photodissociation and Excited-State Character of [Ru(X)(X′)(CO)2(N,N′-diisopropyl-1,4-diazabutadiene)] (X = X′ = Cl or I; X = Me, X′ = I; X = SnPh3, X′ = Cl) Studied by Time-Resolved Infrared Spectroscopy and DFT Calculations
Anders Gabrielsson, Mike Towrie, Stanislav Záliš, and Antonín Vlček Jr.
pp 4236 - 4242; DOI:
10.1021/ic702304k
PDF
A New Class of Luminescent Tricarbonyl Rhenium(I) Complexes Containing Bridging 1,2-Diazine Ligands: Electrochemical, Photophysical, and Computational Characterization
Daniela Donghi, Giuseppe D’Alfonso, Matteo Mauro, Monica Panigati, Pierluigi Mercandelli, Angelo Sironi, Patrizia Mussini, and Laura D’Alfonso
pp 4243 - 4255; DOI:
10.1021/ic7023692
PDF
Supramolecular Adsorption of Alkaloids by Metallosalphen Complexes
Eduardo C. Escudero-Adán, Jordi Benet-Buchholz, and Arjan W. Kleij
pp 4256 - 4263; DOI:
10.1021/ic702257e
PDF
Synthesis, Structures, and Properties of Group 9− and Group 10−Group 6 Heterodinuclear Nitrosyl Complexes
Kazuya Arashiba, Hidetaka Iizuka, Shoji Matsukawa, Shigeki Kuwata, Yoshiaki Tanabe, Masakazu Iwasaki, and Youichi Ishii
pp 4264 - 4274; DOI:
10.1021/ic702309h
PDF
Photophysical Behavior of Open-Shell First-Row Transition-Metal Octabutoxynaphthalocyanines: CoNc(OBu)8 and CuNc(OBu)8 as Case Studies
Alexandra V. Soldatova, Junhwan Kim, Angela Rosa, Giampaolo Ricciardi, Malcolm E. Kenney, and Michael A. J. Rodgers
pp 4275 - 4289; DOI:
10.1021/ic7023204
PDF
Ammine Magnesium Borohydride Complex as a New Material for Hydrogen Storage: Structure and Properties of Mg(BH4)2·2NH3
Grigorii Soloveichik, Jae-Hyuk Her, Peter W. Stephens, Yan Gao, Job Rijssenbeek, Matt Andrus, and J.-C. Zhao
pp 4290 - 4298; DOI:
10.1021/ic7023633
PDF
Reactivity of Chromium(III) Nutritional Supplements in Biological Media: An X-Ray Absorption Spectroscopic Study
Annie Nguyen, Irma Mulyani, Aviva Levina, and Peter A. Lay
pp 4299 - 4309; DOI:
10.1021/ic7024389
PDF
Modulating Affinities of Di-2-picolylamine (DPA)-Substituted Quinoline Sensors for Zinc Ions by Varying Pendant Ligands
Lin Xue, Huan-Huan Wang, Xiao-Jun Wang, and Hua Jiang
pp 4310 - 4318; DOI:
10.1021/ic702393z
PDF
Synthesis of Amidolanthanides with New Chiral Biaryl-Based NNO Ligands and Their Use as Catalysts for Enantioselective Hydroamination/Cyclization
Qiuwen Wang, Li Xiang, Haibin Song, and Guofu Zi
pp 4319 - 4328; DOI:
10.1021/ic702461f
PDF
Theoretical Study of Pyrazolate-Bridged Dinuclear Platinum(II) Complexes: Interesting Potential Energy Curve of the Lowest Energy Triplet Excited State and Phosphorescence Spectra
Ken Saito, Yoshihide Nakao, and Shigeyoshi Sakaki
pp 4329 - 4337; DOI:
10.1021/ic702367f
PDF
Transfer of Copper between Bis(thiosemicarbazone) Ligands and Intracellular Copper-Binding Proteins. Insights into Mechanisms of Copper Uptake and Hypoxia Selectivity
Zhiguang Xiao, Paul S. Donnelly, Matthias Zimmermann, and Anthony G. Wedd
pp 4338 - 4347; DOI:
10.1021/ic702440e
PDF
Ligand Localized Triplet Excited States in Platinum(II) Bipyridyl and Terpyridyl Peryleneacetylides
Aaron A. Rachford, Sébastien Goeb, Raymond Ziessel, and Felix N. Castellano
pp 4348 - 4355; DOI:
10.1021/ic702454k
PDF
Imidazole Substituent Effects on Oxidative Reactivity of Tripodal(imid)2(thioether)CuI Complexes
Lei Zhou and Kenneth M. Nicholas
pp 4356 - 4367; DOI:
10.1021/ic800007t
PDF
Syntheses, Crystal Structures, and Physical Properties of La5Cu6O4S7 and La5Cu6.33O4S7
George H. Chan, Ming-Ling Liu, Li-Dong Chen, Fu-Qiang Huang, Daniel E. Bugaris, Daniel M. Wells, John R. Ireland, Mark C. Hersam, Richard P. Van Duyne, and James A. Ibers
pp 4368 - 4374; DOI:
10.1021/ic7024796
PDF
Theoretical Study of the Reaction of B20H16 with MeCN: Closo/Closo to Closo/Nido Conversion
Oottikkal Shameema, Biswarup Pathak, and Eluvathingal D. Jemmis
pp 4375 - 4382; DOI:
10.1021/ic702509j
PDF
Ruthenium Complexes with Tetraphenylimidodiphosphinate: Syntheses, Structures, and Applications to Catalytic Organic Oxidation
Wai-Man Cheung, Ho-Yuen Ng, Ian D. Williams, and Wa-Hung Leung
pp 4383 - 4391; DOI:
10.1021/ic800018d
PDF
Synthesis and Characterization of (3,1) Ru2(F3ap)4(NCS) and (3,1) Ru2(F3ap)3(F2Oap)(NCS) Where F3ap Is the 2-(2,4,6-Trifluoroanilino)pyridinate Anion
Minh Nguyen, Tuan Phan, Eric Van Caemelbecke, Xin Wei, John L. Bear, and Karl M. Kadish
pp 4392 - 4400; DOI:
10.1021/ic8000703
PDF
Isostructural Potassium and Thallium Salts of Sterically Crowded Triazenes: A Structural and Computational Study
Hyui Sul Lee, Sven-Oliver Hauber, Denis Vinduš, and Mark Niemeyer
pp 4401 - 4412; DOI:
10.1021/ic800029z
PDF
Why Does Cyanide Pretend to be a Weak Field Ligand in [Cr(CN)5]3−?
Richard L. Lord and Mu-Hyun Baik
pp 4413 - 4420; DOI:
10.1021/ic8000653
PDF
Visible-Light Photolytic Synthesis of Multinuclear and Dendritic Iron-Nitrile Cationic Complexes
Cátia Ornelas, Jaime Ruiz, João Rodrigues, and Didier Astruc
pp 4421 - 4428; DOI:
10.1021/ic800100k
PDF

Issue 11


Cd2+-Induced Conformational Change of a Synthetic Metallopeptide: Slow Metal Binding Followed by a Slower Conformational Change
Madhumita Mukherjee, Xianchun Zhu, and Michael Y. Ogawa
pp 4430 - 4432; DOI:
10.1021/ic702370k
PDF
A Nanoporous Ag−Fe Mixed-Metal−Organic Framework Exhibiting Single-Crystal-to-Single-Crystal Transformations upon Guest Exchange
Yixun Zhang, Banglin Chen, Frank R. Fronczek, and Andrew W. Maverick
pp 4433 - 4435; DOI:
10.1021/ic800183v
PDF
A New Family of Spin-Crossover Complexes Based on a FeII(Tetrazolyl)4(MeCN)2-Type Core
Agata Białońska, Robert Bronisz, and Marek Weselski
pp 4436 - 4438; DOI:
10.1021/ic8002993
PDF
PN Bond Formation via Incomplete N-Atom Transfer from a Ferrous Amide Precursor
Debashis Adhikari, Falguni Basuli, Hongjun Fan, John C. Huffman, Maren Pink, and Daniel J. Mindiola
pp 4439 - 4441; DOI:
10.1021/ic800182m
PDF
T-Shaped Cationic CuI Complexes with Hemilabile PNP-Type Ligands
Jarl Ivar van der Vlugt, Evgeny A. Pidko, Dieter Vogt, Martin Lutz, Anthony L. Spek, and Auke Meetsma
pp 4442 - 4444; DOI:
10.1021/ic800298a
PDF
K3(U3O6)(Si2O7) and Rb3(U3O6)(Ge2O7): A Pentavalent-Uranium Silicate and Germanate
Chia-Hui Lin, Chih-Shan Chen, A. A. Shiryaev, Ya. V. Zubavichus, and Kwang-Hwa Lii
pp 4445 - 4447; DOI:
10.1021/ic800300v
PDF
Gold(I) Ethylene and Copper(I) Ethylene Complexes Supported by a Polyhalogenated Triazapentadienyl Ligand
Jaime A. Flores and H. V. Rasika Dias
pp 4448 - 4450; DOI:
10.1021/ic800373u
PDF
Polynuclear Cobalt(II/III) Sulfites: Synthesis, Structure, and Magnetic Properties of the Octanuclear Cluster (NH4)11(Li⊂[Co4IICo4III(SO3)16(NH3)8])·10H2O Encapsulating a Lithium Cation
George I. Chilas, Marios Stylianou, Maciej Kubicki, Tiverios Vaimakis, Paul Kögerler, Anastasios D. Keramidas, and Themistoklis A. Kabanos
pp 4451 - 4453; DOI:
10.1021/ic8004213
PDF
Breaking the Symmetry: Assembly of Cylindrical Nanostructures with a C3-Symmetrical Ligand
Céline Olivier, Euro Solari, Rosario Scopelliti, and Kay Severin
pp 4454 - 4456; DOI:
10.1021/ic8005508
PDF
Synthesis and Characterization of Diorganohydrazido(2–) Tungsten Complexes
Jürgen Koller, Hiral M. Ajmera, Khalil A. Abboud, Timothy J. Anderson, and Lisa McElwee-White
pp 4457 - 4462; DOI:
10.1021/ic701151m
PDF
Hydrogallation of Alkynes with H−GaCl2: Formation of Organoelement Dichlorogallium Compounds Potentially Applicable as Chelating Lewis Acids
Werner Uhl and Michael Claesener
pp 4463 - 4470; DOI:
10.1021/ic700767a
PDF
Synthesis and Properties of Diphenoxo-Bridged CoII, NiII, CuII, and ZnII Complexes of a New Tripodal Ligand: Generation and Properties of MII-Coordinated Phenoxyl Radical Species
Atasi Mukherjee, Francesc Lloret, and Rabindranath Mukherjee
pp 4471 - 4480; DOI:
10.1021/ic701283b
PDF
Metal-Organic Frameworks Constructed from 2,4,6-Tris(4-pyridyl)-1,3,5-triazine
Ming-Xing Li, Zhi-Xin Miao, Min Shao, Sheng-Wen Liang, and Shou-Rong Zhu
pp 4481 - 4489; DOI:
10.1021/ic701346x
PDF
Palladium(II) and Platinum(II) Organometallic Complexes with 4,7-dihydro-5-methyl-7-oxo[1,2,4]triazolo[1,5-a]pyrimidine. Antitumor Activity of the Platinum Compounds
José Ruiz, María Dolores Villa, Natalia Cutillas, Gregorio López, Concepción de Haro, Delia Bautista, Virtudes Moreno, and Laura Valencia
pp 4490 - 4505; DOI:
10.1021/ic701873b
PDF
Potassium Hydroxylamine Complexes
Ajay Venugopal, Raphael J. F. Berger, Alexander Willner, Tania Pape, and Norbert W. Mitzel
pp 4506 - 4512; DOI:
10.1021/ic701701e
PDF
Stabilization of a Helical Water Chain in a Metal-Organic Host of a Trinuclear Schiff Base Complex
Chaitali Biswas, Michael G. B. Drew, and Ashutosh Ghosh
pp 4513 - 4519; DOI:
10.1021/ic8002542
PDF
Iron Tetraanthracenotetraazaporphyrins: Synthesis, Structural Characterization, Ligand Binding Properties, and Unexpected Selectivity of a Bis-“Bowl” Tetraazaporphyrin
Jeffrey P. Fitzgerald, Joshua R. Lebenson, Guangbin Wang, Gordon T. Yee, Bruce C. Noll, and Roger D. Sommer
pp 4520 - 4530; DOI:
10.1021/ic702149z
PDF
Evaluation of CO Coordination Energies from Spectroscopic Data: On the Use of Vibrational Isotopic Effects
Benoît Tremblay and Laurent Manceron
pp 4531 - 4535; DOI:
10.1021/ic701960t
PDF
Tetranuclear Clusters Containing a CrIII-Doped MnIII4O2 Core: Syntheses, Structures, and Magnetic Properties
Yun-Sheng Ma, Yi-Zhi Li, You Song, and Li-Min Zheng
pp 4536 - 4544; DOI:
10.1021/ic701626k
PDF
Synthesis, Structure, and Electrocatalysis of Diiron C-Functionalized Propanedithiolate (PDT) Complexes Related to the Active Site of [FeFe]-Hydrogenases
Li-Cheng Song, Chang-Gong Li, Jie Gao, Bang-Shao Yin, Xiang Luo, Xiao-Guang Zhang, Hai-Lin Bao, and Qing-Mei Hu
pp 4545 - 4553; DOI:
10.1021/ic701982z
PDF
Direct Synthesis, Crystal Structures, High-Field EPR, and Magnetic Studies of Heterometallic Polymers Containing Manganese(II) Carboxylates Interconnected by [Cu(en)2]2+
Valeriya G. Makhankova, Asya O. Beznischenko, Vladimir N. Kokozay, Roman I. Zubatyuk, Oleg V. Shishkin, Julia Jezierska, and Andrew Ozarowski
pp 4554 - 4563; DOI:
10.1021/ic702017p
PDF
Self-Encapsulation of [MII(phen)2(H2O)2]2+ (M = Co, Zn) in One-Dimensional Nanochannels of [MII(H2O)6(BTC)2]4− (M = Co, Cu, Mn): A High HQ/CAT Ratio Catalyst for Hydroxylation of Phenols
Jianhong Bi, Lingtao Kong, Zixiang Huang, and Jinhuai Liu
pp 4564 - 4569; DOI:
10.1021/ic7022049
PDF
Interplay of Supramolecular Organization, Metallophilic Interactions, Phase Changes, and Luminescence in Four Polymorphs of IrI(CO)2(OC(CH3)CHC(CH3)N(p-tol))
Emily M. Gussenhoven, Marilyn M. Olmstead, James C. Fettinger, and Alan L. Balch
pp 4570 - 4578; DOI:
10.1021/ic702243z
PDF
Bis(α-diimine)iron Complexes: Electronic Structure Determination by Spectroscopy and Broken Symmetry Density Functional Theoretical Calculations
Nicoleta Muresan, Connie C. Lu, Meenakshi Ghosh, Jonas C. Peters, Megumi Abe, Lawrence M. Henling, Thomas Weyhermöller, Eckhard Bill, and Karl Wieghardt
pp 4579 - 4590; DOI:
10.1021/ic7022693
PDF
A Comparison of Neptunyl(V) and Neptunyl(VI) Solution Coordination: The Stability of Cation−Cation Interactions
S. Skanthakumar, Mark R. Antonio, and L. Soderholm
pp 4591 - 4595; DOI:
10.1021/ic702478w
PDF
Understanding Selectivity in the Oxidative Addition of the Carbon−Sulfur Bonds of 2-Cyanothiophene to Pt(0)
Tülay A. Ateşin, Abdurrahman Ç. Ateşin, Karlyn Skugrud, and William D. Jones
pp 4596 - 4604; DOI:
10.1021/ic702273a
PDF
Star-Shaped Molecule of MnII4O6 Core with an St = 10 High-Spin State. A Theoretical and Experimental Study with XPS, XMCD, and Other Magnetic Methods
Sumit Khanra, Karsten Kuepper, Thomas Weyhermüller, Manuel Prinz, Michael Raekers, Sebastian Voget, Andrei V. Postnikov, Frank M. F. de Groot, Simon J. George, Marin Coldea, Manfred Neumann, and Phalguni Chaudhuri
pp 4605 - 4617; DOI:
10.1021/ic7023007
PDF
Time-Resolved Laser Fluorescence Spectroscopy and Extended X-Ray Absorption Spectroscopy Investigations of the N3 Complexation of Eu(III), Cm(III), and Am(III) in an Ionic Liquid: Differences and Similarities
S. Stumpf, I. Billard, C. Gaillard, P. J. Panak, and K. Dardenne
pp 4618 - 4626; DOI:
10.1021/ic7023567
PDF
Identification of a Copper(I) Intermediate in the Conversion of 1-Aminocyclopropane Carboxylic Acid (ACC) into Ethylene by Cu(II)−ACC Complexes and Hydrogen Peroxide
Wadih Ghattas, Michel Giorgi, Yasmina Mekmouche, Tsunehiro Tanaka, Antal Rockenbauer, Marius Réglier, Yutaka Hitomi, and A. Jalila Simaan
pp 4627 - 4638; DOI:
10.1021/ic702303g
PDF
Dinitrogen and Acetylide Complexes of Low-Valent Chromium
Louise A. Berben and Stosh A. Kozimor
pp 4639 - 4647; DOI:
10.1021/ic702275g
PDF
Squarato−Metal(II) Complexes. 2. Unusual Bonding Mode for a Squarato-Bridged Trinuclear Copper(II) Complex
Ramon Vicente, Joan Cano, Eliseo Ruiz, Salah S. Massoud, and Franz A. Mautner
pp 4648 - 4655; DOI:
10.1021/ic702324q
PDF
Gd7I12Zn: A Group 12 Atom in the Octahedral Gd6 Cluster
Mar’yana Lukachuk, Lorenz Kienle, Chong Zheng, Hansjürgen Mattausch, and Arndt Simon
pp 4656 - 4660; DOI:
10.1021/ic800024n
PDF
1,4,7,10-Tetraazacyclododecane Metal Complexes as Potent Promoters of Phosphodiester Hydrolysis under Physiological Conditions
Michael Subat, Kristina Woinaroschy, Corinna Gerstl, Biprajit Sarkar, Wolfgang Kaim, and Burkhard König
pp 4661 - 4668; DOI:
10.1021/ic702413q
PDF
Developments in Heterobimetallic s-Block Systems: Synthesis and Structural Survey of Molecular M/Ae (M = Li, Na, K, Cs; Ae = Ca, Sr) Aryloxo Complexes
Maria Felisa Zuniga, Glen B. Deacon, and Karin Ruhlandt-Senge
pp 4669 - 4681; DOI:
10.1021/ic702466d
PDF
Theoretical and Experimental Studies of Diruthenium Tetracarboxylates Structure, Spectroscopy, and Electrochemistry
Maria Ana Castro, Adrian E. Roitberg, and Fabio D. Cukiernik
pp 4682 - 4690; DOI:
10.1021/ic702505z
PDF
Lanthanum(III) and Uranyl(VI) Diglycolamide Complexes: Synthetic Precursors and Structural Studies Involving Nitrate Complexation
Shanmugaperumal Kannan, Morgan A. Moody, Charles L. Barnes, and Paul B. Duval
pp 4691 - 4695; DOI:
10.1021/ic7025076
PDF
Distinct Reaction Pathways of Peralkylated LnIIAlIII Heterobimetallic Complexes with Substituted Phenols
Hanne-Marthe Sommerfeldt, Christian Meermann, Karl W. Törnroos, and Reiner Anwander
pp 4696 - 4705; DOI:
10.1021/ic702517s
PDF
Size Selective Self-Sorting in Coordination-Driven Self-Assembly of Finite Ensembles
Yao-Rong Zheng, Hai-Bo Yang, Brian H. Northrop, Koushik Ghosh, and Peter J. Stang
pp 4706 - 4711; DOI:
10.1021/ic800038j
PDF
Studies on the Properties of Organoselenium(IV) Fluorides and Azides
Thomas M. Klapötke, Burkhard Krumm, and Matthias Scherr
pp 4712 - 4722; DOI:
10.1021/ic800051s
PDF
A Unique Family of Stable and Water-Soluble S-Nitrosothiol Complexes
Laura L. Perissinotti, Gregory Leitus, Linda Shimon, Dario Estrin, and Fabio Doctorovich
pp 4723 - 4733; DOI:
10.1021/ic7024999
PDF
Charge, Orbital, and Magnetic Ordering in YBaFe2O5 from First-Principles Calculations
Xianfeng Hao, Yuanhui Xu, Minfeng Lv, Defeng Zhou, Zhijian Wu, and Jian Meng
pp 4734 - 4739; DOI:
10.1021/ic800060c
PDF
Synthesis and Structure of a New Heptaborate Oxoanion Isomer: B7O9(OH)52−
David M. Schubert, Mandana Z. Visi, Saeed Khan, and Carolyn B. Knobler
pp 4740 - 4745; DOI:
10.1021/ic800068t
PDF
Octahedral Tilting in MM′X4 Metal-Oxide Organic Layer Structures
Marie Vougo-Zanda, Ekaterina V. Anokhina, Selma Duhovic, Lumei Liu, Xiqu Wang, Oluwakemi A. Oloba, Thomas A. Albright, and Allan J. Jacobson
pp 4746 - 4751; DOI:
10.1021/ic8000448
PDF
Synthesis and Characterization of Three Homoleptic Alkoxides of Uranium: [Li(THF)]2[UIV(OtBu)6], [Li(Et2O)][UV(OtBu)6], and UVI(OtBu)6
Skye Fortier, Guang Wu, and Trevor W. Hayton
pp 4752 - 4761; DOI:
10.1021/ic800067k
PDF
On the Origin of Circular Dichroism in Trigonal Dihedral Cobalt (III) Complexes of Unsaturated Bidentate Ligands
Jing Fan and Tom Ziegler
pp 4762 - 4773; DOI:
10.1021/ic800072k
PDF
First Dinuclear B(II) Monocations with Bridging Guanidinate Ligands: Synthesis and Properties
Oxana Ciobanu, Dimitri Emeljanenko, Elisabeth Kaifer, Jürgen Mautz, and Hans-Jörg Himmel
pp 4774 - 4778; DOI:
10.1021/ic8000812
PDF
Determination of the Spin−Lattice Relevant for the Quaternary Magnetic Oxide Bi4Cu3V2O14 on the Basis of Tight-Binding and Density Functional Calculations
Hyun-Joo Koo and Myung-Hwan Whangbo
pp 4779 - 4784; DOI:
10.1021/ic800216j
PDF
Reactivity of a Phosphinito-Bridged PtI−PtI Complex with Nucleophiles: Substitution versus Addition
Vito Gallo, Mario Latronico, Piero Mastrorilli, Cosimo F. Nobile, Flavia Polini, Nazzareno Re, and Ulli Englert
pp 4785 - 4795; DOI:
10.1021/ic800045u
PDF
DFT Calculation of 1J(119Sn,13C) and 2J(119Sn,1H) Coupling Constants in Di- and Trimethyltin(IV) Compounds
Girolamo Casella, Francesco Ferrante, and Giacomo Saielli
pp 4796 - 4807; DOI:
10.1021/ic8000976
PDF
Redox Active Cage for the Electrochemical Sensing of Anions
Valeria Amendola, Massimo Boiocchi, Benoît Colasson, Luigi Fabbrizzi, Enrico Monzani, Maria Jesús Douton-Rodriguez, and Cristina Spadini
pp 4808 - 4816; DOI:
10.1021/ic800099j
PDF
Modeling the Vibronic Spectra of Transition Metal Complexes: The Ligand-Field Spectrum of [PtCl4]2−
Adam J. Bridgeman
pp 4817 - 4825; DOI:
10.1021/ic800091y
PDF
Unique Structural Trends in the Lanthanoid Oxocarbonyl Complexes
Ling Jiang, Xin-Bo Zhang, Song Han, and Qiang Xu
pp 4826 - 4831; DOI:
10.1021/ic800112d
PDF
Single-Molecule Magnets: A Family of MnIII/CeIV Complexes with a [Mn8CeO8]12+ Core
Abhudaya Mishra, Anastasios J. Tasiopoulos, Wolfgang Wernsdorfer, Eleni E. Moushi, Brian Moulton, Michael J. Zaworotko, Khalil A. Abboud, and George Christou
pp 4832 - 4843; DOI:
10.1021/ic8001064
PDF
Preparation, Structures, and Photocatalytic Properties of Three New Uranyl−Organic Assembly Compounds
Zuo-Lei Liao, Guo-Dong Li, Ming-Hui Bi, and Jie-Sheng Chen
pp 4844 - 4853; DOI:
10.1021/ic800109y
PDF
Tetranuclear [{Ni(HL3)}{W(CN)8}]2 Square: A Case of Antiferromagnetic {NiIIWV} Interactions
Thengarai S. Venkatakrishnan, Cédric Desplanches, Raghunathan Rajamani, Philippe Guionneau, Laurent Ducasse, S. Ramasesha, and Jean-Pascal Sutter
pp 4854 - 4860; DOI:
10.1021/ic800114y
PDF
Synthesis, Structure, and Physical Properties of a New Anions-Controlled Cd(II)-Guanazole (3,5-Diamino-1,2,4-triazole) Hybrid Family
Rui-Bo Zhang, Zhao-Ji Li, Ye-Yan Qin, Jian-Kai Cheng, Jian Zhang, and Yuan-Gen Yao
pp 4861 - 4876; DOI:
10.1021/ic8001042
PDF
Kinetics of Thermal Unfolding of Phenylalanine Hydroxylase Variants Containing Different Metal Cofactors (FeII, CoII, and ZnII) and Their Isokinetic Relationship
Aristobulo Loaiza, Kathryn M. Armstrong, Brian M. Baker, and Mahdi M. Abu-Omar
pp 4877 - 4883; DOI:
10.1021/ic800181q
PDF
Theoretical Study of P2O5 Polymorphs at High Pressure: Hexacoordinated Phosphorus
Miguel A. Salvadó and Pilar Pertierra
pp 4884 - 4890; DOI:
10.1021/ic8001543
PDF
Coordination Asymmetry in Divanadium(V) Compounds Containing a V2O3 Core: Synthesis, Characterization, and Redox Properties
Pabitra Baran Chatterjee, Subhajit Bhattacharya, Anandalok Audhya, Ki-Young Choi, Akira Endo, and Muktimoy Chaudhury
pp 4891 - 4902; DOI:
10.1021/ic800208w
PDF
Synthesis and Coordination Chemistry of Ferrocenyl-1,2,3-triazolyl Ligands
Sihem Badèche, Jean-Claude Daran, Jaime Ruiz, and Didier Astruc
pp 4903 - 4908; DOI:
10.1021/ic8002405
PDF
NMR and X-ray Structural Characterization of a Cisplatin Analogue Able To Slow Down the Pt−N7 Rotation of a Coordinated Guanine Base by a Billion-Fold Times: 2,2′-Bipiperidine(dimethylmalonato)platinum(II) Complex
Francesco P. Intini, Renzo Cini, Gabriella Tamasi, Michael B. Hursthouse, and Giovanni Natile
pp 4909 - 4917; DOI:
10.1021/ic800230p
PDF
Trinuclear Heterobimetallic Ni2Ln complexes [L2Ni2Ln][ClO4] (Ln = La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, and Er; LH3 = (S)P[N(Me)NCH−C6H3-2-OH-3-OMe]3): From Simple Paramagnetic Complexes to Single-Molecule Magnet Behavior
Vadapalli Chandrasekhar, Balasubramanian Murugesa Pandian, Ramamoorthy Boomishankar, Alexander Steiner, Jagadese J. Vittal, Ahmad Houri, and Rodolphe Clérac
pp 4918 - 4929; DOI:
10.1021/ic800199x
PDF
Incorporating Distinct Metal Clusters To Construct Diversity of 3D Pillared-Layer Lanthanide-Transition-Metal Frameworks
Jian-Wen Cheng, Shou-Tian Zheng, and Guo-Yu Yang
pp 4930 - 4935; DOI:
10.1021/ic800221j
PDF
Rare-Earth Metal(III) Oxide Selenides M4O4Se[Se2] (M = La, Ce, Pr, Nd, Sm) with Discrete Diselenide Units: Crystal Structures, Magnetic Frustration, and Other Properties
Sabine Strobel, Amitava Choudhury, Peter K. Dorhout, Christian Lipp, and Thomas Schleid
pp 4936 - 4944; DOI:
10.1021/ic800233c
PDF
Further Examples of the Failure of Surrogates to Properly Model the Structural and Hydrothermal Chemistry of Transuranium Elements: Insights Provided by Uranium and Neptunium Diphosphonates
Anna-Gay D. Nelson, Travis H. Bray, Wei Zhan, Richard G. Haire, Todd S. Sayler, and Thomas E. Albrecht-Schmitt
pp 4945 - 4951; DOI:
10.1021/ic800255h
PDF
Neutral Gold(I) Metallosupramolecular Compounds: Synthesis and Characterization, Photophysical Properties, and Density Functional Theory Studies
Laura Rodríguez, Carlos Lodeiro, João Carlos Lima, and Ramon Crehuet
pp 4952 - 4962; DOI:
10.1021/ic800266m
PDF
Detailed Assignment of the Magnetic Circular Dichroism and UV−vis Spectra of Five-Coordinate High-Spin Ferric [Fe(TPP)(Cl)]
Florian Paulat and Nicolai Lehnert
pp 4963 - 4976; DOI:
10.1021/ic8002838
PDF
Studies of the Carbon Dioxide and Epoxide Coupling Reaction in the Presence of Fluorinated Manganese(III) Acacen Complexes: Kinetics of Epoxide Ring-Opening
Donald J. Darensbourg and Eric B. Frantz
pp 4977 - 4987; DOI:
10.1021/ic800286p
PDF
Easy Access to Bio-Inspired Osmium(II) Complexes through Electrophilic Intramolecular C(sp2)-H Bond Cyclometalation
Ricardo Cerón-Camacho, David Morales-Morales, Simon Hernandez, Ronan Le Lagadec, and Alexander D. Ryabov
pp 4988 - 4995; DOI:
10.1021/ic800251t
PDF
Versatile Scorpionates and New Developments in the Denticity Changes of NNCp Hybrid Scorpionate/Cyclopentadienyl Ligands in Sc and Y Compounds: From κ1-Nη5-Cp to κ2-NNη5-Cp
Antonio Otero, Juan Fernández-Baeza, Agustín Lara-Sánchez, Antonio Antiñolo, Juan Tejeda, Emilia Martínez-Caballero, Isabel Márquez-Segovia, Isabel López-Solera, Luis F. Sánchez-Barba, and Carlos Alonso-Moreno
pp 4996 - 5005; DOI:
10.1021/ic800267v
PDF
High-Spin Mn4 and Mn10 Molecules: Large Spin Changes with Structure in Mixed-Valence MnII4MnIII6 Clusters with Azide and Alkoxide-Based Ligands
Theocharis C. Stamatatos, Katye M. Poole, Khalil A. Abboud, Wolfgang Wernsdorfer, Ted A. O’Brien, and George Christou
pp 5006 - 5021; DOI:
10.1021/ic800268z
PDF
Preparation of CdSe Quantum Dots with Full Color Emission Based on a Room Temperature Injection Technique
Liping Liu, Qing Peng, and Yadong Li
pp 5022 - 5028; DOI:
10.1021/ic800368u
PDF

Issue 12


Solid-Phase Synthesis of Tris-heteroleptic Ruthenium(II) Complexes and Application to Acetylcholinesterase Inhibition
Seann P. Mulcahy, Shan Li, Ricarda Korn, Xiulan Xie, and Eric Meggers
pp 5030 - 5032; DOI:
10.1021/ic800080b
PDF
Heteropolynuclear Complexes of 3,5-Dimethylpyrazolate [Pt2M4(Me2pz)8] (M = Ag, Cu). Highly Luminescent Character of the Triplet Excited State Based on Mixed-Metal Cores
Keisuke Umakoshi, Takashi Kojima, Keizo Saito, Seiji Akatsu, Masayoshi Onishi, Shoji Ishizaka, Noboru Kitamura, Yoshihide Nakao, Shigeyoshi Sakaki, and Yoshiki Ozawa
pp 5033 - 5035; DOI:
10.1021/ic702310t
PDF
Formation of Superoxide Anion on Aerial Oxidation of Cu(II)–Porphyrinogen in the Synthesis of Tetrakis(cyclohexyl)porphyrinogenCu(III) Anion
Dibyendu Bhattacharya, Suman Maji, Kuntal Pal, and Sabyasachi Sarkar
pp 5036 - 5038; DOI:
10.1021/ic800282j
PDF
QD-2: A Novel Open-Framework Aluminoborate with Intersecting Three-Dimensional Helical Channels
Guo-Ming Wang, Jin-Hua Li, Hai-Lan Huang, Hui Li, and Jing Zhang
pp 5039 - 5041; DOI:
10.1021/ic800593q
PDF
Stable P−N Bridged Cyclophosphazenes with a Spiro or Ansa Arrangement
Serap Beşli, Simon J. Coles, David B. Davies, Ayşen O. Erkovan, Michael B. Hursthouse, and Adem Kılıç
pp 5042 - 5044; DOI:
10.1021/ic800641s
PDF
Photocontrol of Spatial Orientation and DNA Cleavage Activity of Copper(II)-Bound Dipeptides Linked by an Azobenzene Derivative
Halan Prakash, Akemi Shodai, Hiroyuki Yasui, Hiromu Sakurai, and Shun Hirota
pp 5045 - 5047; DOI:
10.1021/ic8007443
PDF
Spectroscopic Effects of Excited-State Coupling in a Tetragonal Chromium(III) Complex
Rémi Beaulac and Christian Reber
pp 5048 - 5054; DOI:
10.1021/ic702281k
PDF
New Series of Asymmetrically Substituted Bis(1,2-dithiolato)-Nickel(III) Complexes Exhibiting Near IR Absorption and Structural Diversity
Vedichi Madhu and Samar K. Das
pp 5055 - 5070; DOI:
10.1021/ic701408m
PDF
Photoinduced Energy Transfer in a Conformationally Flexible Re(I)/Ru(II) Dyad Probed by Time-Resolved Infrared Spectroscopy: Effects of Conformation and Spatial Localization of Excited States
Timothy L. Easun, Wassim Z. Alsindi, Michael Towrie, Kate L. Ronayne, Xue-Zhong Sun, Michael D. Ward, and Michael W. George
pp 5071 - 5078; DOI:
10.1021/ic702005w
PDF
Dicobalt II−II, II−III, and III−III Complexes as Spectroscopic Models for Dicobalt Enzyme Active Sites
Frank B. Johansson, Andrew D. Bond, Ulla Gro Nielsen, Boujemaa Moubaraki, Keith S. Murray, Kevin J. Berry, James A. Larrabee, and Christine J. McKenzie
pp 5079 - 5092; DOI:
10.1021/ic7020534
PDF
Synthesis, Structure and Application of Chiral Copper(II) Coordination Polymers for Asymmetric Acylation
Suribabu Jammi, Laxmidhar Rout, Prasenjit Saha, Vijay K. Akkilagunta, Sridhar Sanyasi, and Tharmalingam Punniyamurthy
pp 5093 - 5098; DOI:
10.1021/ic800228c
PDF
Synthesis and Photophysical Studies of Calix[4]arene-based Binuclear Platinum(II) Complexes: Probing Metal−Metal and Ligand−Ligand Interactions
Jie Ding, Dun Pan, Chen-Ho Tung, and Li-Zhu Wu
pp 5099 - 5106; DOI:
10.1021/ic702022p
PDF
New 3D and Chiral 1D CuIICrIII Coordination Polymers Exhibiting Ferromagnetism
Olha Sereda, Joan Ribas, and Helen Stoeckli-Evans
pp 5107 - 5113; DOI:
10.1021/ic702234y
PDF
Directing Aryl−I versus Aryl−Br Bond Activation by Nickel via a Ring Walking Process
Olena V. Zenkina, Amir Karton, Dalia Freeman, Linda J. W. Shimon, Jan M. L. Martin, and Milko E. van der Boom
pp 5114 - 5121; DOI:
10.1021/ic702289n
PDF
Reversible Anion Exchange and Sensing in Large Porous Materials Built from 4,4′-Bipyridine via π···π and H-Bonding Interactions
Yongcai Qiu, Zhihui Liu, Yinghua Li, Hong Deng, Ronghua Zeng, and Matthias Zeller
pp 5122 - 5128; DOI:
10.1021/ic702366t
PDF
Nitrogen-Ligated Iron Complexes: Photolytic Approach to the FeN+ Moiety
Drew Buschhorn, Maren Pink, Hongjun Fan, and Kenneth G. Caulton
pp 5129 - 5135; DOI:
10.1021/ic702279b
PDF
Rhenium and Technetium Complexes with Tridentate N-[(N′′,N′′-Dialkylamino)(thiocarbonyl)]-N′-substituted Benzamidine Ligands
Nguyen Hung Huy, Jacqueline Grewe, Jennifer Schroer, Bernd Kuhn, and Ulrich Abram
pp 5136 - 5144; DOI:
10.1021/ic702344s
PDF
pH-Dependent Assembly of Hybrids Based on Wells-Dawson POM/Ag Chemistry
Jingquan Sha, Jun Peng, Yaqan Lan, Zhongmin Su, Haijun Pang, Aixiang Tian, Pengpeng Zhang, and Min Zhu
pp 5145 - 5153; DOI:
10.1021/ic702407y
PDF
Reactions of the (2-Pyridyl) Pyrrolide Platinum(II) Complex Driven by Sterically Encumbered Chelation: A Model for the Reversible Attack of Alcohol at the Coordinated Carbon Monoxide
Jing-Lin Chen, Chen-Huey Lin, Jian-Hong Chen, Yun Chi, Yuan-Chieh Chiu, Pi-Tai Chou, Cheng-Hsuan Lai, Gene-Hsiang Lee, and Arthur J. Carty
pp 5154 - 5161; DOI:
10.1021/ic800117v
PDF
Syntheses, Structures, Photoluminescence, and Magnetic Properties of Phenanthrene-Based Carboxylic Acid Coordination Polymers
Zhaorui Pan, You Song, Yan Jiao, Zhijie Fang, Yizhi Li, and Hegen Zheng
pp 5162 - 5168; DOI:
10.1021/ic702473y
PDF
“Turn-On” Fluorescent Sensor for Hg2+ via Displacement Approach
Guangjie He, Yonggang Zhao, Cheng He, Yang Liu, and Chunying Duan
pp 5169 - 5176; DOI:
10.1021/ic702494s
PDF
Use of Bifunctional Phosphonates for the Preparation of Heterobimetallic 5f−3d Systems
Andrea N. Alsobrook, Wei Zhan, and Thomas E. Albrecht-Schmitt
pp 5177 - 5183; DOI:
10.1021/ic800192r
PDF
67Zn Solid-State NMR Spectroscopy of {[TpBut,Me]Zn(OH2)}[HOB(C6F5)3]. The Importance of the Anion [HOB(C6F5)3]
Andrew S. Lipton, Melissa M. Morlok, Gerard Parkin, and Paul D. Ellis
pp 5184 - 5189; DOI:
10.1021/ic800009b
PDF
Functionalized Europium Nanorods for In Vitro Imaging
Ka-Leung Wong, Ga-Lai Law, Margaret B. Murphy, Peter A. Tanner, Wing-Tak Wong, Paul Kwan-Sing Lam, and Michael Hon-Wah Lam
pp 5190 - 5196; DOI:
10.1021/ic8000416
PDF
Self-Assembly of a Copper(II)-Based Metallosupramolecular Hexagon
Eugenio Coronado, José Ramón Galan-Mascaros, Pablo Gaviña, Carlos Martí-Gastaldo, Francisco M. Romero, and Sergio Tatay
pp 5197 - 5203; DOI:
10.1021/ic8000569
PDF
Valence-State Alternatives in Diastereoisomeric Complexes [(acac)2Ru(μ-QL)Ru(acac)2]n (QL2− = 1,4-Dioxido-9,10-anthraquinone,n = +2, +1, 0, −1, −2)
Somnath Maji, Biprajit Sarkar, Shaikh M. Mobin, Jan Fiedler, Francisco A. Urbanos, Reyes Jimenez-Aparicio, Wolfgang Kaim, and Goutam Kumar Lahiri
pp 5204 - 5211; DOI:
10.1021/ic800115q
PDF
Preparation of Sr7Mn4O13F2 by the Topotactic Reduction and Subsequent Fluorination of Sr7Mn4O15
Ian Saratovsky, Michelle A. Lockett, Nicholas H. Rees, and Michael A. Hayward
pp 5212 - 5217; DOI:
10.1021/ic800066g
PDF
Crystalline-State Guest-Exchange and Gas-Adsorption Phenomenon for a “Soft” Supramolecular Porous Framework Stacking by a Rigid Linear Coordination Polymer
Sheng Hu, Kun-Huan He, Ming-Hua Zeng, Hua-Hong Zou, and Yi-Min Jiang
pp 5218 - 5224; DOI:
10.1021/ic800050u
PDF
Hydrothermal Reaction of Cu(II)/Pyrazine-2,3,5-tricarboxylic acid and Characterization of the Copper(II) Complexes
Feng-Qin Wang, Wei-Hua Mu, Xiang-Jun Zheng, Li-Cun Li, De-Cai Fang, and Lin-Pei Jin
pp 5225 - 5233; DOI:
10.1021/ic8001916
PDF
Preparation and Structural Characterization of the Ih and the D5h Isomers of the Endohedral Fullerenes Tm3N@C80: Icosahedral C80 Cage Encapsulation of a Trimetallic Nitride Magnetic Cluster with Three Uncoupled Tm3+ Ions
Tianming Zuo, Marilyn M. Olmstead, Christine M. Beavers, Alan L. Balch, Guangbin Wang, Gordon T. Yee, Chunying Shu, Liaosa Xu, Bevan Elliott, Luis Echegoyen, James C. Duchamp, and Harry C. Dorn
pp 5234 - 5244; DOI:
10.1021/ic800227x
PDF
Reversible Redox-Switchable Second-Order Optical Nonlinearity in Polyoxometalate: A Quantum Chemical Study of [PW11O39(ReN)]n (n = 3−7)
Wei Guan, Guochun Yang, Chunguang Liu, Ping Song, Liang Fang, Likai Yan, and Zhongmin Su
pp 5245 - 5252; DOI:
10.1021/ic8001527
PDF
Electronic Structure of Alkoxychromium(0) Carbene Complexes: A Joint TD-DFT/Experimental Study
Marta L. Lage, Israel Fernández, María J. Mancheño, and Miguel A. Sierra
pp 5253 - 5258; DOI:
10.1021/ic800187r
PDF
Theoretical Characterization of the Lowest Triplet Excited States of the Tris-(1,4,5,8-tetraazaphenanthrene) Ruthenium Dication Complex
Fabienne Alary, Martial Boggio-Pasqua, Jean-Louis Heully, Colin J. Marsden, and Patricia Vicendo
pp 5259 - 5266; DOI:
10.1021/ic800246t
PDF
Manganese(II) Pyrimidine-4,6-dicarboxylates: Synthetic, Structural, Magnetic, and Adsorption Insights
Garikoitz Beobide, Wen-guo Wang, Oscar Castillo, Antonio Luque, Pascual Román, Giulia Tagliabue, Simona Galli, and Jorge A. R. Navarro
pp 5267 - 5277; DOI:
10.1021/ic8002788
PDF
New Pyrazole-Based Ligands with Two Tripodal Binding Pockets: Potential Scaffolds for Metallobiosite Modeling
Holger Müller, Bernhard Bauer-Siebenlist, Edit Csapo, Sebastian Dechert, Etelka Farkas, and Franc Meyer
pp 5278 - 5292; DOI:
10.1021/ic800248b
PDF
Synthesis, Characterization, and Electronic Structure of Diimine Complexes of Chromium
Kevin A. Kreisel, Glenn P. A. Yap, and Klaus H. Theopold
pp 5293 - 5303; DOI:
10.1021/ic800302w
PDF
Synthesis, Structure, and Polymorphism Studies in Amine-Templated Open-Framework Zinc Phosphites
Sukhendu Mandal and Srinivasan Natarajan
pp 5304 - 5313; DOI:
10.1021/ic800333g
PDF
Redox Transformations of Bis(2,2′-bipyridine)(1-methyl-1-pyridin-2-yl-ethylamine)ruthenium(II)
Justin Neill, Anna S. Nam, Kevin M. Barley, Benjamin Meza, and David N. Blauch
pp 5314 - 5323; DOI:
10.1021/ic800483g
PDF
From Unstable to Stable: Half-Metallocene Catalysts for Olefin Polymerization
Prabhuodeyara M. Gurubasavaraj, Herbert W. Roesky, Bijan Nekoueishahraki, Aritra Pal, and Regine Herbst-Irmer
pp 5324 - 5331; DOI:
10.1021/ic800198e
PDF
Assembly of [(η5-C5Me5)MoS3Cu3]-Supported One-Dimensional Chains with Single, Double, Triple, and Quadruple Strands
Wen-Hua Zhang, Ying-Lin Song, Zhen-Hong Wei, Ling-Ling Li, Yu-Jian Huang, Yong Zhang, and Jian-Ping Lang
pp 5332 - 5346; DOI:
10.1021/ic8003454
PDF
Barrel- and Crown-Shaped Dodecanuclear Copper(II) Cages Built from Phosphonate, Pyrazole, and Hydroxide Ligands
Vadapalli Chandrasekhar, Loganathan Nagarajan, Rodolphe Clérac, Surajit Ghosh, Tapas Senapati, and Sandeep Verma
pp 5347 - 5354; DOI:
10.1021/ic800509f
PDF
Efficient Hydrogen Sorption in 8-Connected MOFs Based on Trinuclear Pinwheel Motifs
Hyungphil Chun, Heejin Jung, Gumae Koo, Heondo Jeong, and Dong-Kook Kim
pp 5355 - 5359; DOI:
10.1021/ic800274w
PDF
Mono-oxo Bis(dithiolene) Mo(IV)/W(IV) Complexes as Building Blocks for Sulfide Bridged Bi- and Tri-Nuclear Complexes
Amit Majumdar, Joyee Mitra, Kuntal Pal, and Sabyasachi Sarkar
pp 5360 - 5364; DOI:
10.1021/ic800466x
PDF
Covalency Trends in Group IV Metallocene Dichlorides. Chlorine K-Edge X-Ray Absorption Spectroscopy and Time Dependent-Density Functional Theory
Stosh A. Kozimor, Ping Yang, Enrique R. Batista, Kevin S. Boland, Carol J. Burns, Christin N. Christensen, David L. Clark, Steven D. Conradson, P. Jeffrey Hay, Juan S. Lezama, Richard L. Martin, Daniel E. Schwarz, Marianne P. Wilkerson, and Laura E. Wolfsberg
pp 5365 - 5371; DOI:
10.1021/ic8004932
PDF
N,N-Di-iso-propylcarbamato Complexes of Boron
Daniela Belli Dell’Amico, Fausto Calderazzo, Luca Labella, and Fabio Marchetti
pp 5372 - 5376; DOI:
10.1021/ic7024523
PDF
Metathesis of Nitrogen Atoms within Triple Bonds Involving Carbon, Tungsten, and Molybdenum
Beth A. Burroughs, Bruce E. Bursten, Shentan Chen, Malcolm H. Chisholm, and Andy R. Kidwell
pp 5377 - 5385; DOI:
10.1021/ic8003917
PDF
Macrocyclic Nickel(II) Complexes Coligated by Hydrosulfide and Hexasulfide Ions: Syntheses, Structures, and Magnetic Properties of [NiII2L(μ-SH)]+ and [{LNiII2}2(μ-S6)]2+
Vasile Lozan and Berthold Kersting
pp 5386 - 5393; DOI:
10.1021/ic8003432
PDF
Variation of Average g Values and Effective Exchange Coupling Constants among [2Fe−2S] Clusters: A Density Functional Theory Study of the Impact of Localization (Trapping Forces) versus Delocalization (Double-Exchange) as Competing Factors
Maylis Orio and Jean-Marie Mouesca
pp 5394 - 5416; DOI:
10.1021/ic701730h
PDF
The Reversible Amination of Tin(II)-Ligated Imines: Latent Initiators for the Polymerization of rac-Lactide
Nonsee Nimitsiriwat, Vernon C. Gibson, Edward L. Marshall, and Mark R. J. Elsegood
pp 5417 - 5424; DOI:
10.1021/ic701671s
PDF
Supramolecular Metal-Polypyridyl and Ru(II) Porphyrin Complexes: Photophysical, Electron Paramagnetic Resonance, and Electrochemical Studies
Fabrizia Fabrizi de Biani, Emanuela Grigiotti, Franco Laschi, Piero Zanello, Alberto Juris, Luca Prodi, Kelly S. Chichak, and Neil R. Branda
pp 5425 - 5440; DOI:
10.1021/ic7018428
PDF
Binuclear Cyclometalated Organoplatinum Complexes Containing 1,1′-Bis(diphenylphosphino)ferrocene as Spacer Ligand: Kinetics and Mechanism of MeI Oxidative Addition
Sirous Jamali, S. Masoud Nabavizadeh, and Mehdi Rashidi
pp 5441 - 5452; DOI:
10.1021/ic701910d
PDF
Microwave-Assisted Homogeneous Precipitation of Hydrotalcites by Urea Hydrolysis
P. Benito, M. Herrero, C. Barriga, F. M. Labajos, and V. Rives
pp 5453 - 5463; DOI:
10.1021/ic7023023
PDF
Ligand-Field Photolysis of [Mo(CN)8]4− in Aqueous Hydrazine: Trapped Mo(II) Intermediate and Catalytic Disproportionation of Hydrazine by Cyano-Ligated Mo(III,IV) Complexes
Janusz Szklarzewicz, Dariusz Matoga, Agnieszka Kłyś, and Wiesław Łasocha
pp 5464 - 5472; DOI:
10.1021/ic800053e
PDF
Tuning the Activity of Zn(II) Complexes in DNA Cleavage: Clues for Design of New Efficient Metallo-Hydrolases
Carla Bazzicalupi, Andrea Bencini, Claudia Bonaccini, Claudia Giorgi, Paola Gratteri, Stefano Moro, Manlio Palumbo, Alessandro Simionato, Jacopo Sgrignani, Claudia Sissi, and Barbara Valtancoli
pp 5473 - 5484; DOI:
10.1021/ic800085n
PDF
Structure and Heats of Formation of Iodine Fluorides and the Respective Closed-Shell Ions from CCSD(T) Electronic Structure Calculations and Reliable Prediction of the Steric Activity of the Free-Valence Electron Pair in ClF6, BrF6, and IF6
David A. Dixon, Daniel J. Grant, Karl O. Christe, and Kirk A. Peterson
pp 5485 - 5494; DOI:
10.1021/ic800021h
PDF
Electrical Properties and Electronic States of Molecular Conductors Based on Unsymmetrical Organometallic-Dithiolene Gold(III) Complexes
Kazuya Kubo, Akiko Nakao, Yasuyuki Ishii, Takashi Yamamoto, Masafumi Tamura, Reizo Kato, Kyuya Yakushi, and Gen-etsu Matsubayashi
pp 5495 - 5502; DOI:
10.1021/ic800176q
PDF
Synthesis, Characterization, and Catalytic Activity of Rare Earth Metal Amides Supported by a Diamido Ligand with a CH2SiMe2 Link
Yunjun Wu, Shaowu Wang, Xiancui Zhu, Gaosheng Yang, Yun Wei, Lijun Zhang, and Hai-bin Song
pp 5503 - 5511; DOI:
10.1021/ic800496d
PDF
Immobilization of Palladium in Mesoporous Silica Matrix: Preparation, Characterization, and Its Catalytic Efficacy in Carbon−Carbon Coupling Reactions
Sreyashi Jana, Buddhadeb Dutta, Rajesh Bera, and Subratanath Koner
pp 5512 - 5520; DOI:
10.1021/ic8004294
PDF

Issue 13


Hollow Single-Crystal Spinel Nanocubes: The Case of Zinc Cobalt Oxide Grown by a Unique Kirkendall Effect
Li Tian, Xianfeng Yang, Ping Lu, Ian D. Williams, Caihong Wang, Shunying Ou, Chaolun Liang, and Mingmei Wu
pp 5522 - 5524; DOI:
10.1021/ic702457b
PDF
Polymorphism in Homochiral Zinc Phosphonates
Xun-Gao Liu, Song-Song Bao, Yi-Zhi Li, and Li-Min Zheng
pp 5525 - 5527; DOI:
10.1021/ic800663t
PDF
Cyclodimers versus Cyclotrimers via Solvent or Temperature Effects on Metallacyclization
Hyun Ji Kang, Tae Hwan Noh, Jong Sung Jin, and Ok-Sang Jung
pp 5528 - 5530; DOI:
10.1021/ic800436n
PDF
Molecular Hysteresis in a Rigid Dinuclear Ruthenium Polypyridyl Complex Incorporating a Ligand-Bound Ambidentate Motif
Olof Johansson and Reiner Lomoth
pp 5531 - 5533; DOI:
10.1021/ic800075b
PDF
Factors Involved in the Nuclearity of Silver Thiosemicarbazone Clusters: Cocrystallization of Two Different Sized Tetranuclear Silver(I) Clusters Derived from a Phosphinothiosemicarbazone Ligand
Alfonso Castiñeiras and Rosa Pedrido
pp 5534 - 5536; DOI:
10.1021/ic800178v
PDF
Synthesis and Structural Determination of a Hexanuclear Zirconium Glycine Compound Formed in Aqueous Solution
Long Pan, Ryan Heddy, Jing Li, Chong Zheng, Xiao-Ying Huang, Xiaozhong Tang, and Latonya Kilpatrick
pp 5537 - 5539; DOI:
10.1021/ic800292e
PDF
D+−π−A Charge-Transfer Molecules Based on Tricyanoquinodimethane and Diphosphine Metal Complexes
Javier Ruiz, Maria J. Antón, Marilín Vivanco, Marta E. G. Mosquera, and Roberto Quesada
pp 5540 - 5542; DOI:
10.1021/ic8008333
PDF
Metal−Organic Framework with Rationally Tuned Micropores for Selective Adsorption of Water over Methanol
Banglin Chen, Yanyan Ji, Ming Xue, Frank R. Fronczek, Eric J. Hurtado, Jalal U. Mondal, Chengdu Liang, and Sheng Dai
pp 5543 - 5545; DOI:
10.1021/ic8004008
PDF
Electronic State of the Dimethyl Sulfoxide Reductase Active Site
Matthias Hofmann
pp 5546 - 5548; DOI:
10.1021/ic800519d
PDF
Radical−Ligand-Derived C−N Coupling, Ga(III)−Radical vs Low-Spin Co(III)−Radical Reactivity
Phalguni Chaudhuri, Eckhard Bill, Rita Wagner, Ulrich Pieper, Biplab Biswas, and Thomas Weyhermüller
pp 5549 - 5551; DOI:
10.1021/ic8006348
PDF
Facile Construction of a Novel Aminoquinazolinate Anionic Ligand through Organolanthanide-Mediated Intermolecular Nucleophilic Addition/Cyclization of Anthranilonitrile
Jie Zhang, Yanan Han, Fuyan Han, Zhenxia Chen, Linhong Weng, and Xigeng Zhou
pp 5552 - 5554; DOI:
10.1021/ic800782r
PDF
Catenation of Loop-Containing 2D Layers with a 3D pcu Skeleton into a New Type of Entangled Framework Having Polyrotaxane and Polycatenane Character
Chao Qin, Xin-Long Wang, En-Bo Wang, and Zhong-Min Su
pp 5555 - 5557; DOI:
10.1021/ic8004536
PDF
Synthesis of Superparamagnetic β-MnO2 Organosol: a Photocatalyst for the Oxidative Phenol Coupling Reaction
Subhra Jana, Surojit Pande, Arun Kumar Sinha, and Tarasankar Pal
pp 5558 - 5560; DOI:
10.1021/ic800499q
PDF
One-Size Adjustable-Gap Cluster Anions: Systematic Approach to Multinary, Water-Soluble Chalcogenidometalate Compounds
Felicitas Lips and Stefanie Dehnen
pp 5561 - 5563; DOI:
10.1021/ic8008199
PDF
Toward a Facile One-Step Construction of Quantum Dots Containing Zn8S Cores
Jingli Xie
pp 5564 - 5566; DOI:
10.1021/ic800721r
PDF
Ionothermal Synthesis of Homochiral Framework with Acetate-Pillared Cobalt−Camphorate Architecture
Shumei Chen, Jian Zhang, and Xianhui Bu
pp 5567 - 5569; DOI:
10.1021/ic8007798
PDF
A Convergent Approach to the Synthesis of Multimetallic Dithiolene Complexes
Kuppuswamy Arumugam, Rongmin Yu, Dino Villagrán, Thomas G. Gray, Joel T. Mague, and James P. Donahue
pp 5570 - 5572; DOI:
10.1021/ic800880s
PDF
Synthesis and Characterization of High Nuclearity Iron(III) Phosphonate Molecular Clusters
Sanjit Konar and Abraham Clearfield
pp 5573 - 5579; DOI:
10.1021/ic702453g
PDF
Synthesis and Characterization of a Family of Penta- and Tetra-Manganese(III) Complexes Derived from an Assembly System Containing tert-Butylphosphonic Acid
Mei Wang, Cheng-Bing Ma, Da-Qiang Yuan, Hui-Sheng Wang, Chang-Neng Chen, and Qiu-Tian Liu
pp 5580 - 5590; DOI:
10.1021/ic701343s
PDF
Hard and Soft Acids and Bases: Atoms and Atomic Ions
James L. Reed
pp 5591 - 5600; DOI:
10.1021/ic701377n
PDF
Lanthanide-Centered Covalently Bonded Hybrids through Sulfide Linkage: Molecular Assembly, Physical Characterization, and Photoluminescence
Bing Yan and Hai-Feng Lu
pp 5601 - 5611; DOI:
10.1021/ic7021825
PDF
Pentadecatungstate with Dinuclear Cerium(III) Unit: Synthesis, Crystal Structure and Properties
Taohai Li, Feng Li, Jian Lü, Zhengang Guo, Shuiying Gao, and Rong Cao
pp 5612 - 5615; DOI:
10.1021/ic700726d
PDF
Ruthenium(II) 2,2′-Bibenzimidazole Complex as a Second-Sphere Receptor for Anions Interaction and Colorimeter
Ying Cui, Yan-Li Niu, Man-Li Cao, Ke Wang, Hao-Jun Mo, Yong-Rui Zhong, and Bao-Hui Ye
pp 5616 - 5624; DOI:
10.1021/ic702050b
PDF
Photosensitizer in a Molecular Bowl and its Effect on the DNA-Binding and -Cleavage Activity of 3d-Metal Scorpionates
Sovan Roy, Ashis K. Patra, Shanta Dhar, and Akhil R. Chakravarty
pp 5625 - 5633; DOI:
10.1021/ic702508r
PDF
Solution Study of a Structurally Characterized Monoalkoxo-Bound Monooxo-Vanadium(V) Complex: Spontaneous Generation of the Corresponding Oxobridged Divanadium(V,V) Complex and its Electroreduction to a Mixed-Valence Species in Solution
Rupam Dinda, Parbati Sengupta, Manas Sutradhar, Thomas C. W. Mak, and Saktiprosad Ghosh
pp 5634 - 5640; DOI:
10.1021/ic702172p
PDF
Synthesis, Characterization, and in Vitro Cytotoxicity of Some Gold(I) and Trans Platinum(II) Thionate Complexes Containing Water-Soluble PTA and DAPTA Ligands. X-ray Crystal Structures of [Au(SC4H3N2)(PTA)], trans-[Pt(SC4H3N2)2(PTA)2], trans-[Pt(SC5H4N)2(PTA)2], and trans-[Pt(SC5H4N)2(DAPTA)2]
Susana Miranda, Elena Vergara, Fabian Mohr, Dick de Vos, Elena Cerrada, Aránzazu Mendía, and Mariano Laguna
pp 5641 - 5648; DOI:
10.1021/ic7021903
PDF
Room-Temperature and Near-Room-Temperature Molecule-Based Magnets
Mark D. Harvey, T. Daniel Crawford, and Gordon T. Yee
pp 5649 - 5655; DOI:
10.1021/ic702359g
PDF
Synthesis and Structure of [2 × 2] Molecular Grid Copper(II) and Nickel(II) Complexes with a New Polydentate Oxime-Containing Schiff Base Ligand
Yurii S. Moroz, Kinga Kulon, Matti Haukka, Elżbieta Gumienna-Kontecka, Henryk Kozłowski, Franc Meyer, and Igor O. Fritsky
pp 5656 - 5665; DOI:
10.1021/ic702375h
PDF
Generation of Blue Light-Emitting Zinc Complexes by Band-Gap Control of the Oxazolylphenolate Ligand System: Syntheses, Characterizations, and Organic Light Emitting Device Applications of 4-Coordinated Bis(2-oxazolylphenolate) Zinc(II) Complexes
Ho-Jin Son, Won-Sik Han, Ji-Yun Chun, Byoung-Kook Kang, Soon-Nam Kwon, Jaejung Ko, Su Jung Han, Chongmok Lee, Sung Joo Kim, and Sang Ook Kang
pp 5666 - 5676; DOI:
10.1021/ic702491j
PDF
Sarcoplasmic Reticulum Calcium ATPase Is Inhibited by Organic Vanadium Coordination Compounds: Pyridine-2,6-dicarboxylatodioxovanadium(V), BMOV, and an Amavadine Analogue
Manuel Aureliano, Fernando Henao, Teresa Tiago, Rui O. Duarte, J. J. G. Moura, Bharat Baruah, and Debbie C. Crans
pp 5677 - 5684; DOI:
10.1021/ic702405d
PDF
Novel Chelate Ring-Opening Induced by Silver(I) of Five-Coordinate Palladium(II) and Platinum(II) Complexes Containing Tripodal Polyphosphines
D. Fernández-Anca, M. Inés García-Seijo, Alfonso Castiñeiras, and M. Esther García-Fernández
pp 5685 - 5695; DOI:
10.1021/ic702419r
PDF
Self-Exchange Reaction of [Ni(mnt)2]1−,2− in Nonaqueous Solutions
Bruce A. Kowert, Michael J. Fehr, and Pamela J. Sheaff
pp 5696 - 5701; DOI:
10.1021/ic702436x
PDF
Effect of Chelate Dynamics on Water Exchange Reactions of Paramagnetic Aminopolycarboxylate Complexes
Joachim Maigut, Roland Meier, Achim Zahl, and Rudi van Eldik
pp 5702 - 5719; DOI:
10.1021/ic702421z
PDF
Detailed Magnetic Studies on Co(N3)2(4-acetylpyridine)2: a Weak-Ferromagnet with a Very Big Canting Angle
Xin-Yi Wang, Zhe-Ming Wang, and Song Gao
pp 5720 - 5726; DOI:
10.1021/ic7023549
PDF
Self-Assembly of a Cyclic Metalladecapyridine from the Reaction of 2,6-Bis(bis(2-pyridyl)methoxymethane)pyridine with Silver(I)
Jie-Sheng Huang, Jin Xie, Steven C. F. Kui, Guo-Su Fang, Nianyong Zhu, and Chi-Ming Che
pp 5727 - 5735; DOI:
10.1021/ic8000043
PDF
Synthesis, Structures, and Magnetic Properties of Face-Sharing Heterodinuclear Ni(II)−Ln(III) (Ln = Eu, Gd, Tb, Dy) Complexes
Tomoka Yamaguchi, Yukinari Sunatsuki, Hiroyuki Ishida, Masaaki Kojima, Haruo Akashi, Nazzareno Re, Naohide Matsumoto, Andrzej Pochaba, and Jerzy Mroziński
pp 5736 - 5745; DOI:
10.1021/ic8000575
PDF
Solvation of UCl62− Anionic Complex by MeBu3N+, BuMe2Im+, and BuMeIm+ Cations
Emilie Bossé, Christophe Den Auwer, Claude Berthon, Philippe Guilbaud, Mikhail S. Grigoriev, Serguei Nikitenko, Claire Le Naour, Céline Cannes, and Philippe Moisy
pp 5746 - 5755; DOI:
10.1021/ic702477z
PDF
Catalytic Phenylborylation Reaction by Iridium(0) Nanoparticles Produced from Hydridoiridium Carborane
Zhu Yinghuai, Koh Chenyan, Ang Thiam Peng, A. Emi, Winata Monalisa, Loo Kui-Jin Louis, Narayan S. Hosmane, and John A. Maguire
pp 5756 - 5761; DOI:
10.1021/ic8000152
PDF
Synthesis, X-Ray Crystallographic Characterization, and Electronic Structure Studies of a Di-Azide Iron(III) Complex: Implications for the Azide Adducts of Iron(III) Superoxide Dismutase
Laurie E. Grove, Jason K. Hallman, Joseph P. Emerson, Jason A. Halfen, and Thomas C. Brunold
pp 5762 - 5774; DOI:
10.1021/ic800073t
PDF
Structures of [(n-C4H9)2NH2]2Cd9Cl20·2H2O and [Cu(C14H24N4)]2Cu13Cl30(H2O)2·xH2O: Perforated Layer Structures Based on the CdCl2 Layer Network
Adrienne A. Thorn, Roger D. Willett, and Brendan Twamley
pp 5775 - 5779; DOI:
10.1021/ic8000834
PDF
Synthesis, Structure, and Physical Properties for a Series of Monomeric Iron(III) Hydroxo Complexes with Varying Hydrogen-Bond Networks
Jhumpa Mukherjee, Robie L. Lucas, Matthew K. Zart, Douglas R. Powell, Victor W. Day, and A. S. Borovik
pp 5780 - 5786; DOI:
10.1021/ic800048e
PDF
Tetravalent Metal Complexation by Keggin and Lacunary Phosphomolybdate Anions
Roy Copping, Leif Jonasson, Andrew J. Gaunt, Dennis Drennan, David Collison, Madeleine Helliwell, Ross J. Pirttijarvi, Chris J. Jones, Anne Huguet, David C. Apperley, Nikolas Kaltsoyannis, and Iain May
pp 5787 - 5798; DOI:
10.1021/ic800101t
PDF
Early Transition Metal Complexes Bearing a C-Capped Tris(phenolate) Ligand Incorporating a Pendant Imine Arm: Synthesis, Structure, and Ethylene Polymerization Behavior
Damien Homden, Carl Redshaw, Joseph A. Wright, David L. Hughes, and Mark R. J. Elsegood
pp 5799 - 5814; DOI:
10.1021/ic702506w
PDF
4-Thiolatobenzoate-Bridged Gold/Zirconium Complex and Its Mononuclear Precursors
Ulrike Helmstedt, Sergei Lebedkin, Thomas Höcher, Steffen Blaurock, and E. Hey-Hawkins
pp 5815 - 5820; DOI:
10.1021/ic800203y
PDF
Novel Michael Addition Products of Bis(amino acidato)metal(II) Complexes: Synthesis, Characterization, Dye Degradation, and Oxidation Properties
V. Rajalakshmi, V. R. Vijayaraghavan, Babu Varghese, and A. Raghavan
pp 5821 - 5830; DOI:
10.1021/ic800086y
PDF
Sn12O8(OH)4(OEt)28(HOEt)4: an Additional Member in the Family of Dodecameric Oxo Clusters
F. Ribot, E. Martinez-Ferrero, K. Boubekeur, P. M. S. Hendrickx, J. C. Martins, L. Van Lokeren, R. Willem, and M. Biesemans
pp 5831 - 5840; DOI:
10.1021/ic800123z
PDF
Direct Comparison of the Magnetic and Electronic Properties of Samarocene and Ytterbocene Terpyridine Complexes
Jacqueline M. Veauthier, Eric J. Schelter, Christin N. Carlson, Brian L. Scott, Ryan E. Da Re, J. D. Thompson, Jaqueline L. Kiplinger, David E. Morris, and Kevin D. John
pp 5841 - 5849; DOI:
10.1021/ic8001465
PDF
Binding Nucleophiles to [Fe4Y4Cl4]2− (Y = S or Se) can Increase or Suppress the Rate of Proton Transfer to the Cluster
Katie Bates and Richard A. Henderson
pp 5850 - 5858; DOI:
10.1021/ic800142e
PDF
Electrochemical Synthesis of Zn−Al Layered Double Hydroxide (LDH) Films
Matthew S. Yarger, Ellen M. P. Steinmiller, and Kyoung-Shin Choi
pp 5859 - 5865; DOI:
10.1021/ic800193j
PDF
Synthesis of New Copper Cyanide complexes via the Transformation of Organonitrile to Inorganic Cyanide
Hong Deng, Yongcai Qiu, Carole Daiguebonne, Nicolas Kerbellec, Olivier Guillou, Matthias Zeller, and Stuart R. Batten
pp 5866 - 5872; DOI:
10.1021/ic800164b
PDF
Coordination Complexes Exhibiting Anion···π Interactions: Synthesis, Structure, and Theoretical Studies
Leoní A. Barrios, Guillem Aromí, Antonio Frontera, David Quiñonero, Pere M. Deyà, Patrick Gamez, Olivier Roubeau, Elizabeth J. Shotton, and Simon J. Teat
pp 5873 - 5881; DOI:
10.1021/ic800215r
PDF
Biomolecule-Assisted Synthesis of Water-Soluble Silver Nanoparticles and Their Biomedical Applications
Qingzhi Wu, Huaqiang Cao, Qiuying Luan, Jiyong Zhang, Zhao Wang, Jamie H. Warner, and Andrew A. R. Watt
pp 5882 - 5888; DOI:
10.1021/ic8002228
PDF
Role of the Electron Transfer and Magnetic Exchange Interactions in the Magnetic Properties of Mixed-Valence Polyoxovanadate Complexes
Carmen J. Calzado, Juan M. Clemente-Juan, Eugenio Coronado, Alejandro Gaita-Arino, and Nicolas Suaud
pp 5889 - 5901; DOI:
10.1021/ic8002355
PDF
Reactions of the Re(CO)3(H2O)3+ Synthon with Monodentate Ligands under Aqueous Conditions
Brenton R. Franklin, Richard S. Herrick, Christopher J. Ziegler, Anıl Çetin, Natalie Barone, and Laura R. Condon
pp 5902 - 5909; DOI:
10.1021/ic800363w
PDF
Computational Analysis of Amine−Borane Adducts as Potential Hydrogen Storage Materials with Reversible Hydrogen Uptake
Anne Staubitz, Maria Besora, Jeremy N. Harvey, and Ian Manners
pp 5910 - 5918; DOI:
10.1021/ic800344h
PDF
Mononuclear Manganese(III) Complexes as Building Blocks for the Design of Trinuclear Manganese Clusters: Study of the Ligand Influence on the Magnetic Properties of the [Mn33-O)]7+ Core
Marta Viciano-Chumillas, Stefania Tanase, Ilpo Mutikainen, Urho Turpeinen, L. Jos de Jongh, and Jan Reedijk
pp 5919 - 5929; DOI:
10.1021/ic8002492
PDF
Synthesis, Characterization, and Structural Studies of Mixed-Ligand Diorganotin Esters, [R2Sn(OP(O)(OH)Ph)(OS(O)2R1)]n [R = n-Bu, R1 = Me (1), n-Pr (2); R = Et, R1 = Me (3)] with 1D and 3D Coordination Polymeric Motifs
Ravi Shankar, Atul Pratap Singh, Archana Jain, Mary F. Mahon, and Kieran C. Molloy
pp 5930 - 5935; DOI:
10.1021/ic8002433
PDF
General Synthesis of (Salen)ruthenium(III) Complexes via N···N Coupling of (Salen)ruthenium(VI) Nitrides
Wai-Lun Man, Hoi-Ki Kwong, William W. Y. Lam, Jing Xiang, Tsz-Wing Wong, Wing-Hong Lam, Wing-Tak Wong, Shie-Ming Peng, and Tai-Chu Lau
pp 5936 - 5944; DOI:
10.1021/ic800263n
PDF
Cyanoscorpionates: Synthesis and Crystallographic Characterization of One-Dimensional Cu(I) Coordination Polymers
Ningfeng Zhao, John C. Bullinger, Michael J. Van Stipdonk, Charlotte L. Stern, and David M. Eichhorn
pp 5945 - 5950; DOI:
10.1021/ic8003307
PDF
Solid-State Molecular Rotators of Anilinium and Adamantylammonium in [Ni(dmit)2] Salts with Diverse Magnetic Properties
Tomoyuki Akutagawa, Daisuke Sato, Hiroyuki Koshinaka, Masaaki Aonuma, Shin-ichiro Noro, Sadamu Takeda, and Takayoshi Nakamura
pp 5951 - 5962; DOI:
10.1021/ic800271m
PDF
(α-Diimine)chromium Complexes: Molecular and Electronic Structures; A Combined Experimental and Density Functional Theoretical Study
Meenakshi Ghosh, Stephen Sproules, Thomas Weyhermüller, and Karl Wieghardt
pp 5963 - 5970; DOI:
10.1021/ic800290s
PDF
A Reactivity Change of a Strontium Monohydroxide by Umpolung to an Acid
Sankaranarayanapillai Sarish, Sharanappa Nembenna, Selvarajan Nagendran, Herbert W. Roesky, Aritra Pal, Regine Herbst-Irmer, Arne Ringe, and Jörg Magull
pp 5971 - 5977; DOI:
10.1021/ic800284u
PDF
Halide Addition/Abstraction in Phosphido Derivatives: Isolation of the Thallium and Silver Intermediates
Juan Forniés, Consuelo Fortuño, Susana Ibáñez, and Antonio Martín
pp 5978 - 5987; DOI:
10.1021/ic800294c
PDF
Homoleptic Cadmium and Mercury Compounds of Stanna-closo-dodecaborate
Marius Kirchmann, Klaus Eichele, and Lars Wesemann
pp 5988 - 5991; DOI:
10.1021/ic800357z
PDF
Synthesis and Characterization of Aluminum- and Gallium-Bridged [1.1]Chromarenophanes and [1.1]Molybdarenophanes
Clinton L. Lund, Jörg A. Schachner, Ian J. Burgess, J. Wilson Quail, Gabriele Schatte, and Jens Müller
pp 5992 - 6000; DOI:
10.1021/ic800336f
PDF
Structure of Fe/Co/Ni Hexacyanoferrate As Probed by Multiple Edge X-ray Absorption Spectroscopy
Marco Giorgetti and Mario Berrettoni
pp 6001 - 6008; DOI:
10.1021/ic800289c
PDF
Tin-Based Organo-Zintl Ions: Alkylation and Alkenylation of Sn94−
Donald J. Chapman and Slavi C. Sevov
pp 6009 - 6013; DOI:
10.1021/ic800383c
PDF
Simple, Nitrogen-Rich, Energetic Salts of 5-Nitrotetrazole
Thomas M. Klapötke, Peter Mayer, Carles Miró Sabaté, Jan M. Welch, and Nikolai Wiegand
pp 6014 - 6027; DOI:
10.1021/ic800353y
PDF
Cooperative Binding of Phosphate Anion and a Neutral Nitrogen Donor to Alkaline-Earth Metal Ions. Investigation of Group 2 Metal−Organophosphate Interaction in the Absence and Presence of 1,10-Phenanthroline
Ramaswamy Murugavel, Subramaniam Kuppuswamy, and Sören Randoll
pp 6028 - 6039; DOI:
10.1021/ic8003239
PDF
Anionic Roussin’s Red Esters (RREs) syn-/anti-[Fe(µ-SEt)(NO)2]2: the Critical Role of Thiolate Ligands in Regulating the Transformation of RREs into Dinitrosyl Iron Complexes and the Anionic RREs
Tsai-Te Lu, Chih-Chin Tsou, Hsiao-Wen Huang, I-Jui Hsu, Jin-Ming Chen, Ting-Shen Kuo, Yu Wang, and Wen-Feng Liaw
pp 6040 - 6050; DOI:
10.1021/ic800360m
PDF
Crystal Structure and Chemical Bonding of Mg3Ru2
Rainer Pöttgen, Viktor Hlukhyy, Aleksey Baranov, and Yuri Grin
pp 6051 - 6055; DOI:
10.1021/ic800387a
PDF
Structural and Electronic Properties of the [FeFe] Hydrogenase H-Cluster in Different Redox and Protonation States. A DFT Investigation
Maurizio Bruschi, Claudio Greco, Piercarlo Fantucci, and Luca De Gioia
pp 6056 - 6071; DOI:
10.1021/ic8006298
PDF
New Layered Hydrogenophosphate, Protonic Conductor: Mn(H2PO4)2
R. Baies, V. Pralong, V. Caignaert, M. P. Saradhi, U. V. Varadaraju, and B. Raveau
pp 6072 - 6076; DOI:
10.1021/ic8004163
PDF
Quinine and Chloroquine Differentially Perturb Heme Monomer−Dimer Equilibrium
Leah B. Casabianca, David An, Jayakumar K. Natarajan, John N. Alumasa, Paul D. Roepe, Christian Wolf, and Angel C. de Dios
pp 6077 - 6081; DOI:
10.1021/ic800440d
PDF
Liquid Azide Salts and Their Reactions with Common Oxidizers IRFNA and N2O4
Stefan Schneider, Tommy Hawkins, Michael Rosander, Jeffrey Mills, Ghanshyam Vaghjiani, and Steven Chambreau
pp 6082 - 6089; DOI:
10.1021/ic8004739
PDF
Synthesis, Structural Characterization, and Ligand Replacement Reactions of gem-Dithiolato-Bridged Rhodium and Iridium Complexes
Angel B. Rivas, José M. Gascón, Fernando J. Lahoz, Ana I. Balana, Alvaro J. Pardey, Luis A. Oro, and Jesús J. Pérez-Torrente
pp 6090 - 6104; DOI:
10.1021/ic800464p
PDF

Issue 14


Cyanide-Bridged Iron(II,III) Cube with Multistepped Redox Behavior
Masayuki Nihei, Mayumi Ui, Norihisa Hoshino, and Hiroki Oshio
pp 6106 - 6108; DOI:
10.1021/ic7024582
PDF
Aryl-Bridged 1-Hydroxypyridin-2-one: Sensitizer Ligands for Eu(III)
Anthony D’Aléo, Jide Xu, Evan G. Moore, Christoph J. Jocher, and Kenneth N. Raymond
pp 6109 - 6111; DOI:
10.1021/ic8003189
PDF
Spanning Pairs of Rh2(acetate)4 Units with Ru(II) Complexes
Michael W. Cooke, Marie-Pierre Santoni, Garry S. Hanan, Frédérique Loiseau, Anna Proust, and Bernold Hasenknopf
pp 6112 - 6114; DOI:
10.1021/ic8003678
PDF
Supramolecular Engineering of a 2D Kagomé Lattice: Synthesis, Structures, and Magnetic Properties
Yan-Feng Yue, Jue Liang, En-Qing Gao, Chen-Jie Fang, Zheng-Guang Yan, and Chun-Hua Yan
pp 6115 - 6117; DOI:
10.1021/ic800497n
PDF
Synthesis and Characterization of the 4,4′-Bipyridyl Dianion and Radical Monoanion. A Structural Study
Mark S. Denning, Mark Irwin, and Jose M. Goicoechea
pp 6118 - 6120; DOI:
10.1021/ic800726p
PDF
Oxidative C-H and C-C Bond Cleavage by a (2,2′-Bipyridine)Copper(I) Chloride Complex
Róbert Csonka, József Kaizer, Michel Giorgi, Marius Réglier, László Hajba, János Mink, and Gábor Speier
pp 6121 - 6123; DOI:
10.1021/ic800745g
PDF
Preparation and Reactivity of a Monomeric Octahedral Platinum(IV) Amido Complex
Colleen Munro-Leighton, Yuee Feng, Jubo Zhang, Nikki M. Alsop, T. Brent Gunnoe, Paul D. Boyle, and Jeffrey L. Petersen
pp 6124 - 6126; DOI:
10.1021/ic800843b
PDF
Structural and Physical Characterization of Tetranuclear [MnII3MnIV] and [MnII2MnIII2] Valence-Isomer Manganese Complexes
Curtis M. Zaleski, Tsu-Chen Weng, Catherine Dendrinou-Samara, Maria Alexiou, Paraskevi Kanakaraki, Wen-Yuan Hsieh, Jeff Kampf, James E. Penner-Hahn, Vincent L. Pecoraro, and Dimitris P. Kessissoglou
pp 6127 - 6136; DOI:
10.1021/ic702109c
PDF
Can Undoped Calcium Tetraborides Exist? An Answer from the Comparison of Its Density Functional Theory Electronic Structure with that of Rare-Earth Metal Tetraboride
Mouna Ben Yahia, Olaf Reckeweg, Régis Gautier, Joseph Bauer, Thomas Schleid, Jean-François Halet, and Jean-Yves Saillard
pp 6137 - 6143; DOI:
10.1021/ic701967n
PDF
Synthesis and Study of the Spectroscopic and Redox Properties of RuII,PtII Mixed-Metal Complexes Bridged by 2,3,5,6-Tetrakis(2-pyridyl)pyrazine
Shengliang Zhao, Shamindri M. Arachchige, Carla Slebodnick, and Karen J. Brewer
pp 6144 - 6152; DOI:
10.1021/ic7023296
PDF
Predicting How Polyphenol Antioxidants Prevent DNA Damage by Binding to Iron
Nathan R. Perron, James N. Hodges, Michael Jenkins, and Julia L. Brumaghim
pp 6153 - 6161; DOI:
10.1021/ic7022727
PDF
Ligand-Bound S = 1/2 FeMo-Cofactor of Nitrogenase: Hyperfine Interaction Analysis and Implication for the Central Ligand X Identity
Vladimir Pelmenschikov, David A. Case, and Louis Noodleman
pp 6162 - 6172; DOI:
10.1021/ic7022743
PDF
Anion Detection by Fluorescent Zn(II) Complexes of Functionalized Polyamine Ligands
Laura Rodríguez, João C. Lima, A. Jorge Parola, Fernando Pina, Robert Meitz, Ricardo Aucejo, Enrique Garcia-España, José M. Llinares, Conxa Soriano, and Javier Alarcón
pp 6173 - 6183; DOI:
10.1021/ic7023956
PDF
Coordination Polymers from the Self-Assembly of Silver(I) Salts and Two Nonlinear Aliphatic Dinitrile Ligands, cis-1,3-Cyclopentanedicarbonitrile and cis-1,3-Bis(cyanomethyl)cyclopentane: Synthesis, Structures, and Photoluminescent Properties
Emerson D. Genuis, Joel A. Kelly, Malay Patel, Robert McDonald, Michael J. Ferguson, and Grace Greidanus-Strom
pp 6184 - 6194; DOI:
10.1021/ic800069f
PDF
Internally Consistent Ion Volumes and Their Application in Volume-Based Thermodynamics
Leslie Glasser and H. Donald Brooke Jenkins
pp 6195 - 6202; DOI:
10.1021/ic702399u
PDF
Quenching Mechanism of Zn(Salicylaldimine) by Nitroaromatics
Meaghan E. Germain, Thomas R. Vargo, Beth Anne McClure, Jeffrey J. Rack, P. Gregory Van Patten, Michael Odoi, and Michael J. Knapp
pp 6203 - 6211; DOI:
10.1021/ic702469q
PDF
Unusual Concerted Lewis Acid−Lewis Base Mechanism for Hydrogen Activation by a Phosphine−Borane Compound
Yong Guo and Shuhua Li
pp 6212 - 6219; DOI:
10.1021/ic702489s
PDF
Valence Electronic Structure of Benzo-2,1,3-chalcogenadiazoles Studied by Photoelectron Spectroscopy and Density Functional Theory
Anthony F. Cozzolino, Nadine E. Gruhn, Dennis L. Lichtenberger, and Ignacio Vargas-Baca
pp 6220 - 6226; DOI:
10.1021/ic800055c
PDF
Synthesis of Two New Linear Trinuclear CuII Complexes: Mechanism of Magnetic Coupling through Hybrid B3LYP Functional and CShM Studies
Santarupa Thakurta, Joy Chakraborty, Georgina Rosair, Javier Tercero, M. Salah El Fallah, Eugenio Garribba, and Samiran Mitra
pp 6227 - 6235; DOI:
10.1021/ic8001459
PDF
Fluorescent Boron Bis(phenolate) with Association Response to Chloride and Dissociation Response to Fluoride
Ewan Galbraith, Thomas M. Fyles, Frank Marken, Matthew G. Davidson, and Tony D. James
pp 6236 - 6244; DOI:
10.1021/ic800204q
PDF
Wheel-Shaped Mn16 Single-Molecule Magnets
Sonali J. Shah, Christopher M. Ramsey, Katie J. Heroux, James R. O’Brien, Antonio G. DiPasquale, Arnold L. Rheingold, Enrique del Barco, and David N. Hendrickson
pp 6245 - 6253; DOI:
10.1021/ic800277j
PDF
Heteroleptic Copper(I) Complexes Coupled with Methano[60]fullerene: Synthesis, Electrochemistry, and Photophysics
Andrea Listorti, Gianluca Accorsi, Yannick Rio, Nicola Armaroli, Omar Moudam, Aline Gégout, Béatrice Delavaux-Nicot, Michel Holler, and Jean-François Nierengarten
pp 6254 - 6261; DOI:
10.1021/ic800315e
PDF
Synthesis, Structural Characterization, and Antiinflammatory Activity of Triethylphosphinegold(I) Sulfanylpropenoates of the Type [(AuPEt3)2xspa] [H2xspa = 3-(Aryl)-2-sulfanylpropenoic acid]: an (H2O)6 Cluster in the Lattice of the Complexes [(AuPEt3)2xspa]·3H2O
Elena Barreiro, José S. Casas, María D. Couce, Ángeles Gato, Agustín Sánchez, José Sordo, José M. Varela, and Ezequiel M. Vázquez López
pp 6262 - 6272; DOI:
10.1021/ic800314p
PDF
Albumin-Mediated Selenium Transfer by a Selenotrisulfide Relay Mechanism
Mamoru Haratake, Masafumi Hongoh, Mihoko Miyauchi, Ritsuko Hirakawa, Masahiro Ono, and Morio Nakayama
pp 6273 - 6280; DOI:
10.1021/ic800310j
PDF
Preparation and Crystal Structures of Bismuth Technetates: A New Metal Oxide System
Efrain E. Rodriguez, Frédéric Poineau, Anna Llobet, Ken Czerwinski, Ram Seshadri, and Anthony K. Cheetham
pp 6281 - 6288; DOI:
10.1021/ic8003273
PDF
Ligand Effects on Luminescence of New Type Blue Light-Emitting Mono(2-phenylpyridinato)iridium(III) Complexes
Min-Sik Eum, Chong Shik Chin, Song yi Kim, Choongil Kim, Sung Kwon Kang, Nam Hwi Hur, Ji Hoon Seo, Gu Young Kim, and Young Kwan Kim
pp 6289 - 6295; DOI:
10.1021/ic800376e
PDF
High-Pressure Synthesis, Crystal and Electronic Structures, and Transport Properties of a Novel Perovskite HgSnO3
Masashi Yoshida, Tetsuhiro Katsumata, and Yoshiyuki Inaguma
pp 6296 - 6302; DOI:
10.1021/ic800370r
PDF
Hydrogen Absorption in Transition Metal Silicides: La3Pd5Si-Hydrogen System
Yaroslav O. Tokaychuk, Yaroslav E. Filinchuk, Denis V. Sheptyakov, and Klaus Yvon
pp 6303 - 6313; DOI:
10.1021/ic800382x
PDF
Influence of Fluoride on the Reversible Binding of NO by [FeII(EDTA)(H2O)]2−. Inhibition of Autoxidation of [FeII(EDTA)(H2O)]2−
Joachim Maigut, Roland Meier, and Rudi van Eldik
pp 6314 - 6321; DOI:
10.1021/ic800378c
PDF
2D Copper(II) Complex Built from N-Methyl-1,3-diamino-2-propanolate and Azide Ligands: Structure, Magnetic, and DFT Studies
M. Salah El Fallah, Ramon Vicente, Javier Tercero, Christian Elpelt, Eva Rentschler, Xavier Solans, and Mercè Font-Bardia
pp 6322 - 6328; DOI:
10.1021/ic8004807
PDF
Novel Luminescent Metal-Organic Frameworks [Eu2L3(DMSO)2(MeOH)2]·2DMSO·3H2O and [Zn2L2(DMSO)2]·1.6H2O (L = 4,4′-Ethyne-1,2-diyldibenzoate)
Bich Tram Nguyen Pham, Liisa M. Lund, and Datong Song
pp 6329 - 6335; DOI:
10.1021/ic800394g
PDF
Chemical and Biological Profiles of Novel Copper(II) Complexes Containing S-Donor Ligands for the Treatment of Cancer
Lorena Giovagnini, Sergio Sitran, Monica Montopoli, Laura Caparrotta, Maddalena Corsini, Claudia Rosani, Piero Zanello, Q. Ping Dou, and Dolores Fregona
pp 6336 - 6343; DOI:
10.1021/ic800404e
PDF
A New Route to Obtain High-Yield Multiple-Shaped Gold Nanoparticles in Aqueous Solution using Microwave Irradiation
Subrata Kundu, Luohan Peng, and Hong Liang
pp 6344 - 6352; DOI:
10.1021/ic8004135
PDF
Structural and Spectroscopic Impact of Tuning the Stereochemical Activity of the Lone Pair in Lead(II) Cyanoaurate Coordination Polymers via Ancillary Ligands
Michael J. Katz, Vladimir K. Michaelis, Pedro M. Aguiar, Renante Yson, Haiyan Lu, Harini Kaluarachchi, Raymond J. Batchelor, Georg Schreckenbach, Scott Kroeker, Howard H. Patterson, and Daniel B. Leznoff
pp 6353 - 6363; DOI:
10.1021/ic800425f
PDF
Phosphorus Complexes of N-Fused Porphyrin and Its Reduced Derivatives: New Isomers of Porphyrin Stabilized via Coordination
Anna Młodzianowska, Lechosław Latos-Grażyński, and Ludmiła Szterenberg
pp 6364 - 6374; DOI:
10.1021/ic800437y
PDF
Coordination Cages of Rhodium and Iridium as Exoreceptors for Alkali Metal Ions
Sebastian Mirtschin, Elvira Krasniqi, Rosario Scopelliti, and Kay Severin
pp 6375 - 6381; DOI:
10.1021/ic800410x
PDF
Electronic Control of the “Bailar Twist” in Formally d0-d2 Molybdenum Tris(dithiolene) Complexes: A Sulfur K-edge X-ray Absorption Spectroscopy and Density Functional Theory Study
Adam L. Tenderholt, Robert K. Szilagyi, Richard H. Holm, Keith O. Hodgson, Britt Hedman, and Edward I. Solomon
pp 6382 - 6392; DOI:
10.1021/ic800494h
PDF
Mechanism of Single Metal Exchange in the Reactions of [M4(SPh)10]2− (M = Zn or Fe) with CoX2 (X = Cl or NO3) or FeCl2
Valerie Autissier and Richard A. Henderson
pp 6393 - 6403; DOI:
10.1021/ic800485t
PDF
Palladium(II) Complexes of Unsymmetrical CNN Pincer Ligands
Martin Bröring, Christian Kleeberg, and Silke Köhler
pp 6404 - 6412; DOI:
10.1021/ic800507k
PDF
New Polydentate Ligand and Catalytic Properties of the Corresponding Ruthenium Complex During Sulfoxidation and Alkene Epoxidation
Olivier Hamelin, Stéphane Ménage, Florence Charnay, Murielle Chavarot, Jean-Louis Pierre, Jacques Pécaut, and Marc Fontecave
pp 6413 - 6420; DOI:
10.1021/ic800534v
PDF
Molecular Structures of Thimerosal (Merthiolate) and Other Arylthiolate Mercury Alkyl Compounds
Jonathan G. Melnick, Kevin Yurkerwich, Daniela Buccella, Wesley Sattler, and Gerard Parkin
pp 6421 - 6426; DOI:
10.1021/ic8005426
PDF
Role of Electronic Structure on DNA Light-Switch Behavior of Ru(II) Intercalators
Yujie Sun, Daniel A. Lutterman, and Claudia Turro
pp 6427 - 6434; DOI:
10.1021/ic800560x
PDF
On the Quest for New Mixed-Metal μ-Oxo-bridged Complexes: Synthesis of Compounds Containing Transition Metal−Oxygen−Main Group Metal Motifs M−O−M1 (M = Ti, Zr; M1 = Al, Ga) without Cyclopentadienyl Ligands
Grigory B. Nikiforov, Herbert W. Roesky, Thomas Schulz, Dietmar Stalke, and M. Witt
pp 6435 - 6443; DOI:
10.1021/ic800567g
PDF
Di- and Triheteronuclear Cu−Gd and Cu−Gd−Cu Complexes with Dissymmetric Double Bridge
Fatima Zohra Chiboub Fellah, Jean-Pierre Costes, Françoise Dahan, Carine Duhayon, Ghenadie Novitchi, Jean-Pierre Tuchagues, and Laure Vendier
pp 6444 - 6451; DOI:
10.1021/ic800599r
PDF
Binding of Ru(bpy)2(eilatin)2+ to Matched and Mismatched DNA
Brian M. Zeglis and Jacqueline K. Barton
pp 6452 - 6457; DOI:
10.1021/ic8006537
PDF
Synthesis, Structure, and Magnetic Properties of [(S)-[PhCH(CH3)N(CH3)3]][Mn(CH3CN)2/3Cr(ox)3]·(CH3CN)_(solvate), a 2D Chiral Magnet Containing a Quaternary Ammonium Chiral Cation
Miguel Clemente-León, Eugenio Coronado, Joao C. Dias, Alejandra Soriano-Portillo, and Roger D. Willett
pp 6458 - 6463; DOI:
10.1021/ic800597w
PDF
Oligo- and Polymeric PdII and PtII Using Pyridyl Carboxylate Spacers for Topology Control
Peili Teo, L. L. Koh, and T. S. Andy Hor
pp 6464 - 6474; DOI:
10.1021/ic8007238
PDF
Ahead of the Lanthanide Contraction; Pressure and Ionic Size in the Synthesis of MSr2RECu2O8 (RE = Rare Earth, M = Ru, Cr, Ir): a Gaussian Relation
M. Á. Alario-Franco, R. Ruiz-Bustos, and A. J. Dos Santos-García
pp 6475 - 6481; DOI:
10.1021/ic7020676
PDF
Synthesis of (1-Adamantylimido)vanadium(V) Complexes Containing Aryloxo, Ketimide Ligands: Effect of Ligand Substituents in Olefin Insertion/Metathesis Polymerization
Wenjuan Zhang and Kotohiro Nomura
pp 6482 - 6492; DOI:
10.1021/ic800347n
PDF
Magnetic and Dielectric Properties of InFe2O4, InFeCuO4, and InGaCuO4
Kenji Yoshii, Naoshi Ikeda, Yuka Okajima, Yasuhiro Yoneda, Yoji Matsuo, Yoichi Horibe, and Shigeo Mori
pp 6493 - 6501; DOI:
10.1021/ic702365k
PDF
Synthesis, Structure, and Reactivity of Rhodium and Iridium Complexes of the Chelating Bis-Sulfoxide tBuSOC2H4SOtBu. Selective O−H Activation of 2-Hydroxy-isopropyl-pyridine
Thomas Schaub, Yael Diskin-Posner, Udo Radius, and David Milstein
pp 6502 - 6512; DOI:
10.1021/ic800354q
PDF
Synthesis and Reactivity of the Aquation Product of the Antitumor Complex trans-[RuIIICl4(indazole)2]
Berta Cebrián-Losantos, Erwin Reisner, Christian R. Kowol, Alexander Roller, Sergiu Shova, Vladimir B. Arion, and Bernhard K. Keppler
pp 6513 - 6523; DOI:
10.1021/ic800506g
PDF
Mixed-Valent Diruthenium Half-Sandwich Complexes Containing Two Chelating 1,2-Dicarba-closo-dodecaborane-1,2-dithiolate Ligands: Reactivity towards Phenylacetylene, 1,4-Diethynylbenzene, and Ethynylferrocene
Dehong Wu, Yuguang Li, Lei Han, Yizhi Li, and Hong Yan
pp 6524 - 6531; DOI:
10.1021/ic800619z
PDF
Ruthenium Tris(bipyridine) Complexes with Sulfur Substituents: Model Studies for PEG Coupling
Gina L. Fiore, Brenda N. Goguen, Jessica L. Klinkenberg, Sarah J. Payne, J. N. Demas, and Cassandra L. Fraser
pp 6532 - 6540; DOI:
10.1021/ic800262d
PDF
Spectroscopic Characterization of Molybdenum Dinitrogen Complexes Containing a Combination of Di- and Triphosphine Coligands: 31P NMR Analysis of Five-Spin Systems
Kristina Klatt, Gerald Stephan, Gerhard Peters, and Felix Tuczek
pp 6541 - 6550; DOI:
10.1021/ic800389g
PDF
New Bis-Cresol-Bridged bis(1,4,7-Triazacyclononane) Ligand As Receptor for Metal Cations and Phosphate Anions
Enrico Arturoni, Carla Bazzicalupi, Andrea Bencini, Claudia Caltagirone, Andrea Danesi, Alessandra Garau, Claudia Giorgi, Vito Lippolis, and Barbara Valtancoli
pp 6551 - 6563; DOI:
10.1021/ic800549e
PDF
Self-Encapsulation of [MII(phen)2(H2O)2]2+ (M = Co, Zn) in One-Dimensional Nanochannels of [MII(H2O)6(BTC)2]4− (M = Co, Cu, Mn): A High HQ/CAT Ratio Catalyst for Hydroxylation of Phenols
Jianhong Bi, Lingtao Kong, Zixiang Huang, and Jinhuai Liu
pp 6564 - 6564; DOI:
10.1021/ic801065a
PDF

Issue 15


A Novel Solution-Processible Heterodinuclear AlIII/IrIII Complex for Host−Dopant Assembly OLEDs
Jung Oh Huh, Min Hyung Lee, Hyosook Jang, Kyu Young Hwang, Jong Soon Lee, Se Hun Kim, and Youngkyu Do
pp 6566 - 6568; DOI:
10.1021/ic8002806
PDF
Heme Peroxidase-Catalyzed Iodination of Human Angiotensins and the Effect of Iodination on Angiotensin Converting Enzyme Activity
Bhaskar J. Bhuyan and Govindasamy Mugesh
pp 6569 - 6571; DOI:
10.1021/ic800395k
PDF
Dinuclear Copper(II) Complexes of a Polybenzimidazole Ligand: Their Structures and Inductive Roles in DNA Condensation
Xianggao Meng, Liang Liu, Chunshan Zhou, Li Wang, and Changlin Liu
pp 6572 - 6574; DOI:
10.1021/ic800532q
PDF
Sublimation Not an Innocent Technique: A Case of Bis-Cyclometalated Iridium Emitter for OLED
Etienne Baranoff, Stéphane Suàrez, Philippe Bugnon, Claudia Barolo, Roberto Buscaino, Rosario Scopelliti, Libero Zuppiroli, Michael Graetzel, and Md. K. Nazeeruddin
pp 6575 - 6577; DOI:
10.1021/ic800747t
PDF
Temperature- and Stoichiometry-Controlled Dimensionality in a Magnesium 4,5-Imidazoledicarboxylate System with Strong Hydrophilic Pore Surfaces
K. L. Gurunatha, Kazuhiro Uemura, and Tapas Kumar Maji
pp 6578 - 6580; DOI:
10.1021/ic8007377
PDF
Pentanuclear Dysprosium Hydroxy Cluster Showing Single-Molecule-Magnet Behavior
Michael T. Gamer, Yanhua Lan, Peter W. Roesky, Annie K. Powell, and Rodolphe Clérac
pp 6581 - 6583; DOI:
10.1021/ic8008255
PDF
Spin-Crossover Coordination Nanoparticles
Florence Volatron, Laure Catala, Eric Rivière, Alexandre Gloter, Odile Stéphan, and Talal Mallah
pp 6584 - 6586; DOI:
10.1021/ic800803w
PDF
Template Syntheses of Iron(II) Complexes Containing Chiral P−N−N−P and P−N−N Ligands
Alexandre A. Mikhailine, Eunice Kim, Carsten Dingels, Alan J. Lough, and Robert H. Morris
pp 6587 - 6589; DOI:
10.1021/ic800884c
PDF
A 2D Coordination Polymer with Canted Ferromagnetism Constructed from Ferromagnetic [NiIICoII] Nodes
Diana G. Branzea, Lorenzo Sorace, Catalin Maxim, Marius Andruh, and Andrea Caneschi
pp 6590 - 6592; DOI:
10.1021/ic800946v
PDF
Spin Maximization: Switching of the Usual S = 11 State of MnII4MnIII3 Disklike Complexes to the Maximum S = 16
Theocharis C. Stamatatos, Katye M. Poole, Dolos Foguet-Albiol, Khalil A. Abboud, Ted A. O’Brien, and George Christou
pp 6593 - 6595; DOI:
10.1021/ic801024d
PDF
A New Class of Iridium Complexes Suitable for Stepwise Incorporation into Linear Assemblies: Synthesis, Electrochemistry, and Luminescence
Victoria L. Whittle and J. A. Gareth Williams
pp 6596 - 6607; DOI:
10.1021/ic701788d
PDF
Density Functional Theory Studies of Spin, Charge, and Orbital Ordering in YBaT2O5 (T = Mn, Fe, Co)
R. Vidya, P. Ravindran, K. Knizek, A. Kjekshus, and H. Fjellvåg
pp 6608 - 6620; DOI:
10.1021/ic702025c
PDF
Comparison of Mass Spectrometry and Other Techniques for Probing Interactions Between Metal Complexes and DNA
Thitima Urathamakul, Daniel J. Waller, Jennifer L. Beck, Janice R. Aldrich-Wright, and Stephen F. Ralph
pp 6621 - 6632; DOI:
10.1021/ic702179a
PDF
Electron Paramagnetic Resonance and Density-Functional Theory Studies of Cu(II)-bis(oxamato) Complexes
Björn Bräuer, Florian Weigend, Maria Fittipaldi, Dante Gatteschi, Edward J. Reijerse, Annalisa Guerri, Samuele Ciattini, Georgeta Salvan, and Tobias Rüffer
pp 6633 - 6644; DOI:
10.1021/ic702460t
PDF
Novel Iron(III) Complexes of Sterically Hindered 4N Ligands: Regioselectivity in Biomimetic Extradiol Cleavage of Catechols
Ramasamy Mayilmurugan, Helen Stoeckli-Evans, and Mallayan Palaniandavar
pp 6645 - 6658; DOI:
10.1021/ic702410d
PDF
Medium and Interfacial Effects in the Multistep Reduction of Binuclear Complexes with Robson-Type Ligand
Renat R. Nazmutdinov, Nataliya V. Roznyatovskaya, Dmitrii V. Glukhov, Ibragim Manyurov, Vladimir M. Mazin, Galina A. Tsirlina, and Michael Probst
pp 6659 - 6673; DOI:
10.1021/ic702511w
PDF
Reduction of Pertechnetate by Acetohydroxamic Acid: Formation of [TcII(NO)(AHA)2(H2O)]+ and Implications for the UREX Process
Cynthia-May S. Gong, Wayne W. Lukens, Frederic Poineau, and Kenneth R. Czerwinski
pp 6674 - 6680; DOI:
10.1021/ic8000202
PDF
Probing the mer- to fac-Isomerization of Tris-Cyclometallated Homo- and Heteroleptic (C,N)3 Iridium(III) Complexes
Aidan R. McDonald, Martin Lutz, Lars S. von Chrzanowski, Gerard P. M. van Klink, Anthony L. Spek, and Gerard van Koten
pp 6681 - 6691; DOI:
10.1021/ic800169n
PDF
Synthesis and Structures of Selected Triazapentadienate of Li, Mn, Fe, Co, Ni, Cu(I), and Cu(II) using 2,4-N,N′-Disubstituted 1,3,5-Triazapentadienate Anions as Ancillary Ligands: [N(Ar)C(NMe2)NC(NMe2)N(R)] (Ar = Ph, 2,6-iPr2−C6H3; R = H, SiMe3)
Meisu Zhou, Yanping Song, Tao Gong, Hongbo Tong, Jianping Guo, Linhong Weng, and Diansheng Liu
pp 6692 - 6700; DOI:
10.1021/ic800320e
PDF
Integrated Paramagnetic Resonance of High-Spin Co(II) in Axial Symmetry: Chemical Separation of Dipolar and Contact Electron−Nuclear Couplings
William K. Myers, Eileen N. Duesler, and David L. Tierney
pp 6701 - 6710; DOI:
10.1021/ic800245k
PDF
General Molecular Mechanics Method for Transition Metal Carboxylates and its Application to the Multiple Coordination Modes in Mono- and Dinuclear Mn(II) Complexes
Robert J. Deeth
pp 6711 - 6725; DOI:
10.1021/ic800313s
PDF
Clarification of the Oxidation State of Cobalt Corroles in Heterogeneous and Homogeneous Catalytic Reduction of Dioxygen
Karl M. Kadish, Jing Shen, Laurent Frémond, Ping Chen, Maya El Ojaimi, Mohammed Chkounda, Claude P. Gros, Jean-Michel Barbe, Kei Ohkubo, Shunichi Fukuzumi, and Roger Guilard
pp 6726 - 6737; DOI:
10.1021/ic800458s
PDF
Aminoethylglycine-Functionalized Ru(bpy)32+ with Pendant Bipyridines Self-Assemble Multimetallic Complexes by Copper and Zinc Coordination
Carl P. Myers, Brian P. Gilmartin, and Mary Elizabeth Williams
pp 6738 - 6747; DOI:
10.1021/ic800285s
PDF
Syntheses, Structures, and Electrochemical Properties of Inclusion Compounds of Cucurbit[8]uril with Cobalt(III) and Nickel(II) Complexes
Tatiana V. Mitkina, Nina F. Zakharchuk, Dmitry Y. Naumov, Olga A. Gerasko, Dieter Fenske, and Vladimir P. Fedin
pp 6748 - 6755; DOI:
10.1021/ic8003036
PDF
High-Pressure Anisotropic Distortion of Pb3Bi2S6: a Pressure-Induced, Reversible Phase Transition with Migration of Chemical Bonds
Lars A. Olsen, Tonči Balić-Žunić, and Emil Makovicky
pp 6756 - 6762; DOI:
10.1021/ic800380p
PDF
Ternary Rare-Earth Titanium Antimonides RE2Ti11 − xSb14 + x (RE = Sm, Gd, Tb, Yb)
Haiying Bie and Arthur Mar
pp 6763 - 6770; DOI:
10.1021/ic800317c
PDF
Kinetics and Mechanisms of the Oxidation of Iodide and Bromide in Aqueous Solutions by a trans-Dioxoruthenium(VI) Complex
William W. Y. Lam, Wai-Lun Man, Yi-Ning Wang, and Tai-Chu Lau
pp 6771 - 6778; DOI:
10.1021/ic8003849
PDF
Unsaturated Binuclear Cyclopentadienylrhenium Carbonyl Derivatives: Metal−Metal Multiple Bonds and Agostic Hydrogen Atoms
Bing Xu, Qian-shu Li, Yaoming Xie, R. Bruce King, and Henry F. Schaefer III
pp 6779 - 6790; DOI:
10.1021/ic800403p
PDF
Two-Dimensional Hybrid Germanium Zeotype Formed by Selective Coordination of the trans-1,2-Diaminocyclohexane Isomer to the Ge Atom: Heterogeneous Acid−Base Bifunctional Catalyst
Felipe Gándara, Manuela E. Medina, Natalia Snejko, Berta Gómez-Lor, Marta Iglesias, Enrique Gutiérrez-Puebla, and M. Angeles Monge
pp 6791 - 6795; DOI:
10.1021/ic8004097
PDF
Photophysics of the Platinum(II) Terpyridyl Terpyridylacetylide Platform and the Influence of FeII and ZnII Coordination
Maria L. Muro, Stéphane Diring, Xianghuai Wang, Raymond Ziessel, and Felix N. Castellano
pp 6796 - 6803; DOI:
10.1021/ic800316x
PDF
Molecular and Electronic Structures of Mononuclear Iron Complexes Using Strongly Electron-Donating Ligands and their Oxidized Forms
Julia B. H. Strautmann, Serena DeBeer George, Eberhard Bothe, Eckhard Bill, Thomas Weyhermüller, Anja Stammler, Hartmut Bögge, and Thorsten Glaser
pp 6804 - 6824; DOI:
10.1021/ic800335t
PDF
Robust Metal−Organic Framework Enforced by Triple-Framework Interpenetration Exhibiting High H2 Storage Density
Ming Xue, Shengqian Ma, Zhao Jin, Roxanna M. Schaffino, Guang-Shan Zhu, Emil B. Lobkovsky, Shi-Lun Qiu, and Banglin Chen
pp 6825 - 6828; DOI:
10.1021/ic800854y
PDF
Oxalate-Based Soluble 2D Magnets: The Series [K(18-crown-6)]3[MII3(H2O)4{MIII(ox)3}3] (MIII = Cr, Fe; MII = Mn, Fe, Ni, Co, Cu; ox = C2O42−; 18-crown-6 = C12H24O6)
Eugenio Coronado, José R. Galán-Mascarós, Carlos Martí-Gastaldo, João C. Waerenborgh, and Piotr Gaczyński
pp 6829 - 6839; DOI:
10.1021/ic800418k
PDF
A Series of Bis(phosphinic)diamido Yttrium Complexes As Initiators for Lactide Polymerization
Rachel H. Platel, Andrew J. P. White, and Charlotte K. Williams
pp 6840 - 6849; DOI:
10.1021/ic800419t
PDF
Sterically Congested Uranyl Complexes with Seven-Coordination of the UO2 Unit: the Peculiar Ligation Mode of Nitrate in [UO2(NO3)2(Rbtp)] Complexes
Jean-Claude Berthet, Pierre Thuéry, Jean-Pierre Dognon, Denis Guillaneux, and Michel Ephritikhine
pp 6850 - 6862; DOI:
10.1021/ic8004486
PDF
Extended Structure Design with Simple Molybdenum Oxide Building Blocks and Urea As a Directing Agent
Sandra J. Veen, Soumyajit Roy, Yaroslav Filinchuk, Dmitry Chernyshov, Andrei V. Petukhov, Marjan Versluijs-Helder, Alfred Broersma, Fouad Soulimani, Tom Visser, and Willem K. Kegel
pp 6863 - 6866; DOI:
10.1021/ic800444m
PDF
Investigation of the Copper Binding Site and the Role of Histidine as a Ligand in Riboflavin Binding Protein
Sheila R. Smith, Krisztina Z. Bencze, Kristen A. Russ, Kristen Wasiukanis, Marilee Benore-Parsons, and Timothy L. Stemmler
pp 6867 - 6872; DOI:
10.1021/ic800431b
PDF
Syntheses, Structures, Physical Properties, and Electronic Properties of Some AMUQ3 Compounds (A = Alkali Metal, M = Cu or Ag, Q = S or Se)
Jiyong Yao, Daniel M. Wells, George H. Chan, Hui-Yi Zeng, Donald E. Ellis, Richard P. Van Duyne, and James A. Ibers
pp 6873 - 6879; DOI:
10.1021/ic800424t
PDF
Substituted β-Cyclodextrin and Calix[4]arene As Encapsulatory Vehicles for Platinum(II)-Based DNA Intercalators
Anwen M. Krause-Heuer, Nial J. Wheate, Michael J. Tilby, D. Graham Pearson, Christopher J. Ottley, and Janice R. Aldrich-Wright
pp 6880 - 6888; DOI:
10.1021/ic800467c
PDF
Europium(III) Reduction and Speciation within a Wells−Dawson Heteropolytungstate
Jing Jing, Benjamin P. Burton-Pye, Lynn C. Francesconi, and Mark R. Antonio
pp 6889 - 6899; DOI:
10.1021/ic800465e
PDF
Bulky N-Substituted 1,3-Benzazaphospholes: Access via Pd-Catalyzed C−N and C−P Cross Coupling, Lithiation, and Conversion to Novel PC−PtBu2 Hybrid Ligands
Bhaskar Reddy Aluri, Markus K. Kindermann, Peter G. Jones, Ina Dix, and Joachim Heinicke
pp 6900 - 6912; DOI:
10.1021/ic800430f
PDF
Unprecedented Formation of Novel Phosphonodithioate Ligands from Diferrocenyldithiadiphosphetane Disulfide
Eva M. Barranco, Olga Crespo, M. Concepción Gimeno, Peter G. Jones, and Antonio Laguna
pp 6913 - 6918; DOI:
10.1021/ic800470e
PDF
Oxidation of Pt-bound Bis-hydroxylamine as a Novel Route to Unexplored Dinitrosoalkane Ligated Species
Konstantin V. Luzyanin, Pavel V. Gushchin, Armando J. L. Pombeiro, Matti Haukka, Victor I. Ovcharenko, and Vadim Yu. Kukushkin
pp 6919 - 6930; DOI:
10.1021/ic800481a
PDF
Copper(I) Cyanide Networks: Synthesis, Structure, and Luminescence Behavior. Part 2. Piperazine Ligands and Hexamethylenetetramine
Mi Jung Lim, Courtney A. Murray, Tristan A. Tronic, Kathryn E. deKrafft, Amanda N. Ley, Jordan C. deButts, Robert D. Pike, Haiyan Lu, and Howard H. Patterson
pp 6931 - 6947; DOI:
10.1021/ic8005184
PDF
CO-Migration in the Ligand Substitution Process of the Chelating Diphosphite Diiron Complex (μ-pdt)[Fe(CO)3][Fe(CO){(EtO)2PN(Me)P(OEt)2}]
Ning Wang, Mei Wang, Tianbiao Liu, Ping Li, Tingting Zhang, Marcetta Y. Darensbourg, and Licheng Sun
pp 6948 - 6955; DOI:
10.1021/ic800525n
PDF
Extended Triple-Bridged Ni(II)- and Co(II)-Hydroxamate Trinuclear Complexes: Synthesis, Crystal Structures, and Magnetic Properties
Z. Tomkowicz, S. Ostrovsky, H. Müller-Bunz, A. J. Hussein Eltmimi, M. Rams, D. A. Brown, and W. Haase
pp 6956 - 6963; DOI:
10.1021/ic800264y
PDF
Ruthenium(III) Chloride Complex with a Tridentate Bis(arylimino)pyridine Ligand: Synthesis, Spectra, X-ray Structure, 9-Ethylguanine Binding Pattern, and In Vitro Cytotoxicity
Ariadna Garza-Ortiz, Palanisamy Uma Maheswari, Maxime Siegler, Anthony L. Spek, and Jan Reedijk
pp 6964 - 6973; DOI:
10.1021/ic8005579
PDF
Ultrafast Excited State Dynamics of Pt(II) Chromophores Bearing Multiple Infrared Absorbers
Elena A. Glik, Solen Kinayyigit, Kate L. Ronayne, Michael Towrie, Igor V. Sazanovich, Julia A. Weinstein, and Felix N. Castellano
pp 6974 - 6983; DOI:
10.1021/ic800578h
PDF
Tributylphosphate Extraction Behavior of Bismuthate-Oxidized Americium
Bruce J. Mincher, Leigh R. Martin, and Nicholas C. Schmitt
pp 6984 - 6989; DOI:
10.1021/ic800667h
PDF
New Palladium(II) and Platinum(II) Complexes with 9-Aminoacridine: Structures, Luminiscence, Theoretical Calculations, and Antitumor Activity
José Ruiz, Julia Lorenzo, Consuelo Vicente, Gregorio López, José María López-de-Luzuriaga, Miguel Monge, Francesc X. Avilés, Delia Bautista, Virtudes Moreno, and Antonio Laguna
pp 6990 - 7001; DOI:
10.1021/ic800589m
PDF
Precursors to [FeFe]-Hydrogenase Models: Syntheses of Fe2(SR)2(CO)6 from CO-Free Iron Sources
Phillip I. Volkers, Christine A. Boyke, Jinzhu Chen, Thomas B. Rauchfuss, C. Matthew Whaley, Scott R. Wilson, and Haijun Yao
pp 7002 - 7008; DOI:
10.1021/ic800601k
PDF
Series of Mixed Valent Fe(II)Fe(I) Complexes That Model the Hox State of [FeFe]Hydrogenase: Redox Properties, Density-Functional Theory Investigation, and Reactivities with Extrinsic CO
Christine M. Thomas, Tianbiao Liu, Michael B. Hall, and Marcetta Y. Darensbourg
pp 7009 - 7024; DOI:
10.1021/ic800654a
PDF
Homoleptic Selenium Cyanides: Attempted Preparation of Se(CN)4 and Redetermination of the Crystal Structure of Se(CN)2
Thomas M. Klapötke, Burkhard Krumm, and Matthias Scherr
pp 7025 - 7028; DOI:
10.1021/ic801011g
PDF
Photocatalytic Degradation of Dichloromethane by Chlorocuprate(II) Ions
Kevin J. Doyle, Huy Tran, Miguel Baldoni-Olivencia, Merve Karabulut, and Patrick E. Hoggard
pp 7029 - 7034; DOI:
10.1021/ic800684v
PDF
New Tetraphosphane Ligands {(X2P)2NC6H4N(PX2)2} (X = Cl, F, OMe, OC6H4OMe-o): Synthesis, Derivatization, Group 10 and 11 Metal Complexes and Catalytic Investigations. DFT Calculations on Intermolecular P···P Interactions in Halo-Phosphines
Chelladurai Ganesamoorthy, Maravanji S. Balakrishna, Joel T. Mague, and Heikki M. Tuononen
pp 7035 - 7047; DOI:
10.1021/ic800724u
PDF
Trichromophoric Systems from Square-Planar Pt-Ethynylbipyridine and Octahedral Ru- and Os-Bipyridine Centers: Syntheses, Structures, Electrochemical Behavior, and Bipartition of Energy Transfer
Barbara Ventura, Andrea Barbieri, Francesco Barigelletti, Julie Batcha Seneclauze, Pascal Retailleau, and Raymond Ziessel
pp 7048 - 7058; DOI:
10.1021/ic800768v
PDF

Issue 16


Self-Assembly and Characterization of a Novel 2D Network Polymer Containing a 60-Membered Organotin Macrocycle
Chunlin Ma, Qingfeng Wang, and Rufen Zhang
pp 7060 - 7061; DOI:
10.1021/ic800903s
PDF
High-Extinction Ruthenium Compounds for Sunlight Harvesting and Hole Transport
Aaron Staniszewski, William B. Heuer, and Gerald J. Meyer
pp 7062 - 7064; DOI:
10.1021/ic800171h
PDF
Structures of Silver Pyrazolates in Hydrocarbon Solutions via Vapor-Pressure Osmometry
D. M. Milan Krishantha, Chammi S. Palehepitiya Gamage, Zoltan A. Schelly, and H. V. Rasika Dias
pp 7065 - 7067; DOI:
10.1021/ic801141s
PDF
AEuAsS3 (A = Li, K, Rb, and Cs): New As3+ Species from an Arsenic-Rich Polysulfide Flux
Tarun K. Bera and Mercouri G. Kanatzidis
pp 7068 - 7070; DOI:
10.1021/ic801017h
PDF
Rapid Synthesis of Polyethylenimine-Protected Prussian Blue Nanocubes through a Thermal Process
Junfeng Zhai, Yueming Zhai, Liang Wang, and Shaojun Dong
pp 7071 - 7073; DOI:
10.1021/ic800941d
PDF
Fe2OCl62− Salt Formed by Electrochemical Oxidation of Ethylenedioxytetrathiafulvalenoquinone-1,3-dithiolemethide in the Presence of FeCl4 Ion with a Silicon Wafer Electrode
Tadahiro Koike, Sayo Yokota, Hideki Fujiwara, Toyonari Sugimoto, Satoru Noguchi, Dominique de Caro, and Lydie Valade
pp 7074 - 7076; DOI:
10.1021/ic8006487
PDF
Yttrium and Erbium Halide Complexes with [{Ti(η5-C5Me5)(μ-NH)}33-N)] as a Neutral Tridentate Ligand
Jorge Caballo, María García-Castro, Avelino Martín, Miguel Mena, Adrián Pérez-Redondo, and Carlos Yélamos
pp 7077 - 7079; DOI:
10.1021/ic8010426
PDF
Synthesis and Structure of an Aluminum Borate Chloride Consisting of 12-Membered Borate Rings and Aluminate Clusters
Wenliang Gao, Yingxia Wang, Guobao Li, Fuhui Liao, Liping You, and Jianhua Lin
pp 7080 - 7082; DOI:
10.1021/ic8010053
PDF
Catechol Oxidase Activity of a Series of New Dinuclear Copper(II) Complexes with 3,5-DTBC and TCC as Substrates: Syntheses, X-ray Crystal Structures, Spectroscopic Characterization of the Adducts and Kinetic Studies
Kazi Sabnam Banu, Tanmay Chattopadhyay, Arpita Banerjee, Santanu Bhattacharya, Eringathodi Suresh, Munirathinam Nethaji, Ennio Zangrando, and Debasis Das
pp 7083 - 7093; DOI:
10.1021/ic701332w
PDF
Assembly of Silver(I)−Organic Networks from Flexible Supramolecular Synthons with Pendant Ethynide Arms Attached to a Naphthyl Skeleton
Shuang-Quan Zang and Thomas C. W. Mak
pp 7094 - 7105; DOI:
10.1021/ic800576b
PDF
Redox Properties of Ruthenium Nitrosyl Porphyrin Complexes with Different Axial Ligation: Structural, Spectroelectrochemical (IR, UV−Visible, and EPR), and Theoretical Studies
Priti Singh, Atanu Kumar Das, Biprajit Sarkar, Mark Niemeyer, Federico Roncaroli, José A. Olabe, Jan Fiedler, Stanislav Záliš, and Wolfgang Kaim
pp 7106 - 7113; DOI:
10.1021/ic702371t
PDF
Transition Metal Coordination Chemistry ofN,N-Bis(2-{pyrid-2-ylethyl})hydroxylamine
Christopher W. Belock, Anil Çetin, Natalie V. Barone, and Christopher J. Ziegler
pp 7114 - 7120; DOI:
10.1021/ic702406n
PDF
Mechanistic Studies on Fast Ligand Substitution Reactions of Pt(II) in Different Ionic Liquids: Role of Solvent Polarity and Ion-Pair Formation
Svetlana Begel, Peter Illner, Simon Kern, Ralph Puchta, and Rudi van Eldik
pp 7121 - 7132; DOI:
10.1021/ic702420v
PDF
Two Dawson-Templated Three-Dimensional Metal−Organic Frameworks Based on Oxalate-Bridged Binuclear Cobalt(II)/Nickel(II) SBUs and Bpy Linkers
Xinyu Zhao, Dadong Liang, Shuxia Liu, Chunyan Sun, Ruige Cao, Chaoying Gao, Yuanhang Ren, and Zhongmin Su
pp 7133 - 7138; DOI:
10.1021/ic800131r
PDF
Molybdenum and Tungsten Structural Differences are Dependent on ndz2/(n + 1)s Mixing: Comparisons of (silox)3MX/R (M = Mo, W; silox = tBu3SiO)
David S. Kuiper, Richard E. Douthwaite, Ana-Rita Mayol, Peter T. Wolczanski, Emil B. Lobkovsky, Thomas R. Cundari, Oanh P. Lam, and Karsten Meyer
pp 7139 - 7153; DOI:
10.1021/ic800139c
PDF
Syntheses and Phosphorescent Properties of Blue Emissive Iridium Complexes with Tridentate Pyrazolyl Ligands
Lifen Yang, Fumio Okuda, Katsuaki Kobayashi, Koichi Nozaki, Yoshiaki Tanabe, Youichi Ishii, and Masa-aki Haga
pp 7154 - 7165; DOI:
10.1021/ic800196s
PDF
New Water Soluble and Luminescent Platinum(II) Compounds, Vapochromic Behavior of [K(H2O)][Pt(bzq)(CN)2], New Examples of the Influence of the Counterion on the Photophysical Properties of d8 Square-Planar Complexes
Juan Forniés, Sara Fuertes, J. Antonio López, Antonio Martín, and Violeta Sicilia
pp 7166 - 7176; DOI:
10.1021/ic800265q
PDF
Silanol-Based Pincer Pt(II) Complexes: Synthesis, Structure, and Unusual Reactivity
Edward E. Korshin, Gregory Leitus, Linda J. W. Shimon, Leonid Konstantinovski, and David Milstein
pp 7177 - 7189; DOI:
10.1021/ic800457u
PDF
Highly Sensitive Multiresponsive Chemosensor for Selective Detection of Hg2+ in Natural Water and Different Monitoring Environments
Dayu Wu, Wei Huang, Zhihua Lin, Chunying Duan, Cheng He, Shuo Wu, and Dehui Wang
pp 7190 - 7201; DOI:
10.1021/ic8004344
PDF
Magnetic Susceptibility and Ground-State Zero-Field Splitting in High-Spin Mononuclear Manganese(III) of Inverted N-Methylated Porphyrin Complexes: Mn(2-NCH3NCTPP)Br
Sheng-Wei Hung, Fuh-An Yang, Jyh-Horung Chen, Shin-Shin Wang, and Jo-Yu Tung
pp 7202 - 7206; DOI:
10.1021/ic800490t
PDF
Phosphorous Acid and Urea: Valuable Sources of Phosphorus and Nitrogen in the Hydrothermal Synthesis of Ammonium-Thorium Phosphates
Miguel A. Salvadó, Pilar Pertierra, Anatoly I. Bortun, Camino Trobajo, and José R. García
pp 7207 - 7210; DOI:
10.1021/ic800818c
PDF
Solid State and Aqueous Solution Characterization of Rectangular Tetranuclear VIV/V-p-Semiquinonate/Hydroquinonate Complexes Exhibiting a Proton Induced Electron Transfer
Chryssoula Drouza and Anastasios D. Keramidas
pp 7211 - 7224; DOI:
10.1021/ic800569t
PDF
Influence of the Apical Ligand in the Thermotropic Mesomorphism of Cationic Copper-Based Surfactants
Jeffery A. Driscoll, Paul H. Keyes, Mary Jane Heeg, Paul A. Heiney, and Claudio N. Verani
pp 7225 - 7232; DOI:
10.1021/ic8005162
PDF
A Second-Generation Janus Scorpionate Ligand: Controlling Coordination Modes in Iron(II) Complexes by Steric Modulation
Rosalice M. Silva, Chengeto Gwengo, Sergey V. Lindeman, Mark D. Smith, Gary J. Long, Fernande Grandjean, and James R. Gardinier
pp 7233 - 7242; DOI:
10.1021/ic8005794
PDF
Distortion and Charge Density Wave in the Ga Square Net Coupled to the Site Occupancy Wave in YCo0.88Ga3Ge
Danielle L. Gray, Melanie C. Francisco, and Mercouri G. Kanatzidis
pp 7243 - 7248; DOI:
10.1021/ic801080f
PDF
Energy Transfer Dynamics in ReI−Based Polynuclear Assemblies: A Quantitative Application of Förster Theory
Troy E. Knight, Dong Guo, Juan Pablo Claude, and James K. McCusker
pp 7249 - 7261; DOI:
10.1021/ic800670b
PDF
Energy Transfer and Tunable Luminescence Properties of Eu3+ in TbBO3 Microspheres via a Facile Hydrothermal Process
Jun Yang, Cuimiao Zhang, Chunxia Li, Yingning Yu, and Jun Lin
pp 7262 - 7270; DOI:
10.1021/ic800586n
PDF
Synthesis and Study of Hexanuclear Molybdenum Clusters Containing Thiolate Ligands
Lisa F. Szczepura, Karen A. Ketcham, Betty A. Ooro, Julia A. Edwards, Jeffrey N. Templeton, David L. Cedeño, and Alan J. Jircitano
pp 7271 - 7278; DOI:
10.1021/ic800613d
PDF
Oxidative Addition of Group 13 and 14 Metal Halides and Alkyls to Ga(DDP) (DDP = Bulky Bisimidinate)
Andreas Kempter, Christian Gemel, and Roland A. Fischer
pp 7279 - 7285; DOI:
10.1021/ic800690z
PDF
How Close Can You Get? Studies of Ultrafast Light-Induced Processes in Ruthenium-[60] Fullerene Dyads with Short Pyrazolino and Pyrrolidino Links
Susanne Karlsson, Judit Modin, Hans-Christian Becker, Leif Hammarström, and Helena Grennberg
pp 7286 - 7294; DOI:
10.1021/ic800168d
PDF
Isoquinoline-Based TQEN Family as TPEN-Derived Fluorescent Zinc Sensors
Yuji Mikata, Azusa Yamanaka, Azusa Yamashita, and Shigenobu Yano
pp 7295 - 7301; DOI:
10.1021/ic8002614
PDF
Synthesis and Characterization of Phase-Pure Manganese(II) and Manganese(III) Silicalite-2
Adrian Lita, Xisai Ma, Robert W. Meulenberg, Tony van Buuren, and A. E. Stiegman
pp 7302 - 7308; DOI:
10.1021/ic800366j
PDF
Designed Synthesis of New ortho-Carborane Derivatives: from Mono- to Polysubstituted Frameworks
Gemma Barberà, Albert Vaca, Francesc Teixidor, Reijo Sillanpää, Raikko Kivekäs, and Clara Viñas
pp 7309 - 7316; DOI:
10.1021/ic800362z
PDF
Oxoperoxo Vanadium(V) Complexes of L-Lactic Acid: Density Functional Theory Study of Structure and NMR Chemical Shifts
Licínia L. G. Justino, M. Luísa Ramos, Fernando Nogueira, Abilio J. F. N. Sobral, Carlos F. G. C. Geraldes, Martin Kaupp, Hugh D. Burrows, Carlos Fiolhais, and Victor M. S. Gil
pp 7317 - 7326; DOI:
10.1021/ic800405x
PDF
17O Solid-State NMR and First-Principles Calculations of Sodium Trimetaphosphate (Na3P3O9), Tripolyphosphate (Na5P3O10), and Pyrophosphate (Na4P2O7)
Filipe Vasconcelos, Sylvain Cristol, Jean-Francois Paul, Grégory Tricot, Jean-Paul Amoureux, Lionel Montagne, Francesco Mauri, and Laurent Delevoye
pp 7327 - 7337; DOI:
10.1021/ic800637p
PDF
Synthesis, Structure, Spectroscopic Properties, and Antiproliferative Activity In Vitro of Novel Osmium(III) Complexes with Azole Heterocycles
Iryna N. Stepanenko, Artem A. Krokhin, Roland O. John, Alexander Roller, Vladimir B. Arion, Michael A. Jakupec, and Bernhard K. Keppler
pp 7338 - 7347; DOI:
10.1021/ic8006958
PDF
BX4 and AlX4 Superhalogen Anions (X = F, Cl, Br): An ab Initio Study
Celina Sikorska, Sylwia Smuczyńska, Piotr Skurski, and Iwona Anusiewicz
pp 7348 - 7354; DOI:
10.1021/ic800863z
PDF
Magnetic Ground-State of Perovskite PbVO3 with Large Tetragonal Distortion
Kengo Oka, Ikuya Yamada, Masaki Azuma, Soshi Takeshita, Kohki H. Satoh, Akihiro Koda, Ryosuke Kadono, Mikio Takano, and Yuichi Shimakawa
pp 7355 - 7359; DOI:
10.1021/ic800649a
PDF
Binding Properties of Solvatochromic Indicators [Cu(X)(acac)(tmen)] (X = PF6 and BF4, acac = Acetylacetonate, tmen = N,N,N′,N′-Tetramethylethylenediamine) in Solution and the Solid State
Shin-ichiro Noro, Nobuhiro Yanai, Susumu Kitagawa, Tomoyuki Akutagawa, and Takayoshi Nakamura
pp 7360 - 7365; DOI:
10.1021/ic800685z
PDF
Triazenide Complexes of the Heavier Alkaline Earths: Synthesis, Characterization, And Suitability for Hydroamination Catalysis
Anthony G. M. Barrett, Mark R. Crimmin, Michael S. Hill, Peter B. Hitchcock, Gabriele Kociok-Köhn, and Panayiotis A. Procopiou
pp 7366 - 7376; DOI:
10.1021/ic800789x
PDF
Ligand Field Stabilization and Activation Energies Revisited: Molecular Modeling of the Thermodynamic and Kinetic Properties of Divalent, First-Row Aqua Complexes
Robert J. Deeth and Kris Randell
pp 7377 - 7388; DOI:
10.1021/ic800628j
PDF
Pentanuclear and Heptanuclear Helicates By Self-Assembly of d10 Metal Ions and a Rigid Aromatic Bis-Bidentate Chelator
Ai-Xin Zhu, Jie-Peng Zhang, Yan-Yong Lin, and Xiao-Ming Chen
pp 7389 - 7395; DOI:
10.1021/ic8007969
PDF
1D Molecular Ladder of the Ionic Complex of Terbium-4-Sebacoylbis(1-phenyl-3-methyl-5-pyrazolonate) and Sodium Dibenzo-18-Crown-6: Synthesis, Crystal Structure, and Photophysical Properties
P.N. Remya, S. Biju, M. L. P. Reddy, Alan H. Cowley, and Michael Findlater
pp 7396 - 7404; DOI:
10.1021/ic800615y
PDF
Redox and Structural Properties of Mixed-Valence Models for the Active Site of the [FeFe]-Hydrogenase: Progress and Challenges
Aaron K. Justice, Luca De Gioia, Mark J. Nilges, Thomas B. Rauchfuss, Scott R. Wilson, and Giuseppe Zampella
pp 7405 - 7414; DOI:
10.1021/ic8007552
PDF
Mixed-Ligand Uranyl(V) β-Diketiminate/β-Diketonate Complexes: Synthesis and Characterization
Trevor W. Hayton and Guang Wu
pp 7415 - 7423; DOI:
10.1021/ic800778j
PDF
First Row Transition Metal Ion-Assisted Ammonia−Borane Hydrolysis for Hydrogen Generation
Suresh Babu Kalidindi, M. Indirani, and Balaji R. Jagirdar
pp 7424 - 7429; DOI:
10.1021/ic800805r
PDF
ZnVSe2O7 and Cd6V2Se5O21: New d10 Transition-Metal Selenites with V(IV) or V(V) Cations
Hai-Long Jiang, Fang Kong, Yang Fan, and Jiang-Gao Mao
pp 7430 - 7437; DOI:
10.1021/ic800638e
PDF
Cobalt(II) Citrate Cubane Single-Molecule Magnet
Kyle W. Galloway, Alexander M. Whyte, Wolfgang Wernsdorfer, Javier Sanchez-Benitez, Konstantin V. Kamenev, Andrew Parkin, Robert D. Peacock, and Mark Murrie
pp 7438 - 7442; DOI:
10.1021/ic800896k
PDF

Issue 17


Biphasic Hydrogenation over PVP Stabilized Rh Nanoparticles in Hydroxyl Functionalized Ionic Liquids
Xue Yang, Ning Yan, Zhaofu Fei, R. Micaela Crespo-Quesada, Gábor Laurenczy, Lioubov Kiwi-Minsker, Yuan Kou, Yongdan Li, and Paul J. Dyson
pp 7444 - 7446; DOI:
10.1021/ic8009145
PDF
A New Class of Isocyanide-Containing Rhenium(I) Bipyridyl Luminophore with Readily Tunable and Highly Environmentally Sensitive Excited-State Properties
Chi-On Ng, Larry Tso-Lun Lo, Siu-Mui Ng, Chi-Chiu Ko, and Nianyong Zhu
pp 7447 - 7449; DOI:
10.1021/ic800906x
PDF
Separation and Optical Resolution of a Pair of atrop Diastereomers of the Octahedral Rhodium(III) Complex with a Nine-Membered S,S-Chelate Ring
Nobuto Yoshinari and Takumi Konno
pp 7450 - 7452; DOI:
10.1021/ic800910e
PDF
Multiple-Timescale Photoreactivity of a Model Compound Related to the Active Site of [FeFe]-Hydrogenase
Anna R. Ridley, A. Ian Stewart, Katrin Adamczyk, Hirendra N. Ghosh, Boutheïna Kerkeni, Z. Xiao Guo, Erik T. J. Nibbering, Christopher J. Pickett, and Neil T. Hunt
pp 7453 - 7455; DOI:
10.1021/ic800568k
PDF
Synthesis and Structure of a Ferrocenylboron Dication
Holger Braunschweig, Martin Kaupp, Christoph Lambert, Dörte Nowak, Krzysztof Radacki, Sandra Schinzel, and Katharina Uttinger
pp 7456 - 7458; DOI:
10.1021/ic800876p
PDF
Coordination Networks from a Bifunctional Molecule Containing Carboxyl and Thioether Groups
Xiao-Ping Zhou, Zhengtao Xu, Matthias Zeller, Allen D. Hunter, Stephen Sin-Yin Chui, and Chi-Ming Che
pp 7459 - 7461; DOI:
10.1021/ic800952z
PDF
Hybrid Cobalt Hydroxyoxalate Material Containing 3D Co−O−Co Connectivity and Showing Ferrimagnetic Ordering
Xian-Ming Zhang, Xu-Hui Zhang, Hai-Shun Wu, Ming-Liang Tong, and Seik Weng Ng
pp 7462 - 7464; DOI:
10.1021/ic8012014
PDF
Selenidobis(dithiolene)metal(IV) Complexes (Metal M = Mo, W) Potentially Related to the Nicotinic Acid Hydroxylase Reaction Center: Redox Aspects in Electrochemistry and Oxygen Atom Transfer from Me3NO to MIV Centers
Hiroyuki Tano, Reiko Tajima, Hiroyuki Miyake, Shinobu Itoh, and Hideki Sugimoto
pp 7465 - 7467; DOI:
10.1021/ic8009942
PDF
First-Row Transition-Metal Complexes of a New Pentadentate Ligand, α,α,α′,α′-Tetra(pyrazolyl)lutidine
Tyler J. Morin, Brian Bennett, Sergey V. Lindeman, and James R. Gardinier
pp 7468 - 7470; DOI:
10.1021/ic801093q
PDF
Synthesis and Characterization of a Cationic Ruthenium Complex Featuring an Unusual Bis(η2-BH) Monoborane Ligand
Kevin D. Hesp, Matthew A. Rankin, Robert McDonald, and Mark Stradiotto
pp 7471 - 7473; DOI:
10.1021/ic801300m
PDF
In Situ Spectroscopy and Spectroelectrochemistry of Uranium in High-Temperature Alkali Chloride Molten Salts
Ilya B. Polovov, Vladimir A. Volkovich, John M. Charnock, Brett Kralj, Robert G. Lewin, Hajime Kinoshita, Iain May, and Clint A. Sharrad
pp 7474 - 7482; DOI:
10.1021/ic701415z
PDF
Syntheses, Structures, and Photophysical Properties of Mono- and Dinuclear Sulfur-Rich Gold(I) Complexes
Fabrice Guyon, Aurélien Hameau, Abderrahim Khatyr, Michael Knorr, Hedi Amrouche, Daniel Fortin, Pierre D. Harvey, Carsten Strohmann, Amadou L. Ndiaye, Volker Huch, Michael Veith, and Narcis Avarvari
pp 7483 - 7492; DOI:
10.1021/ic7022067
PDF
Effects of Excited State−Excited State Configurational Mixing on Emission Bandshape Variations in Ruthenium−Bipyridine Complexes
Onduru S. Odongo, Mary Jane Heeg, Yuan-Jang Chen, Puhui Xie, and John F. Endicott
pp 7493 - 7511; DOI:
10.1021/ic7024473
PDF
Redox Control of Photoinduced Electron Transfer in Axial Terpyridoxy Porphyrin Complexes
Prashanth Kumar Poddutoori, Premaladha Poddutoori, Bhaskar G. Maiya, Thazhe Kootteri Prasad, Yuri E. Kandrashkin, Sergei Vasil’ev, Doug Bruce, and Art van der Est
pp 7512 - 7522; DOI:
10.1021/ic702480m
PDF
Syntheses, Structures, and Spectroscopic Properties of K9Nd[PS4]4, K3Nd[PS4]2, Cs3Nd[PS4]2, and K3Nd3[PS4]4
Yuandong Wu and Wolfgang Bensch
pp 7523 - 7534; DOI:
10.1021/ic800143x
PDF
Water-Soluble 2-Hydroxyisophthalamides for Sensitization of Lanthanide Luminescence
Amanda P. S. Samuel, Evan G. Moore, Marco Melchior, Jide Xu, and Kenneth N. Raymond
pp 7535 - 7544; DOI:
10.1021/ic800328g
PDF
Experimental and Theoretical Study of the Antisymmetric Magnetic Behavior of Copper inverse-9-Metallacrown-3 Compounds
Tereza Afrati, Catherine Dendrinou-Samara, Catherine Raptopoulou, Aris Terzis, Vassilis Tangoulis, Athanassios Tsipis, and Dimitris P. Kessissoglou
pp 7545 - 7555; DOI:
10.1021/ic8003257
PDF
Chiral Distortion in a MnIV(salen)(N3)2 Derived from Jacobsen’s Catalyst as a Possible Conformation Model for Its Enantioselective Reactions
Takuya Kurahashi and Hiroshi Fujii
pp 7556 - 7567; DOI:
10.1021/ic800443q
PDF
High-Throughput Assisted Rationalization of the Formation of Metal Organic Frameworks in the Iron(III) Aminoterephthalate Solvothermal System
Sebastian Bauer, Christian Serre, Thomas Devic, Patricia Horcajada, Jérôme Marrot, Gérard Férey, and Norbert Stock
pp 7568 - 7576; DOI:
10.1021/ic800538r
PDF
Temperature-Dependent Interactions and Disorder in the Spin-Transition Compound [FeII(L)2][ClO4]2·C7H8 Through Structural, Calorimetric, Magnetic, Photomagnetic, and Diffuse Reflectance Investigations
Vibha Mishra, Rabindranath Mukherjee, Jorge Linares, Chérif Balde, Cédric Desplanches, Jean-François Létard, Eric Collet, Loic Toupet, Miguel Castro, and François Varret
pp 7577 - 7587; DOI:
10.1021/ic8002977
PDF
Metallo-Supramolecular Self-Assembly: the Case of Triangle-Square Equilibria
Torsten Weilandt, Ralf W. Troff, Heidi Saxell, Kari Rissanen, and Christoph A. Schalley
pp 7588 - 7598; DOI:
10.1021/ic800334k
PDF
4′-(5′′′-R-Pyrimidyl)-2,2′:6′,2′′-terpyridyl (R = H, OEt, Ph, Cl, CN) Platinum(II) Phenylacetylide Complexes: Synthesis and Photophysics
Zhiqiang Ji, Yunjing Li, and Wenfang Sun
pp 7599 - 7607; DOI:
10.1021/ic800358w
PDF
Novel Mixed-Valence Manganese Cluster with Two Distinct Mn3(II/III/II) and Mn3(III/II/III) Trinuclear Units in a Pseudocubane-like Arrangement
Anastasia Dimitrakopoulou, Vassilis Psycharis, Catherine P. Raptopoulou, Aris Terzis, Vassilis Tangoulis, and Dimitris P. Kessissoglou
pp 7608 - 7614; DOI:
10.1021/ic800472c
PDF
Extended OrganicInorganic Hybrids Based on Dawson and Double-Dawson-Type Polyoxometalates
Zhiming Zhang, Yangguang Li, Yonghui Wang, Yanfei Qi, and Enbo Wang
pp 7615 - 7622; DOI:
10.1021/ic800479k
PDF
Synthesis and Magnetic Properties of New Mono- and Binuclear Iron Complexes with Salicyloylhydrazono Dithiolane Ligand
Nouri Bouslimani, Nicolas Clément, Guillaume Rogez, Philippe Turek, Maxime Bernard, Samuel Dagorne, David Martel, Hoan Nguyen Cong, and Richard Welter
pp 7623 - 7630; DOI:
10.1021/ic800522h
PDF
Hydrogenation of Molecular Cyclic Diborane(4) Compounds Featuring B−B Bonds and Olefinic or Aromatic Bridges: a Quantum Chemical Study
F. Allouti, W. Siebert, and H.-J. Himmel
pp 7631 - 7637; DOI:
10.1021/ic800540z
PDF
Structural Characterization and Self-Association of (Arylimido)vanadium(V) Triisopropoxides
Toshiyuki Moriuchi, Kenta Ishino, Tomohiko Beppu, Masafumi Nishina, and Toshikazu Hirao
pp 7638 - 7643; DOI:
10.1021/ic800528m
PDF
Tuning of the [Cu3(μ-O)]4+/5+ Redox Couple: Spectroscopic Evidence of Charge Delocalization in the Mixed-Valent [Cu3(μ-O)]5+ Species
Marlyn Rivera-Carrillo, Indranil Chakraborty, Gellert Mezei, Richard D. Webster, and Raphael G. Raptis
pp 7644 - 7650; DOI:
10.1021/ic800531y
PDF
Approximant Phases and an Icosahedral Quasicrystal in the Ca−Au−Ga System: The Influence of Size of Gallium versus Indium
Qisheng Lin and John D. Corbett
pp 7651 - 7659; DOI:
10.1021/ic800694j
PDF
Structural Variation within Homometallic Uranium(VI) Carboxyphosphonates: In Situ Ligand Synthesis, Directed Assembly, Metal−Ligand Coordination and Hydrogen Bonding
Karah E. Knope and Christopher L. Cahill
pp 7660 - 7672; DOI:
10.1021/ic800683m
PDF
[1H, 15N] Heteronuclear Single Quantum Coherence NMR Study of the Mechanism of Aquation of Platinum(IV) Ammine Complexes
Murray S. Davies, Matthew D. Hall, Susan J. Berners-Price, and Trevor W. Hambley
pp 7673 - 7680; DOI:
10.1021/ic8006734
PDF
Halide Coordination to Zinc Porphyrin Sensitizers Anchored to Nanocrystalline TiO2
Amanda J. Morris, Andras Marton, and Gerald J. Meyer
pp 7681 - 7685; DOI:
10.1021/ic800682q
PDF
Organic-Soluble Tri-, Tetra-, and Pentanuclear Titanium(IV) Phosphates
Ramaswamy Murugavel and Subramaniam Kuppuswamy
pp 7686 - 7694; DOI:
10.1021/ic800675n
PDF
Synthesis, Structure, and Electronic Properties of a Dimer of Ru(bpy)2 Doubly Bridged by Methoxide and Pyrazolate
Hershel Jude, Francisca N. Rein, Peter S. White, Dana M. Dattelbaum, and Reginaldo C. Rocha
pp 7695 - 7702; DOI:
10.1021/ic800719u
PDF
[Pt]2Pb Trinuclear Systems: Impact of the Anionic Platinum Fragment on the Lead Environment and Photoluminescence
Jesús Rubén Berenguer, Alvaro Díez, Julio Fernández, Juan Forniés, Ana García, Belén Gil, Elena Lalinde, and M. Teresa Moreno
pp 7703 - 7716; DOI:
10.1021/ic8006876
PDF
Solvent, Anion, and Structural Effects on the Redox Potentials and UV−visible Spectral Properties of Mononuclear Manganese Corroles
Jing Shen, Maya El Ojaimi, Mohammed Chkounda, Claude P. Gros, Jean-Michel Barbe, Jianguo Shao, Roger Guilard, and Karl M. Kadish
pp 7717 - 7727; DOI:
10.1021/ic8007415
PDF
Two- and Three-fold Interpenetrated Metal-Organic Frameworks from One-Pot Crystallization
Mohammad Hedayetullah Mir, Susumu Kitagawa, and Jagadese J. Vittal
pp 7728 - 7733; DOI:
10.1021/ic800766q
PDF
A New Bis(1-naphthylimino)acenaphthene Compound and Its Pd(II) and Zn(II) Complexes: Synthesis, Characterization, Solid-State Structures and Density Functional Theory Studies on the syn and anti Isomers
Vitor Rosa, Teresa Avilés, Gabriel Aullon, Berta Covelo, and Carlos Lodeiro
pp 7734 - 7744; DOI:
10.1021/ic800790u
PDF
Hydration of Hydrogentungstate Anions at Different pH Conditions: A Car−Parrinello Molecular Dynamics Study
Antonio Rodríguez-Fortea, Laia Vilà-Nadal, and Josep M. Poblet
pp 7745 - 7750; DOI:
10.1021/ic8007766
PDF
Phase Selection and Discovery among Five Assembly Modes in a Coordination Polymerization
Stephen R. Caskey, Antek G. Wong-Foy, and Adam J. Matzger
pp 7751 - 7756; DOI:
10.1021/ic800777r
PDF
Investigation of Nanostructure and Thermal Behavior of Zinc-Substituted Fluorapatite
G. W. Chinthaka Silva, Oliver Hemmers, Ken R. Czerwinski, and Dennis W. Lindle
pp 7757 - 7767; DOI:
10.1021/ic800794x
PDF
Structure and Properties of [CrIIIF(NCMe)5](BF4)2·MeCN: A Nonaqueous Source of CrIIIF2+ and a Building Block for New Prussian-Blue-Like Magnetic Materials
Kendric J. Nelson, Antonio G. DiPasquale, Arnold L. Rheingold, Matthew C. Daniels, and Joel S. Miller
pp 7768 - 7774; DOI:
10.1021/ic800837f
PDF
Interconversion between (3,1) and (4,0) Isomers of Ru2(L)4X Complexes where L is 2-Anilinopyridinate or 2-(2,4,6-Trifluoroanilino)pyridinate Anion and X = Cl or C≡CC5H4N
Minh Nguyen, Tuan Phan, Eric Van Caemelbecke, Wiroaj Kajonkijya, John L. Bear, and Karl M. Kadish
pp 7775 - 7783; DOI:
10.1021/ic800787p
PDF
Coordination-Driven Self-Assembly of a Novel Carbonato-Bridged Heteromolecular Neutral Nickel(II) Triangle by Atmospheric CO2 Fixation
Pampa Mukherjee, Michael G. B. Drew, Marta Estrader, and Ashutosh Ghosh
pp 7784 - 7791; DOI:
10.1021/ic800786s
PDF
Unravelling the Intrinsic Features of NO Binding to Iron(II)- and Iron(III)-Hemes
Barbara Chiavarino, Maria Elisa Crestoni, Simonetta Fornarini, and Carme Rovira
pp 7792 - 7801; DOI:
10.1021/ic800953w
PDF
Remarkable Tuning of the Photophysical Properties of Bifunctional Lanthanide tris(Dipicolinates) and its Consequence on the Design of Bioprobes
Anne-Laure Gassner, Céline Duhot, Jean-Claude G. Bünzli, and Anne-Sophie Chauvin
pp 7802 - 7812; DOI:
10.1021/ic800842f
PDF
General Synthesis and Phase Control of Metal Molybdate Hydrates MMoO4·nH2O (M = Co, Ni, Mn, n = 0, 3/4, 1) Nano/Microcrystals by a Hydrothermal Approach: Magnetic, Photocatalytic, and Electrochemical Properties
Yi Ding, Yong Wan, Yu-Lin Min, Wei Zhang, and Shu-Hong Yu
pp 7813 - 7823; DOI:
10.1021/ic8007975
PDF
Covalency in the f Element−Chalcogen Bond. Computational Studies of M[N(EPR2)2]3 (M = La, Ce, Pr, Pm, Eu, U, Np, Pu, Am, Cm; E = O, S, Se, Te; R = H, iPr, Ph)
Kieran I. M. Ingram, Matthew J. Tassell, Andrew J. Gaunt, and Nikolas Kaltsoyannis
pp 7824 - 7833; DOI:
10.1021/ic800835k
PDF
Cupric Siliconiobate. Synthesis and Solid-State Studies of a Pseudosandwich-Type Heteropolyanion
Travis M. Anderson, Todd M. Alam, Mark A. Rodriguez, Joel N. Bixler, Wenqian Xu, John B. Parise, and May Nyman
pp 7834 - 7839; DOI:
10.1021/ic800860q
PDF
Lanthanide Complexes Based on a 1,7-Diaza-12-crown-4 Platform Containing Picolinate Pendants: A New Structural Entry for the Design of Magnetic Resonance Imaging Contrast Agents
Marta Mato-Iglesias, Adrián Roca-Sabio, Zoltán Pálinkás, David Esteban-Gómez, Carlos Platas-Iglesias, Éva Tóth, Andrés de Blas, and Teresa Rodríguez-Blas
pp 7840 - 7851; DOI:
10.1021/ic800878x
PDF
Catalytic Dioxygen Activation by (Nitro)(meso-tetrakis(2-N-methylpyridyl)porphyrinato)cobalt(III) Cation Derivatives Electrostatically Immobilized in Nafion Films: An Experimental and DFT Investigation
John A. Goodwin, Jennifer L. Coor, Donald F. Kavanagh, Mathieu Sabbagh, James W. Howard, John R. Adamec, Deidre J. Parmley, Emily M. Tarsis, Tigran S. Kurtikyan, Astghik A. Hovhannisyan, Patrick J. Desrochers, and Jean M. Standard
pp 7852 - 7862; DOI:
10.1021/ic8000762
PDF
Investigation of Thermal Expansion and Compressibility of Rare-Earth Orthovanadates Using a Dielectric Chemical Bond Method
Siyuan Zhang, Shihong Zhou, Huaiyong Li, and Ling Li
pp 7863 - 7867; DOI:
10.1021/ic800672h
PDF
Chemical Stability of ZnO Nanostructures in Simulated Physiological Environments and Its Application in Determining Polar Directions
Chun Cheng, Renlong Xin, Yang Leng, Dapeng Yu, and Ning Wang
pp 7868 - 7873; DOI:
10.1021/ic8005234
PDF
On the Structure of Amorphous Calcium CarbonateA Detailed Study by Solid-State NMR Spectroscopy
Holger Nebel, Markus Neumann, Christian Mayer, and Matthias Epple
pp 7874 - 7879; DOI:
10.1021/ic8007409
PDF
Reactivity of Electrochemically Generated Rhenium (II) Tricarbonyl α-Diimine Complexes: A Reinvestigation of the Oxidation of Luminescent Re(CO)3(α-Diimine)Cl and Related Compounds
John P. Bullock, Eric Carter, Ryan Johnson, Abigail T. Kennedy, Sarah E. Key, Brian J. Kraft, David Saxon, and Patrick Underwood
pp 7880 - 7887; DOI:
10.1021/ic800530n
PDF
Theoretical Study of the Relative Stabilities of the α/β3-[XW11O39]m Lacunary Polyoxometalates (X = P, Si)
Danielle Laurencin, Anna Proust, and Hélène Gérard
pp 7888 - 7893; DOI:
10.1021/ic800539j
PDF
Synthetic and Mechanistic Aspects of a New Method for Ruthenium-Metalation of Porphyrins and Schiff-Bases
Júlio S. Rebouças, Elizabeth L. S. Cheu, Caroline J. Ware, Brian R. James, and Kirsten A. Skov
pp 7894 - 7907; DOI:
10.1021/ic800616q
PDF
Mononuclear Nickel(III) Complexes [NiIII(OR)(P(C6H3-3-SiMe3-2-S)3)] (R = Me, Ph) Containing the Terminal Alkoxide Ligand: Relevance to the Nickel Site of Oxidized-Form [NiFe] Hydrogenases
Tzung-Wen Chiou and Wen-Feng Liaw
pp 7908 - 7913; DOI:
10.1021/ic801069t
PDF
Effect of Chloride Ion on the Kinetics and Mechanism of the Reaction between Chlorite Ion and Hypochlorous Acid
Balázs Kormányos, István Nagypál, Gábor Peintler, and Attila K. Horváth
pp 7914 - 7920; DOI:
10.1021/ic8006684
PDF
Construction of Subphthalocyanine−Porphyrin and Subphthalocyanine−Phthalocyanine Heterodyads through Axial Coordination
Hu Xu and Dennis K. P. Ng
pp 7921 - 7927; DOI:
10.1021/ic800756h
PDF
Cobalt(III)-Mediated Disulfuration and Hydrosulfuration of Alkynes
Bao-Hua Xu, Xu-Qing Peng, Zhi-Wei Xu, Yi-Zhi Li, and Hong Yan
pp 7928 - 7933; DOI:
10.1021/ic801199e
PDF
First-Principles Investigation of the Schrock Mechanism of Dinitrogen Reduction Employing the Full HIPTN3N Ligand
Stephan Schenk, Boris Le Guennic, Barbara Kirchner, and Markus Reiher
pp 7934 - 7934; DOI:
10.1021/ic8012409
PDF

Issue 18


Alkali Metal Cation Effects on Hydrogen Uptake and Binding in Metal-Organic Frameworks
Karen L. Mulfort and Joseph T. Hupp
pp 7936 - 7938; DOI:
10.1021/ic800700h
PDF
Unexpected Cyclopentadienyl/Alkoxo Ligand Exchange in Titano- and Zirconocene. New Opportunities
Piotr Sobota, Józef Utko, £ukasz John, Lucjan B. Jerzykiewicz, and Anna Drág-Jarzábek
pp 7939 - 7941; DOI:
10.1021/ic8009749
PDF
Selective Metal Substitution for the Preparation of Heterobimetallic Microporous Coordination Polymers
Stephen R. Caskey and Adam J. Matzger
pp 7942 - 7944; DOI:
10.1021/ic8007427
PDF
A Novel Metal−Organic Network with High Thermal Stability: Nonlinear Optical and Photoluminescent Properties
Yan Li, Gang Xu, Wen-Qiang Zou, Ming-Sheng Wang, Fa-Kun Zheng, Mei-Feng Wu, Hui-Yi Zeng, Guo-Cong Guo, and Jin-Shun Huang
pp 7945 - 7947; DOI:
10.1021/ic800761h
PDF
Mixed-Valence CuIICuI15I17 Cluster Builds up a 3D Metal−Organic Framework with Paramagnetic and Thermochromic Characteristics
Jun He, Jing-Xiang Zhang, Chun-Kwan Tsang, Zhengtao Xu, Ye-Gao Yin, Dan Li, and Seik-Weng Ng
pp 7948 - 7950; DOI:
10.1021/ic8009207
PDF
Aqueous Ln(III) Luminescence Agents Derived from a Tasty Precursor
Christoph J. Jocher, Evan G. Moore, Jason D. Pierce, and Kenneth N. Raymond
pp 7951 - 7953; DOI:
10.1021/ic8010162
PDF
Seven-Coordinate Ruthenium Atoms Sequestered in Praseodymium Clusters in the Chloride {RuPr3}Cl3
Nina Herzmann, Anja-Verena Mudring, and Gerd Meyer
pp 7954 - 7956; DOI:
10.1021/ic800907c
PDF
Ferroelectric Heterobimetallic Clusters with Ferromagnetic Interactions
Cai-Feng Wang, Zhi-Guo Gu, Xiao-Mei Lu, Jing-Lin Zuo, and Xiao-Zeng You
pp 7957 - 7959; DOI:
10.1021/ic801049e
PDF
Structural and Magnetic Characterization of a μ-1,5-Dicyanamide-Bridged Iron Basic Carboxylate [Fe3O(O2C(CH3)3)6] 1D Chain
Pablo Alborés and Eva Rentschler
pp 7960 - 7962; DOI:
10.1021/ic801113d
PDF
Aurophilic Self-Assembly of a Mo4Au2 Phosphinidene Complex with an Unprecedented H-Shaped Planar Metal Core
M. Angeles Alvarez, Inmaculada Amor, M. Esther García, and Miguel A. Ruiz
pp 7963 - 7965; DOI:
10.1021/ic8011487
PDF
Harnessing Scorpionate Ligand Equilibria for Modeling Reduced Nickel Superoxide Dismutase Intermediates
Huaibo Ma, Swarup Chattopadhyay, Jeffrey L. Petersen, and Michael P. Jensen
pp 7966 - 7968; DOI:
10.1021/ic801099r
PDF
Di-2-pyridyl Ketone/Benzoate/Azide Combination as a Source of Copper(II) Clusters and Coordination Polymers: Dependence of the Product Identity on the Solvent
Theocharis C. Stamatatos, Vassilis Tangoulis, Catherine P. Raptopoulou, Aris Terzis, Giannis S. Papaefstathiou, and Spyros P. Perlepes
pp 7969 - 7971; DOI:
10.1021/ic801196u
PDF
Synthesis, X-ray Crystallographic, and NMR Characterizations of Platinum(II) and Platinum(IV) Pyrophosphato Complexes
Robert J. Mishur, Chong Zheng, Thomas M. Gilbert, and Rathindra N. Bose
pp 7972 - 7982; DOI:
10.1021/ic800237a
PDF
Theoretical Study of the Uranyl Complexation by Hydroxamic and Carboxylic Acid Groups
Béatrice Boulet, Laurent Joubert, Gérard Cote, Céline Bouvier-Capely, Catherine Cossonnet, and Carlo Adamo
pp 7983 - 7991; DOI:
10.1021/ic7018633
PDF
Spherical versus Linear Anion Encapsulation in the Cavity of a Protonated Azacryptand
I. Ravikumar, P. S. Lakshminarayanan, E. Suresh, and Pradyut Ghosh
pp 7992 - 7999; DOI:
10.1021/ic702056y
PDF
Enantiopure, Supramolecular Helices Containing Three-Dimensional Tetranuclear Lanthanide(III) Arrays: Synthesis, Structure, Properties, and Solvent-Driven Trinuclear/Tetranuclear Interconversion
Marco Lama, Olimpia Mamula, Gregg S. Kottas, Luisa De Cola, Helen Stoeckli-Evans, and Sergiu Shova
pp 8000 - 8015; DOI:
10.1021/ic7021006
PDF
New Ruthenium(II) Complexes with Enantiomerically Pure Bis- and Tris(pinene)-Fused Tridentate Ligands. Synthesis, Characterization and Stereoisomeric Analysis
Xavier Sala, Albert Poater, Alexander von Zelewsky, Teodor Parella, Xavier Fontrodona, Isabel Romero, Miquel Solà, Montserrat Rodríguez, and Antoni Llobet
pp 8016 - 8024; DOI:
10.1021/ic800252f
PDF
Acetonitrile-Vapor-Induced Color and Luminescence Changes in a Cyclometalated Heteroleptic Iridium Complex
Zhiwei Liu, Zuqiang Bian, Jiang Bian, Zhendong Li, Daobo Nie, and Chunhui Huang
pp 8025 - 8030; DOI:
10.1021/ic702141h
PDF
Synthesis, Structures, and Solution Dynamics of Palladium Complexes of Quinoline-Functionalized N-Heterocyclic Carbenes
Hong Mei Peng, Guoyong Song, Yongxin Li, and Xingwei Li
pp 8031 - 8043; DOI:
10.1021/ic800361v
PDF
Synthesis and Structures of a New Series of Silver-Vanadate Hybrid Solids and Their Optical and Photocatalytic Properties
Haisheng Lin and Paul A. Maggard
pp 8044 - 8052; DOI:
10.1021/ic8004129
PDF
Crystal Structure and Magnetic Properties of Two Isomeric Three-Dimensional Pyromellitate-Containing Cobalt(II) Complexes
Oscar Fabelo, Jorge Pasán, Laura Cañadillas-Delgado, Fernando S. Delgado, Francesc Lloret, Miguel Julve, and Catalina Ruiz-Pérez
pp 8053 - 8061; DOI:
10.1021/ic800704y
PDF
Rare-Earth Amidate Complexes. Easily Accessed Initiators For ε-Caprolactone Ring-Opening Polymerization
Louisa J. E. Stanlake, J. David Beard, and Laurel L. Schafer
pp 8062 - 8068; DOI:
10.1021/ic8010635
PDF
Vapochromic Behavior of {Ag2(Et2O)2[Au(C6F5)2]2}n with Volatile Organic Compounds
Eduardo J. Fernández, José M. López-de-Luzuriaga, Miguel Monge, M. Elena Olmos, Raquel C. Puelles, Antonio Laguna, Ahmed A. Mohamed, and John P. Fackler, Jr.
pp 8069 - 8076; DOI:
10.1021/ic800452w
PDF
CaMn1−x NbxO3 (x ≤ 0.08) Perovskite-Type Phases As Promising New High-Temperature n-Type Thermoelectric Materials
L. Bocher, M. H. Aguirre, D. Logvinovich, A. Shkabko, R. Robert, M. Trottmann, and A. Weidenkaff
pp 8077 - 8085; DOI:
10.1021/ic800463s
PDF
New Optical Supramolecular Compound Constructed from a Polyoxometalate Cluster and an Organic Substrate
Yi-Ming Xie, Qi-Sheng Zhang, Zhen-Guo Zhao, Xiao-Yuan Wu, Shan-Ci Chen, and Can-Zhong Lu
pp 8086 - 8090; DOI:
10.1021/ic800827a
PDF
One-, Two-, and Three-Dimensional Arrays of Eu3+-4,4,5,5,5-pentafluoro-1-(naphthalen-2-yl)pentane-1,3-dione complexes: Synthesis, Crystal Structure and Photophysical Properties
D. B. Ambili Raj, S. Biju, and M. L. P. Reddy
pp 8091 - 8100; DOI:
10.1021/ic8004757
PDF
Facile Synthesis and Functionality-Dependent Electrochemistry of Fe-Only Hydrogenase Mimics
Gang Si, Wen-Guang Wang, Hong-Yan Wang, Chen-Ho Tung, and Li-Zhu Wu
pp 8101 - 8111; DOI:
10.1021/ic800676y
PDF
Trinuclear {M1}CN{M2}2 Complexes (M1 = CrIII, FeIII, CoIII; M2 = CuII, NiII, MnII). Are Single Molecule Magnets Predictable?
Mihail Atanasov, Christoph Busche, Peter Comba, Fadi El Hallak, Bodo Martin, Gopalan Rajaraman, Joris van Slageren, and Hubert Wadepohl
pp 8112 - 8125; DOI:
10.1021/ic800556c
PDF
Assembly of a Cubic Nanocage Co8L12 and a Hydrogen-Bonded 3D NbO Net Based on the [(HCO3)2]2− Synthon and Water
Man-Li Cao, Hong-Guo Hao, Wei-Xiong Zhang, and Bao-Hui Ye
pp 8126 - 8133; DOI:
10.1021/ic800585d
PDF
Synthesis, Structure, and Magnetism of Three Azido-Bridged Co2+ Compounds with a Flexible Coligand 1,2-(Tetrazole-1-yl)ethane
Ru-Yin Li, Xin-Yi Wang, Tao Liu, Hong-Bin Xu, Fei Zhao, Zhe-Ming Wang, and Song Gao
pp 8134 - 8142; DOI:
10.1021/ic800570a
PDF
Anion Influence on the Structure and Magnetic Properties of a Series of Multidimensional Pyrimidine-2-carboxylato-Bridged Copper(II) Complexes
José Suárez-Varela, Antonio J. Mota, Hakima Aouryaghal, Joan Cano, A. Rodríguez-Diéguez, Dominique Luneau, and Enrique Colacio
pp 8143 - 8158; DOI:
10.1021/ic800625w
PDF
Infrared Spectra, Structure, and Bonding of the GeH3CrH, HGeMoH3, and HGeWH3 Molecules in Solid Neon and Argon
Xuefeng Wang and Lester Andrews
pp 8159 - 8166; DOI:
10.1021/ic800552s
PDF
The Alkylation Mechanism of Zinc-Bound Thiolates Depends upon the Zinc Ligands
Delphine Picot, Gilles Ohanessian, and Gilles Frison
pp 8167 - 8178; DOI:
10.1021/ic800697s
PDF
Self-Assembly of Polyoxometalate-Based Metal Organic Frameworks Based on Octamolybdates and Copper-Organic Units: from CuII, CuI,II to CuI via Changing Organic Amine
Ya-Qian Lan, Shun-Li Li, Xin-Long Wang, Kui-Zhan Shao, Dong-Ying Du, Hong-Ying Zang, and Zhong-Min Su
pp 8179 - 8187; DOI:
10.1021/ic800702d
PDF
Vibronic Effects in Cu(II)-Doped Ba2Zn(HCO2)6·4H2O
Kieran S. Hadler, James R. Kilmartin, Graeme R. Hanson, Michael A. Hitchman, Charles J. Simmons, and Mark J. Riley
pp 8188 - 8196; DOI:
10.1021/ic8007206
PDF
Cu6S4 Cluster Based Twelve-Connected Face-Centered Cubic and Cu19I4S12 Cluster Based Fourteen-Connected Body-Centered Cubic Topological Coordination Polymers
Zheng-Ming Hao, Rui-Qin Fang, Hai-Shun Wu, and Xian-Ming Zhang
pp 8197 - 8203; DOI:
10.1021/ic800709w
PDF
Synthesis, Structure, and High-Temperature Thermoelectric Properties of Boron-Doped Ba8Al14Si31 Clathrate I Phases
Cathie L. Condron, Susan M. Kauzlarich, Teruyuki Ikeda, G. Jeffrey Snyder, Frank Haarmann, and Peter Jeglič
pp 8204 - 8212; DOI:
10.1021/ic800772m
PDF
Expedient Multi-Step Synthesis of Organometallic Complexes of Tc and Re in High Effective Specific Activity. A New Platform for the Production of Molecular Imaging and Therapy Agents
Patrick W. Causey, Travis R. Besanger, Paul Schaffer, and John F. Valliant
pp 8213 - 8221; DOI:
10.1021/ic800775w
PDF
Reactions of Copper(II)-H2O2 Adducts Supported by Tridentate Bis(2-pyridylmethyl)amine Ligands: Sensitivity to Solvent and Variations in Ligand Substitution
Atsushi Kunishita, Joseph D. Scanlon, Hirohito Ishimaru, Kaoru Honda, Takashi Ogura, Masatatsu Suzuki, Christopher J. Cramer, and Shinobu Itoh
pp 8222 - 8232; DOI:
10.1021/ic800845h
PDF
Hydration Properties of Aqueous Pb(II) Ion
Matthew C. F. Wander and Aurora E. Clark
pp 8233 - 8241; DOI:
10.1021/ic800750g
PDF
Photophysical Properties of Platinum(II)−Acetylide Complexes: the Effect of a Strongly Electron-Accepting Diimine Ligand on Excited-State Structure
Christopher J. Adams, Natalie Fey, Zoë A. Harrison, Igor V. Sazanovich, Michael Towrie, and Julia A. Weinstein
pp 8242 - 8257; DOI:
10.1021/ic800850h
PDF
Disordered Structures of the TM−Mg−Zn 1/1 Quasicrystal Approximants (TM = Hf, Zr, or Ti) and Chemical Intergrowth
Cesar Pay Gómez, Satoshi Ohhashi, Akiji Yamamoto, and An Pang Tsai
pp 8258 - 8266; DOI:
10.1021/ic800874u
PDF
Nanoparticulated Silicas with Bimodal Porosity: Chemical Control of the Pore Sizes
Jamal El Haskouri, José Manuel Morales, David Ortiz de Zárate, Lorenzo Fernández, Julio Latorre, Carmen Guillem, Aurelio Beltrán, Daniel Beltrán, and Pedro Amorós
pp 8267 - 8277; DOI:
10.1021/ic800893a
PDF
Stabilization of Plutonium(III) in the Preyssler Polyoxometalate
Mark R. Antonio and Ming-Hsi Chiang
pp 8278 - 8285; DOI:
10.1021/ic8008893
PDF
Topology Analysis and Nonlinear-Optical-Active Properties of Luminescent Metal−Organic Framework Materials Based on Zinc/Lead Isophthalates
Lei Zhang, Ye-Yan Qin, Zhao-Ji Li, Qi-Pu Lin, Jian-Kai Cheng, Jian Zhang, and Yuan-Gen Yao
pp 8286 - 8293; DOI:
10.1021/ic800871r
PDF
Electrochemical and Complexation Behavior of Neptunium in Aqueous Perchlorate and Nitrate Solutions
Atsushi Ikeda-Ohno, Christoph Hennig, André Rossberg, Harald Funke, Andreas C. Scheinost, Gert Bernhard, and Tsuyoshi Yaita
pp 8294 - 8305; DOI:
10.1021/ic8009095
PDF
Decomposition of Dinuclear Manganese Complexes for the Preparation of Nanostructured Oxide Materials
Jonathan P. Hill, Humberto Palza, Sher Alam, Katsuhiko Ariga, Amy Lea Schumacher, Francis D’Souza, Christopher E. Anson, and Annie K. Powell
pp 8306 - 8314; DOI:
10.1021/ic8008915
PDF
N2-Functionalized Blue Luminescent Guanosines by 2,2′-Dipyridylamino and 2-(2′-Pyridyl)benzimidazolyl Chelate Groups and Their Interactions with Zn(II) Ions
Sanela Martić, Gang Wu, and Suning Wang
pp 8315 - 8323; DOI:
10.1021/ic800899b
PDF
Modulation of Metal Displacements in a Saddle Distorted Macrocycle: Synthesis, Structure, and Properties of High-Spin Fe(III) Porphyrins and Implications for the Hemoproteins
Ranjan Patra, Arvind Chaudhary, Sudip Kumar Ghosh, and Sankar Prasad Rath
pp 8324 - 8335; DOI:
10.1021/ic800944q
PDF
Hybrid Organic−Inorganic Framework Structures: Influence of Cation Size on Metal−Oxygen−Metal Connectivity in the Alkaline Earth Thiazolothiazoledicarboxylates
Eduardo H. L. Falcão, Naraso, Russell K. Feller, Guang Wu, Fred Wudl, and Anthony K. Cheetham
pp 8336 - 8342; DOI:
10.1021/ic8009173
PDF
Behavior of BrO3F and ClO3F Toward Strong Lewis Acids and the Characterization of [XO2][SbF6] (X = Cl, Br) by Single Crystal X-ray Diffraction, Raman Spectroscopy, and Computational Methods
John F. Lehmann, Sebastian Riedel, and Gary J. Schrobilgen
pp 8343 - 8356; DOI:
10.1021/ic800929h
PDF
Physicochemical Properties of the High-Field MRI-Relevant [Gd(DTTA-Me)(H2O)2] Complex
Loïck Moriggi, Caroline Cannizzo, Cora Prestinari, Florent Berrière, and Lothar Helm
pp 8357 - 8366; DOI:
10.1021/ic800512k
PDF
The Cyclic “Silver-Diphos” Motif [Ag2(μ-diphosphine)2]2+ as a Synthon for Building up Larger Structures
Philip W. Miller, Mark Nieuwenhuyzen, Jonathan P. H. Charmant, and Stuart L. James
pp 8367 - 8379; DOI:
10.1021/ic800664f
PDF
Hydrolytic Metal with a Hydrophobic Periphery: Titanium(IV) Complexes of Naphthalene-2,3-diolate and Interactions with Serum Albumin
Arthur D. Tinoco, Emily V. Eames, Christopher D. Incarvito, and Ann M. Valentine
pp 8380 - 8390; DOI:
10.1021/ic800529v
PDF
Interaction of Mixed-Donor Macrocycles Containing the 1,10-Phenanthroline Subunit with Selected Transition and Post-Transition Metal Ions: Metal Ion Recognition in Competitive Liquid−Liquid Solvent Extraction of CuII, ZnII, PbII, CdII, AgI, and HgII
M. Carla Aragoni, Massimiliano Arca, Andrea Bencini, Silvia Biagini, Alexander J. Blake, Claudia Caltagirone, Francesco Demartin, Greta De Filippo, Francesco A. Devillanova, Alessandra Garau, Karsten Gloe, Francesco Isaia, Vito Lippolis, Barbara Valtancoli, and Marco Wenzel
pp 8391 - 8404; DOI:
10.1021/ic800548p
PDF
Electron-Transfer Reactions of Nitrosyl and Superoxo Metal Complexes
Wenjing Song, Arkady Ellern, and Andreja Bakac
pp 8405 - 8411; DOI:
10.1021/ic800867j
PDF
Low-Valent Molecular Plutonium Halide Complexes
Andrew J. Gaunt, Sean D. Reilly, Alejandro E. Enriquez, Trevor W. Hayton, James M. Boncella, Brian L. Scott, and Mary P. Neu
pp 8412 - 8419; DOI:
10.1021/ic8009139
PDF
Complex Phosphorus Thermochemistry. Volume-Based Thermodynamics and the Estimation of Standard Enthalpies of Formation of Gas phase Ions: Δf(PCl4+, g) and Δf(PCl6, g)
H. Donald Brooke Jenkins
pp 8420 - 8425; DOI:
10.1021/ic800990k
PDF
Exchange Interactions and Electron Delocalization in the Mixed-Valence Cluster V4IVV2VO7(OC2H5)12
Maria A. Augustyniak-Jabłokow, Charles Daniel, Hans Hartl, Johann Spandl, and Yurii V. Yablokov
pp 8426 - 8426; DOI:
10.1021/ic801466e
PDF

Issue 19


Preface: Overview of the Forum on Functional Inorganic Materials
P. Shiv Halasyamani and Kenneth R. Poeppelmeier
pp 8427 - 8428; DOI:
10.1021/ic801375s
PDF
Recent Progress in Oxide Thermoelectric Materials: p-Type Ca3Co4O9 and n-Type SrTiO3
Hiromichi Ohta, Kenji Sugiura, and Kunihito Koumoto
pp 8429 - 8436; DOI:
10.1021/ic800644x
PDF
Optical Properties of Cation-Substituted Zinc Oxide
Young-Il Kim and Ram Seshadri
pp 8437 - 8443; DOI:
10.1021/ic800916a
PDF
Isolation of Two-Dimensional 2:1 Cation-Ordered Perovskite Units by Anion Vacancy Ordering in Ba6Na2Nb2P2O17
Xiaojun Kuang, John B. Claridge, Tim Price, David M. Iddles, and Matthew J. Rosseinsky
pp 8444 - 8450; DOI:
10.1021/ic800788e
PDF
Role of Temperature and Time in the Formation of Infinite −M−O−M− Linkages and Isolated Clusters in MOFs: A Few Illustrative Examples
Partha Mahata, Manikanda Prabu, and Srinivasan Natarajan
pp 8451 - 8463; DOI:
10.1021/ic800621q
PDF
Ag4V2O6F2 (SVOF): A High Silver Density Phase and Potential New Cathode Material for Implantable Cardioverter Defibrillators
Frédéric Sauvage, Vincent Bodenez, Hervé Vezin, Thomas A. Albrecht, Jean-Marie Tarascon, and Kenneth R. Poeppelmeier
pp 8464 - 8472; DOI:
10.1021/ic800793e
PDF
Structures, Physical Properties, and Chemistry of Layered Oxychalcogenides and Oxypnictides
Simon J. Clarke, Paul Adamson, Sebastian J. C. Herkelrath, Oliver J. Rutt, Dinah R. Parker, Michael J. Pitcher, and Catherine F. Smura
pp 8473 - 8486; DOI:
10.1021/ic8009964
PDF
Status of Trivalent Copper and Charge-Transfer Excitons in High-TC Cuprates
Michel Pouchard, Jean-Pierre Doumerc, and Antoine Villesuzanne
pp 8487 - 8497; DOI:
10.1021/ic801031y
PDF
Structures and Properties of Functional Metal Selenites and Tellurites
Jiang-Gao Mao, Hai-Long Jiang, and Fang Kong
pp 8498 - 8510; DOI:
10.1021/ic8005629
PDF
Polar Hexagonal Tungsten Bronze-Type Oxides: KNbW2O9, RbNbW2O9, and KTaW2O9
H. Y. Chang, T. Sivakumar, K. M. Ok, and P. Shiv Halasyamani
pp 8511 - 8517; DOI:
10.1021/ic800573k
PDF
Synthetic Approaches for Noncentrosymmetric Molybdates
Desmond J. Hubbard, Alexander R. Johnston, Hernan Sanchez Casalongue, Amy Narducci Sarjeant, and Alexander J. Norquist
pp 8518 - 8525; DOI:
10.1021/ic800572g
PDF
Increasing the Structural Complexity of Chromium(IV) Oxides by High-Pressure and High-Temperature Reactions of CrO2
E. Castillo-Martínez, A. M. Arévalo-López, R. Ruiz-Bustos, and M. A. Alario-Franco
pp 8526 - 8542; DOI:
10.1021/ic801015b
PDF
Target-Aimed Synthesis of Anion-Deficient Perovskites
Evgeny V. Antipov, Artem M. Abakumov, and Sergey Ya. Istomin
pp 8543 - 8552; DOI:
10.1021/ic800791s
PDF
Transition-Metal Oxides with Triangular Lattices: Generation of New Magnetic and Electronic Properties
A. Maignan, W. Kobayashi, S. Hébert, G. Martinet, D. Pelloquin, N. Bellido, and Ch. Simon
pp 8553 - 8561; DOI:
10.1021/ic8006926
PDF
A-Site-Ordered Perovskites with Intriguing Physical Properties
Yuichi Shimakawa
pp 8562 - 8570; DOI:
10.1021/ic800696u
PDF
Use of YbIII-Centered Near-Infrared (NIR) Luminescence To Determine the Hydration State of a 3,2-HOPO-Based MRI Contrast Agent
Evan G. Moore, Michael Seitz, and Kenneth N. Raymond
pp 8571 - 8573; DOI:
10.1021/ic801060x
PDF
Cyclic Ti9 Keggin Trimers with Tetrahedral (PO4) or Octahedral (TiO6) Capping Groups
Ghada A. Al-Kadamany, Firasat Hussain, Sib Sankar Mal, Michael H. Dickman, Nathalie Leclerc-Laronze, Jérôme Marrot, Emmanuel Cadot, and Ulrich Kortz
pp 8574 - 8576; DOI:
10.1021/ic801114n
PDF
Low-Valent Uranium Iodides: Straightforward Solution Syntheses of UI3 and UI4 Etherates
Christopher D. Carmichael, Natalie A. Jones, and Polly L. Arnold
pp 8577 - 8579; DOI:
10.1021/ic801138e
PDF
Crystallographic Characterizations and New High-Yield Synthetic Routes for the Complete Series of 6-X-B10H13 Halodecaboranes (X = F, Cl, Br, I) via Superacid-Induced Cage-Opening Reactions of closo-B10H102−
William C. Ewing, Patrick J. Carroll, and Larry G. Sneddon
pp 8580 - 8582; DOI:
10.1021/ic801288e
PDF
Iridium-Catalyzed Dehydrogenation of Substituted Amine Boranes: Kinetics, Thermodynamics, and Implications for Hydrogen Storage
Brandon L. Dietrich, Karen I. Goldberg, D. Michael Heinekey, Tom Autrey, and John C. Linehan
pp 8583 - 8585; DOI:
10.1021/ic801161g
PDF
Cationic Main-Group Metal Chalcogenide with a 1-D Polymeric Structure, [{In(dien)}2(InTe4)]·Cl
Chun-Ying Li, Xiao-Xia Chen, Jian Zhou, Qin-Yu Zhu, Zhi-Xin Lei, Yong Zhang, and Jie Dai
pp 8586 - 8588; DOI:
10.1021/ic801121q
PDF
Selective Cytotoxic Ru(II) Arene Cp* Complex Salts [R-PhRuCp*]+X for X = BF4, PF6, and BPh4
Bradley T. Loughrey, Peter C. Healy, Peter G. Parsons, and Michael L. Williams
pp 8589 - 8591; DOI:
10.1021/ic801159f
PDF
AgI Bimetallic Molecular Clips with Adaptive Coordination Behavior for Supramolecular Chemistry
Stefan Welsch, Christophe Lescop, Manfred Scheer, and Régis Réau
pp 8592 - 8594; DOI:
10.1021/ic801222j
PDF
Reactivity of Pt0 Complexes toward Gallium(III) Halides: Synthesis of a Platinum Gallane Complex and Oxidative Addition of Gallium Halides to Pt0
Holger Braunschweig, Katrin Gruss, and Krzysztof Radacki
pp 8595 - 8597; DOI:
10.1021/ic801293e
PDF
Formation of a Coordinated 2-Aminoethylidene Ligand and Its Rearrangement by Deprotonation into a Phosphinoallyl Ligand Containing a Pyrrolidin-2-yl Ring
M. Carmen Puerta, Pedro Valerga, and M. Dolores Palacios
pp 8598 - 8600; DOI:
10.1021/ic801302z
PDF
Bonding Mode of a Bifunctional P∼Si−H Ligand in the Ruthenium Complex “Ru(PPh2CH2OSiMe2H)3
Virginia Montiel-Palma, Olivier Piechaczyk, Alexandre Picot, Audrey Auffrant, Laure Vendier, Pascal Le Floch, and Sylviane Sabo-Etienne
pp 8601 - 8603; DOI:
10.1021/ic801327a
PDF
Coordination-Tuned Single-Molecule-Magnet Behavior of TbIII−CuII Dinuclear Systems
Takashi Kajiwara, Motohiro Nakano, Shinya Takaishi, and Masahiro Yamashita
pp 8604 - 8606; DOI:
10.1021/ic8013656
PDF
Cooperative Self-Assembly of Chiral L-Malate and Achiral Succinate in the Formation of a Three-Dimensional Homochiral Framework
Areg Zingiryan, Jian Zhang, and Xianhui Bu
pp 8607 - 8609; DOI:
10.1021/ic801404p
PDF
Single-Molecule-Magnet Behavior and Spin Changes Affected by Crystal Packing Effects
Patrick L. Feng, Changhyun Koo, John J. Henderson, Motohiro Nakano, Stephen Hill, Enrique del Barco, and David N. Hendrickson
pp 8610 - 8612; DOI:
10.1021/ic801208z
PDF
In Situ Crystallography of KHSO4: Probing the Kinetic Pathway for the Evolution of a Pyrolysis Reaction in the Crystalline State
Diptikanta Swain and Tayur N. Guru Row
pp 8613 - 8615; DOI:
10.1021/ic801426f
PDF
C3 Vanadium(V) Amine Triphenolate Complexes: Vanadium Haloperoxidase Structural and Functional Models
Miriam Mba, Marta Pontini, Silvia Lovat, Cristiano Zonta, Gerald Bernardinelli, Peter E. Kündig, and Giulia Licini
pp 8616 - 8618; DOI:
10.1021/ic8015113
PDF
Scandium Sulfate Complexation in Aqueous Solution by Dielectric Relaxation Spectroscopy
Simon Schrödle, Wolfgang Wachter, Richard Buchner, and Glenn Hefter
pp 8619 - 8628; DOI:
10.1021/ic702396r
PDF
Exploiting Soft and Hard X-Ray Absorption Spectroscopy to Characterize Metallodrug/Protein Interactions: the Binding of [trans-RuCl4(Im)(dimethylsulfoxide)][ImH] (Im = imidazole) to Bovine Serum Albumin
Isabella Ascone, Luigi Messori, Angela Casini, Chiara Gabbiani, Antonella Balerna, Francesca Dell’Unto, and Agostina Congiu Castellano
pp 8629 - 8634; DOI:
10.1021/ic8001477
PDF
Mechanisms of the Water−Gas-Shift Reaction by Iron Pentacarbonyl in the Gas Phase
Xavier Rozanska and Rodolphe Vuilleumier
pp 8635 - 8640; DOI:
10.1021/ic8001866
PDF
Synthesis, X-Ray Crystal Structures, and Phosphate Ester Cleavage Properties of bis(2-Pyridylmethyl)amine Copper(II) Complexes with Guanidinium Pendant Groups
Matthew J. Belousoff, Linda Tjioe, Bim Graham, and Leone Spiccia
pp 8641 - 8651; DOI:
10.1021/ic8004079
PDF
Multi-Dimensional Transition-Metal Coordination Polymers of 4,4′-Bipyridine-N,N′-dioxide: 1D Chains and 2D Sheets
Junhua Jia, Alexander J. Blake, Neil R. Champness, Peter Hubberstey, Claire Wilson, and Martin Schröder
pp 8652 - 8664; DOI:
10.1021/ic800422g
PDF
Highly Fluorescent Group 13 Metal Complexes With Cyclic, Aromatic Hydroxamic Acid Ligands
Michael Seitz, Evan G. Moore, and Kenneth N. Raymond
pp 8665 - 8673; DOI:
10.1021/ic800269w
PDF
Investigation of Layered Double Hydroxides Intercalated by Oxomolybdenum Catecholate Complexes
Bernardo Monteiro, Sandra Gago, Filipe A. Almeida Paz, Robert Bilsborrow, Isabel S. Gonçalves, and Martyn Pillinger
pp 8674 - 8686; DOI:
10.1021/ic800420a
PDF
Mössbauer, Electron Paramagnetic Resonance, and Theoretical Study of a High-Spin, Four-Coordinate Fe(II) Diketiminate Complex
Sebastian A. Stoian, Jeremy M. Smith, Patrick L. Holland, Eckard Münck, and Emile L. Bominaar
pp 8687 - 8695; DOI:
10.1021/ic8004568
PDF
Influence of Ligand Polarizability on the Reversible Binding of O2 by trans-[Rh(X)(XNC)(PPh3)2] (X = Cl, Br, SC6F5, C2Ph; XNC = Xylyl Isocyanide). Structures and a Kinetic Study
Laurence Carlton, Lebohang V. Mokoena, and Manuel A. Fernandes
pp 8696 - 8703; DOI:
10.1021/ic800478g
PDF
Synthesis and Characterization of Two Intensely Colored Tris(benzoylcyanoxime)iron(II) Anionic Complexes
Travis Owen, Fernande Grandjean, Gary J. Long, Konstantin V. Domasevitch, and Nikolay Gerasimchuk
pp 8704 - 8713; DOI:
10.1021/ic8004322
PDF
Formations of Mixed-Valence OxovanadiumV,IV Citrates and Homocitrate with N-Heterocycle Chelated Ligand
Can-Yu Chen, Zhao-Hui Zhou, Hong-Bin Chen, Pei-Qiang Huang, Khi-Rui Tsai, and Yuan L. Chow
pp 8714 - 8720; DOI:
10.1021/ic800553p
PDF
Coordination Polymers Based on Aluminum(III) Porphyrins
Gregory J. E. Davidson, Laura A. Lane, Paul R. Raithby, John E. Warren, Carol V. Robinson, and Jeremy K. M. Sanders
pp 8721 - 8726; DOI:
10.1021/ic800587y
PDF
Synthesis, Characterization, and Reactivity of Rhodium(I) Acetylacetonato Complexes Containing Pyridinecarboxaldimine Ligands
Diane A. Kanas, Stephen J. Geier, Christopher M. Vogels, Andreas Decken, and Stephen A. Westcott
pp 8727 - 8735; DOI:
10.1021/ic800703n
PDF
Copper−Hydroperoxo-Mediated N-Debenzylation Chemistry Mimicking Aspects of Copper Monooxygenases
Debabrata Maiti, Amy A. Narducci Sarjeant, and Kenneth D. Karlin
pp 8736 - 8747; DOI:
10.1021/ic800617m
PDF
Template Synthesis of Lanthanide (Pr, Nd, Gd) Coordination Polymers with 2-Hydroxynicotinic Acid Exhibiting Ferro-/Antiferromagnetic Interaction
Na Xu, Wei Shi, Dai-Zheng Liao, Shi-Ping Yan, and Peng Cheng
pp 8748 - 8756; DOI:
10.1021/ic800623v
PDF
Tetra-2,3-pyrazinoporphyrazines with Externally Appended Pyridine Rings. 6. Chemical and Redox Properties and Highly Effective Photosensitizing Activity for Singlet Oxygen Production of Penta- and Monopalladated Complexes in Dimethylformamide Solution
Maria Pia Donzello, Elisa Viola, Costanza Bergami, Danilo Dini, Claudio Ercolani, Mauro Giustini, Karl M. Kadish, Moreno Meneghetti, Fabrizio Monacelli, Angela Rosa, and Giampaolo Ricciardi
pp 8757 - 8766; DOI:
10.1021/ic800678m
PDF
Synthesis of Binuclear Platinum Complexes Containing the Ligands 8-Naphthyridine, 2-Aminopyridine, and 7-Azaindolate. An Experimental Study of the Steric Hindrance of the Bulky Pentafluorophenyl Ligands in the Synthesis of Binuclear Complexes
José M. Casas, Beatriz E. Diosdado, Juan Forniés, Antonio Martín, Angel J. Rueda, and A. Guy Orpen
pp 8767 - 8775; DOI:
10.1021/ic8006475
PDF
Reduction of an η2-Iminoacyl Ligand to η2-Iminium Enabled by Adjacent Carbon Monoxide Ligand Replacement with a Variable Electron Donor Alkyne Ligand in a Cationic Tungsten(II) Bis(acetylacetonate) Complex
Andrew B. Jackson, Chetna Khosla, Peter S. White, and Joseph L. Templeton
pp 8776 - 8787; DOI:
10.1021/ic800738a
PDF
Formation of Intramolecular Rings in Ferramonocarbollide Complexes
Andreas Franken, Bruce E. Hodson, Thomas D. McGrath, and F. Gordon A. Stone
pp 8788 - 8797; DOI:
10.1021/ic800780w
PDF
Phenyltin-Substituted 9-Tungstogermanate and Comparison with Its Tungstosilicate Analogue
Santiago Reinoso, Michael H. Dickman, Antonia Praetorius, Luis Fernando Piedra-Garza, and Ulrich Kortz
pp 8798 - 8806; DOI:
10.1021/ic800852d
PDF
Novel 48-Membered Hexadecanuclear and 60-Membered Icosanuclear Manganese Metallamacrocycles
Wenlong Liu, Kyungjin Lee, Mira Park, Rohith P. John, Dohyun Moon, Yang Zou, Xinfang Liu, Hyeong-Cheol Ri, Ghyung Hwa Kim, and Myoung Soo Lah
pp 8807 - 8812; DOI:
10.1021/ic800708z
PDF
Synthesis, Structure, and Spectroscopic Properties of Chiral Oxorhenium(V) Complexes Incorporating Polydentate Ligands Derived from L-Amino Acids: A Density Functional Theory/Time-Dependent Density Functional Theory Investigation
Sucharita Basak and Kajal Krishna Rajak
pp 8813 - 8822; DOI:
10.1021/ic800764n
PDF
The Boron Connection: A Parallel Description of Aromatic, Bonding, and Structural Characteristics of Hydrogenated Silicon−Carbon Clusters and Isovalent Carboranes
Aristides D. Zdetsis
pp 8823 - 8829; DOI:
10.1021/ic800838b
PDF
Hetero-Bimetallic Complexes Involving Vanadium(V) and Rhenium(VII) Centers, Connected by Unsupported μ-Oxido Bridge: Synthesis, Characterization, and Redox Study
Pabitra Baran Chatterjee, Sk Md Towsif Abtab, Kisholoy Bhattacharya, Akira Endo, Elizabeth J. Shotton, Simon J. Teat, and Muktimoy Chaudhury
pp 8830 - 8838; DOI:
10.1021/ic800815p
PDF
Nature of Catalytic Activities of CoO Nanocrystals in Thermal Decomposition of Ammonium Perchlorate
Liping Li, Xuefei Sun, Xiaoqing Qiu, Jiaoxing Xu, and Guangshe Li
pp 8839 - 8846; DOI:
10.1021/ic8008283
PDF
Electroreduction of the Ruthenium Complex [(bpy)2Ru(tatpp)]Cl2 in Water: Insights on the Mechanism of Multielectron Reduction and Protonation of the Tatpp Acceptor Ligand as a Function of pH
Norma R. de Tacconi, Reynaldo O. Lezna, Rungano Chitakunye, and Frederick M. MacDonnell
pp 8847 - 8858; DOI:
10.1021/ic8009157
PDF
Magneto-Structure Relationship in Copper(II) and Nickel(II) Complexes Chelated with Stable tert-Butyl 5-Phenyl-2-pyridyl Nitroxide and Related Radicals
Atsushi Okazawa, Yasunori Nagaichi, Takashi Nogami, and Takayuki Ishida
pp 8859 - 8868; DOI:
10.1021/ic800937n
PDF
Sandwich-Type Tetranuclear Lanthanide Complexes with Cucurbit[6]uril: From Molecular Compounds to Coordination Polymers
Olga A. Gerasko, Ekaterina A. Mainicheva, Marina I. Naumova, Marco Neumaier, Manfred M. Kappes, Sergey Lebedkin, Dieter Fenske, and Vladimir P. Fedin
pp 8869 - 8880; DOI:
10.1021/ic8008317
PDF
In Situ Observation of the Formation of Si Clathrate Ba8Si46 at High Pressures and High Temperatures
Motoharu Imai and Takumi Kikegawa
pp 8881 - 8883; DOI:
10.1021/ic800895g
PDF
Hydrogen Bonding Influence of 1,10-Phenanthroline on Five-Coordinate High-Spin Imidazole-Ligated Iron(II) Porphyrinates
Chuanjiang Hu, Bruce C. Noll, Charles E. Schulz, and W. Robert Scheidt
pp 8884 - 8895; DOI:
10.1021/ic8009496
PDF
Synthesis, Structure and Magnetic Behavior of Five-Coordinate Bis(iminopyrrolyl) Complexes of Cobalt(II) containing PMe3 and THF Ligands
Sónia A. Carabineiro, Ronan M. Bellabarba, Pedro T. Gomes, Sofia I. Pascu, Luís F. Veiros, Cristina Freire, Laura C. J. Pereira, Rui T. Henriques, M. Conceição Oliveira, and John E. Warren
pp 8896 - 8911; DOI:
10.1021/ic800992f
PDF
Syntheses, Characterization, and Photochromic Studies of Spirooxazine-Containing 2,2′-Bipyridine Ligands and Their Zinc(II) Thiolate Complexes
Zhihong Bao, Ka-Yuen Ng, Vivian Wing-Wah Yam, Chi-Chiu Ko, Nianyong Zhu, and Lixin Wu
pp 8912 - 8920; DOI:
10.1021/ic8009755
PDF
The Key Role of the Intermolecular π−π Interactions in the Presence of Spin Crossover in Neutral [Fe(abpt)2A2] Complexes (A = Terminal Monoanion N Ligand)
Gaelle Dupouy, Mathieu Marchivie, Smail Triki, Jean Sala-Pala, Jean-Yves Salaün, Carlos J. Gómez-García, and Philippe Guionneau
pp 8921 - 8931; DOI:
10.1021/ic800955r
PDF
Linking Number Analysis of a Pentadecanuclear Metallamacrocycle: A Möbius-Craig System Revealed
Henry S. Rzepa
pp 8932 - 8934; DOI:
10.1021/ic800987f
PDF
Novel 3-D PtS-like Tetrazolate-Bridged Manganese(II) Complex Exhibiting Spin-Canted Antiferromagnetism and Field-Induced Spin-Flop Transition
Ying-Bing Lu, Ming-Sheng Wang, Wei-Wei Zhou, Gang Xu, Guo-Cong Guo, and Jin-Shun Huang
pp 8935 - 8942; DOI:
10.1021/ic801026y
PDF
Ligand-Derived Oxidase Activity. Catalytic Aerial Oxidation of Alcohols (Including Methanol) by Cu(II)-Diradical Complexes
Chandan Mukherjee, Ulrich Pieper, Eberhard Bothe, Vinzenz Bachler, Eckhard Bill, Thomas Weyhermüller, and Phalguni Chaudhuri
pp 8943 - 8956; DOI:
10.1021/ic8009767
PDF
Anion-Dependent Self-Assembly of Silver(I) and Diaminotriazines to Coordination Polymers: Non-Covalent Bonds and Role Interchange between Silver and Hydrogen Bonds
Blanca R. Manzano, Félix A. Jalón, M. Laura Soriano, M. Carmen Carrión, M. Pilar Carranza, Kurt Mereiter, Ana M. Rodríguez, Antonio de la Hoz, and Ana Sánchez-Migallón
pp 8957 - 8971; DOI:
10.1021/ic800997d
PDF
Transformation of Proton-Conducting Perovskite-Type into Fluorite-Type Fast Oxide Ion Electrolytes Using a CO2 Capture Technique and Their Electrical Properties
Francesca Trobec and Venkataraman Thangadurai
pp 8972 - 8984; DOI:
10.1021/ic8010025
PDF
Flux Synthesis, Crystal Structures, and Luminescence Properties of Salt-Inclusion Lanthanide Silicates: [K9F2][Ln3Si12O32] (Ln = Sm, Eu, Gd)
Ming-Feng Tang, Pei-Yun Chiang, Yu-Han Su, Yu-Chi Jung, Guang-Yi Hou, Bor-Chen Chang, and Kwang-Hwa Lii
pp 8985 - 8989; DOI:
10.1021/ic801007k
PDF
Functionalization of Aminophosphanes: Synthesis and X-Ray Crystal Structure of Novel Dilithium and Trilithium Complexes Containing Silicon-Fused Heteronuclear SiN2PLi Five-Membered Rings
Anukul Jana, Gerald Schwab, Herbert W. Roesky, and Dietmar Stalke
pp 8990 - 8994; DOI:
10.1021/ic800995h
PDF
Nanoscale Ru(0) Particles: Arene Hydrogenation Catalysts in Imidazolium Ionic Liquids
Martin H. G. Prechtl, Morgana Scariot, Jackson D. Scholten, Giovanna Machado, Sérgio R. Teixeira, and Jairton Dupont
pp 8995 - 9001; DOI:
10.1021/ic801014f
PDF
Influence of the Metal Orbital Occupancy and Principal Quantum Number on Organoazide (RN3) Conversion to Transition-Metal Imide Complexes
Amy N. Walstrom, Benjamin C. Fullmer, Hongjun Fan, Maren Pink, Drew T. Buschhorn, and Kenneth G. Caulton
pp 9002 - 9009; DOI:
10.1021/ic801035z
PDF
Solution Behavior and Structural Properties of Cu(I) Complexes Featuring m-Terphenyl Isocyanides
Brian J. Fox, Queena Y. Sun, Antonio G. DiPasquale, Alexander R. Fox, Arnold L. Rheingold, and Joshua S. Figueroa
pp 9010 - 9020; DOI:
10.1021/ic8010986
PDF
High-Yield Syntheses and Reactivity Studies of Fe10 “Ferric Wheels”: Structural, Magnetic, and Computational Characterization of a Star-Shaped Fe8 Complex
Theocharis C. Stamatatos, Alexander G. Christou, Shreya Mukherjee, Katye M. Poole, Christos Lampropoulos, Khalil A. Abboud, Ted A. O’Brien, and George Christou
pp 9021 - 9034; DOI:
10.1021/ic801038r
PDF
A New Approach for the Detection of Ethylene Using Silica-Supported Palladium Complexes
Patricia Cabanillas-Galán, Linda Farmer, Terence Hagan, Mark Nieuwenhuyzen, Stuart L. James, and M. Cristina Lagunas
pp 9035 - 9041; DOI:
10.1021/ic800986t
PDF
Comparisons between Yttrium and Titanium N-Heterocyclic Carbene Complexes in the Search for Early Transition Metal NHC Backbonding Interactions
Polly L. Arnold, Sergey Zlatogorsky, Natalie A. Jones, Christopher D. Carmichael, Stephen T. Liddle, Alexander J. Blake, and Claire Wilson
pp 9042 - 9049; DOI:
10.1021/ic801046u
PDF
[H2bipy]2[(UO2)6Zn2(PO3OH)4(PO4)4]·H2O: An Open-Framework Uranyl Zinc Phosphate Templated by Diprotonated 4,4′-Bipyridyl
Yaqin Yu, Wei Zhan, and Thomas E. Albrecht-Schmitt
pp 9050 - 9054; DOI:
10.1021/ic801125w
PDF
Near-Infrared Luminescence of Nine-Coordinate Neodymium Complexes with Benzimidazole-Substituted 8-Hydroxyquinolines
Nail M. Shavaleev, Rosario Scopelliti, Frédéric Gumy, and Jean-Claude G. Bünzli
pp 9055 - 9068; DOI:
10.1021/ic8010585
PDF
Unsymmetrical Platinum(II) Phosphido Derivatives: Oxidation and Reductive Coupling Processes Involving Platinum(III) Complexes as Intermediates
Irene Ara, Juan Forniés, Consuelo Fortuño, Susana Ibáñez, Antonio Martín, Piero Mastrorilli, and Vito Gallo
pp 9069 - 9080; DOI:
10.1021/ic8011124
PDF
Electron Tunneling through Oligo-p-xylene Bridges
David Hanss and Oliver S. Wenger
pp 9081 - 9084; DOI:
10.1021/ic801203n
PDF
Synthesis and Characterization of Bis[bis(pentafluoroethyl)phosphinyl]imides, M+N[(C2F5)2P(O)]2, M = H, Na, K, Cs, Ag, Me4N
Dana Bejan, Helge Willner, Nikolai Ignatiev, and Christian W. Lehmann
pp 9085 - 9089; DOI:
10.1021/ic801088q
PDF
Rhodium Nanocatalysts Stabilized by Various Bipyridine Ligands in Nonaqueous Ionic Liquids: Influence of the Bipyridine Coordination Modes in Arene Catalytic Hydrogenation
Bastien Léger, Audrey Denicourt-Nowicki, Hélène Olivier-Bourbigou, and Alain Roucoux
pp 9090 - 9096; DOI:
10.1021/ic8010713
PDF
Hydrothermal Synthesis of Vanadium Oxyfluoride Chains Incorporating Covalently Bound Copper Coordination Complexes
Thushitha Mahenthirarajah, Yang Li, and Philip Lightfoot
pp 9097 - 9102; DOI:
10.1021/ic801106h
PDF
Spontaneous Magnetization in Ni−Al and Ni−Fe Layered Double Hydroxides
Eugenio Coronado, José R. Galán-Mascarós, Carlos Martí-Gastaldo, Antonio Ribera, Elías Palacios, Miguel Castro, and Ramón Burriel
pp 9103 - 9110; DOI:
10.1021/ic801123v
PDF
Insertion of a Spin Crossover FeIII Complex into an Oxalate-Based Layered Material: Coexistence of Spin Canting and Spin Crossover in a Hybrid Magnet
Miguel Clemente-León, Eugeno Coronado, M. Carmen Giménez-López, Alejandra Soriano-Portillo, João C. Waerenborgh, Fernando S. Delgado, and Catalina Ruiz-Pérez
pp 9111 - 9120; DOI:
10.1021/ic801165b
PDF

Issue 20


CuII-Mediated Synthesis of a New Fluorescent Pyrido[1,2-a]quinoxalin-11-ium Derivative
Rik Rani Koner and Manabendra Ray
pp 9122 - 9124; DOI:
10.1021/ic8008464
PDF
Reactions of Ruthenium Complexes Having Pyridyl-Containing Ligands, 2-Pyridinecarboxylato and 2,2′-Bipyridine, with an Azide Ion: Formation of Nitrido-Bridged Diruthenium Complexes
Sayuri Matsumura, Kazunori Shikano, Takao Oi, Noriyuki Suzuki, and Hirotaka Nagao
pp 9125 - 9127; DOI:
10.1021/ic801070a
PDF
A Conducting Coordination Polymer Based on Assembled Cu9 Cages
Salomé Delgado, Pablo J. Sanz Miguel, José L. Priego, Reyes Jiménez-Aparicio, Carlos J. Gómez-García, and Félix Zamora
pp 9128 - 9130; DOI:
10.1021/ic801314s
PDF
Tuning Emission Properties of Iridium and Ruthenium Metallosurfactants in Micellar Systems
Andrés Guerrero-Martínez, Yolanda Vida, David Domínguez-Gutiérrez, Rodrigo Q. Albuquerque, and Luisa De Cola
pp 9131 - 9133; DOI:
10.1021/ic800849y
PDF
Preparation, Separation, and Characterization of Ruthenium(II) Thiocyanate Linkage Isomers
Lucas Vandenburgh, Matthew R. Buck, and Daniel A. Freedman
pp 9134 - 9136; DOI:
10.1021/ic801194j
PDF
Sorting the Assemblies of Unsymmetrically Covalently Functionalized Mn-Anderson Polyoxometalate Clusters with Mass Spectrometry
Yu-Fei Song, De-Liang Long, Stephanie E. Kelly, and Leroy Cronin
pp 9137 - 9139; DOI:
10.1021/ic801366r
PDF
GaCl3-Assisted Cyclization Reactions in Hypersilyl(trimethylsilyl)aminodichlorophosphine
Alexander Villinger, Andrea Westenkirchner, Ronald Wustrack, and Axel Schulz
pp 9140 - 9142; DOI:
10.1021/ic801501c
PDF
Concurrent Sensing of Benzene and Oxygen by a Crystalline Salt of Tris(5,6-dimethyl-1,10-phenanthroline)ruthenium(II)
Kari A. McGee, Brian J. Marquardt, and Kent R. Mann
pp 9143 - 9145; DOI:
10.1021/ic801287p
PDF
A Heterometallic, Heterovalent CuI/SnII/IV/S Cluster with an Unprecedented Cu4Sn Core and Stannacyclopentane Units
Hari Pada Nayek, Werner Massa, and Stefanie Dehnen
pp 9146 - 9148; DOI:
10.1021/ic8013877
PDF
Near-Quantitative Internal Quantum Efficiency in a Light-Emitting Electrochemical Cell
Henk J. Bolink, Eugenio Coronado, Rubén D. Costa, Nora Lardiés, and Enrique Ortí
pp 9149 - 9151; DOI:
10.1021/ic801587n
PDF
Co(C2O4)(HO(CH2)3OH): An Antiferromagnetic Neutral Zigzag Chain Compound Showing Long-Range Ordering of Spin Canting
Zhiming Duan, Yan Zhang, Bin Zhang, and Daoben Zhu
pp 9152 - 9154; DOI:
10.1021/ic801544r
PDF
Isocyanide Ligands Adsorbed on Metal Surfaces: Applications in Catalysis, Nanochemistry, and Molecular Electronics
Robert J. Angelici and Mihaela Lazar
pp 9155 - 9165; DOI:
10.1021/ic800513t
PDF
Primary and Secondary Phosphine Complexes of Iron Porphyrins and Ruthenium Phthalocyanine: Synthesis, Structure, and P−H Bond Functionalization
Jie-Sheng Huang, Guang-Ao Yu, Jin Xie, Kwok-Ming Wong, Nianyong Zhu, and Chi-Ming Che
pp 9166 - 9181; DOI:
10.1021/ic800484k
PDF
Metal−Metal Communication in Copper(II) Complexes of Cyclotetraphosphazene Ligands
Eric W. Ainscough, Andrew M. Brodie, Ross J. Davidson, Boujemaa Moubaraki, Keith S. Murray, Carl A. Otter, and Mark R. Waterland
pp 9182 - 9192; DOI:
10.1021/ic8008706
PDF
Ionic-Liquid-Promoted Decaborane Dehydrogenative Alkyne-Insertion Reactions: A New Route to o-Carboranes
Yuqi Li, Patrick J. Carroll, and Larry G. Sneddon
pp 9193 - 9202; DOI:
10.1021/ic800999y
PDF
Ionic-Liquid-Promoted Decaborane Olefin-Hydroboration: A New Efficient Route to 6-R-B10H13 Derivatives
Upal Kusari, Patrick J. Carroll, and Larry G. Sneddon
pp 9203 - 9215; DOI:
10.1021/ic801000c
PDF
Computational Studies of the Reactions of B10H13 with Alkynes and Olefins: Pathways for Dehydrogenative Alkyne-Insertion and Olefin-Hydroboration Reactions
Chang Won Yoon, Upal Kusari, and Larry G. Sneddon
pp 9216 - 9227; DOI:
10.1021/ic8010019
PDF
Theoretical Studies on the Redox Potentials of Fe Dinuclear Complexes as Models for Hydrogenase
Lindsay E. Roy, Enrique R. Batista, and P. Jeffrey Hay
pp 9228 - 9237; DOI:
10.1021/ic800541w
PDF
Syntheses, X-ray Structures, Solid State High-Field Electron Paramagnetic Resonance, and Density-Functional Theory Investigations on Chloro and Aqua MnII Mononuclear Complexes with Amino-Pyridine Pentadentate Ligands
Christelle Hureau, Sihem Groni, Régis Guillot, Geneviève Blondin, Carole Duboc, and Elodie Anxolabéhère-Mallart
pp 9238 - 9247; DOI:
10.1021/ic800551u
PDF
Dimolybdenum Bis-2,4,6-triisopropyl-benzoate Bis-4-isonicotinate: A Redox Active Analogue of 4,4′-Bipyridine with Ambivalent Properties
Malcolm H. Chisholm, Angela S. Dann, Fabian Dielmann, Judith C. Gallucci, Nathan J. Patmore, Ramkrishna Ramnauth, and Manfred Scheer
pp 9248 - 9255; DOI:
10.1021/ic800693r
PDF
Highly Selective Phosphorescent Chemosensor for Fluoride Based on an Iridium(III) Complex Containing Arylborane Units
Qiang Zhao, Fuyou Li, Shujuan Liu, Mengxiao Yu, Zhiqiang Liu, Tao Yi, and Chunhui Huang
pp 9256 - 9264; DOI:
10.1021/ic800500c
PDF
Cationic Methyl Complexes of the Rare-Earth Metals: An Experimental and Computational Study on Synthesis, Structure, and Reactivity
Mathias U. Kramer, Dominique Robert, Stefan Arndt, Peter M. Zeimentz, Thomas P. Spaniol, Ahmed Yahia, Laurent Maron, Odile Eisenstein, and Jun Okuda
pp 9265 - 9278; DOI:
10.1021/ic801259n
PDF
Synthesis and Characterization of the Trihalophosphine Compounds of Ruthenium [RuX26-cymene)(PY3)] (X = Cl, Br, Y = F, Cl, Br) and the Related PF2(NMe2) and P(NMe2)3 Compounds; Multinuclear NMR Spectroscopy and the X-ray Single Crystal Structures of [RuBr26-cymene)(PF3)], [RuBr26-cymene)(PF2{NMe2})], and [RuI26-cymene)(P{NMe2}3)]
Ahmed M. A. Boshaala, Stephen J. Simpson, Jochen Autschbach, and Shaohui Zheng
pp 9279 - 9292; DOI:
10.1021/ic800611h
PDF
New Directions in the Preparation and Redox Chemistry of Fluoride-Templated Tetranuclear Vanadium Phosphonate Cage Compounds, Mn+[(V2O3)2(RPO3)4⊂F]n
Jabor K. Jabor, Reinhard Stösser, Michael Feist, Petra Neubauer, and Manfred Meisel
pp 9293 - 9302; DOI:
10.1021/ic800707v
PDF
Neglected Bidentate sp2 N-Donor Carrier Ligands with Triazine Nitrogen Lone Pairs: Platinum Complexes Retromodeling Cisplatin Guanine Nucleobase Adducts
Vidhi Maheshwari, Patricia A. Marzilli, and Luigi G. Marzilli
pp 9303 - 9313; DOI:
10.1021/ic800836t
PDF
Hexanuclear Cobalt Carbonyl Carbide Clusters: The Interplay between Octahedral and Trigonal Prismatic Structures
Jijun Zhao, Jingcheng Xu, and R. Bruce King
pp 9314 - 9320; DOI:
10.1021/ic8009089
PDF
An Open-Framework Thorium Sulfate Hydrate with 11.5 Å Voids
Richard E. Wilson, S. Skanthakumar, Karah E. Knope, Christopher L. Cahill, and L. Soderholm
pp 9321 - 9326; DOI:
10.1021/ic800931f
PDF
Strong Rail Spin 1/2 Antiferromagnetic Ladder Systems: (Dimethylammonium)(3,5-Dimethylpyridinium)CuX4, X = Cl, Br
Firas Awwadi, Roger D. Willett, Brendan Twamley, Ryan Schneider, and Christopher P. Landee
pp 9327 - 9332; DOI:
10.1021/ic800905e
PDF
Solid- and Solution Phase Transformations in Novel Hybrid Iodoplumbate Derivatives Templated by Solvated Yttrium Complexes
Shashank Mishra, Erwann Jeanneau, Stéphane Daniele, Gilles Ledoux, and Prakash N. Swamy
pp 9333 - 9343; DOI:
10.1021/ic8010376
PDF
BaIrIn4 and Ba2Ir4In13: Two In-Rich Polar Intermetallic Structures with Different Augmented Prismatic Environments about the Cations
Andriy M. Palasyuk and John D. Corbett
pp 9344 - 9350; DOI:
10.1021/ic8006124
PDF
Inorganic Asymmetric Synthesis: Diastereoselective Syntheses of Mono- and Dinuclear Complexes Containing Octahedral, Two-Bladed Propeller, Bis(pyridine-2-aldehyde 2′-pyridylhydrazone)iron(II) Stereocenters
Rebecca J. Warr, Anthony C. Willis, and S. Bruce Wild
pp 9351 - 9362; DOI:
10.1021/ic800936d
PDF
Phosphaalkenes as Long-Lived Phosphorus Cluster Surface Functional Groups: Intramolecular PC Addition to a Niobium-Supported P7 Cage
Brandi M. Cossairt and Christopher C. Cummins
pp 9363 - 9371; DOI:
10.1021/ic8009282
PDF
Density Functional Theory Study of the Structural, Electronic, and Magnetic Properties of a μ-oxo Bridged Dinuclear FeIV Complex Based on a Tetra-Amido Macrocyclic Ligand
Arani Chanda, Filipe Tiago de Oliveira, Terrence J. Collins, Eckard Münck, and Emile L. Bominaar
pp 9372 - 9379; DOI:
10.1021/ic800881p
PDF
Thermodynamic and Kinetic Studies of H Atom Transfer from HMo(CO)35-C5H5) to Mo(N[t-Bu]Ar)3 and (PhCN)Mo(N[t-Bu]Ar)3: Direct Insertion of Benzonitrile into the Mo−H Bond of HMo(N[t-Bu]Ar)3 forming (Ph(H)CN)Mo(N[t-Bu]Ar)3
Manuel Temprado, James Eric McDonough, Arjun Mendiratta, Yi-Chou Tsai, George C. Fortman, Christopher C. Cummins, Elena V. Rybak-Akimova, and Carl D. Hoff
pp 9380 - 9389; DOI:
10.1021/ic800945m
PDF
Chiral II−VI Semiconductor Nanostructure Superlattices Based on an Amino Acid Ligand
Jean-Noël Rebilly, Paul W. Gardner, George R. Darling, John Bacsa, and Matthew J. Rosseinsky
pp 9390 - 9399; DOI:
10.1021/ic801097w
PDF
Trinuclear Mo3S7 Clusters Coordinated to Dithiolate or Diselenolate Ligands and Their Use in the Preparation of Magnetic Single Component Molecular Conductors
Rosa Llusar, Sonia Triguero, Victor Polo, Cristian Vicent, Carlos J. Gómez-García, Olivier Jeannin, and Marc Fourmigué
pp 9400 - 9409; DOI:
10.1021/ic8009546
PDF
DNA-Binding and Physical Studies of Pt(4′-NR2-trpy)CN+ Systems (trpy = 2,2′:6′,2′′-Terpyridine)
Meaghan L. Clark, Robert L. Green, Olivia E. Johnson, Phillip E. Fanwick, and David R. McMillin
pp 9410 - 9418; DOI:
10.1021/ic8009354
PDF
Iron(III) Uptake and Release by Chrysobactin, a Siderophore of the Phytophatogenic Bacterium Erwinia chrysanthemi
Vladislav Tomišić, Sylvie Blanc, Mourad Elhabiri, Dominique Expert, and Anne-Marie Albrecht-Gary
pp 9419 - 9430; DOI:
10.1021/ic801143e
PDF
Synthesis, Crystal Structures, and Luminescence of Organic-Lanthanide Complexes with Nicotinate and Isonicotinate Ligands
Guohua Jia, Ga-Lai Law, Ka-Leung Wong, Peter A. Tanner, and Wing-Tak Wong
pp 9431 - 9438; DOI:
10.1021/ic8010103
PDF
Linkage Isomerism in the Binding of Pentapeptide Ac-His(Ala)3His-NH2 to (Ethylenediamine)Palladium(II): Effect of the Binding Mode on Peptide Conformation
Huy N. Hoang, Gavin K. Bryant, Michael J. Kelso, Renee L. Beyer, Trevor G. Appleton, and David P. Fairlie
pp 9439 - 9449; DOI:
10.1021/ic800970p
PDF
High and Low Spin Mononuclear and Dinuclear Iron(II) Complexes of 4-Amino and 4-Pyrrolyl-3,5-di(2-pyridyl)-4H-1,2,4-triazoles
Jonathan A. Kitchen, Andy Noble, Carsten D. Brandt, Boujemaa Moubaraki, Keith S. Murray, and Sally Brooker
pp 9450 - 9458; DOI:
10.1021/ic801039j
PDF
Large Mn25 Single-Molecule Magnet with Spin S = 51/2: Magnetic and High-Frequency Electron Paramagnetic Resonance Spectroscopic Characterization of a Giant Spin State
Muralee Murugesu, Susumu Takahashi, Anthony Wilson, Khalil A. Abboud, Wolfgang Wernsdorfer, Stephen Hill, and George Christou
pp 9459 - 9470; DOI:
10.1021/ic801142p
PDF
Polygallide RE2MGa9Ge2 (RE = Ce, Sm; M = Ni, Co) Phases Grown in Molten Gallium
Marina A. Zhuravleva and Mercouri G. Kanatzidis
pp 9471 - 9477; DOI:
10.1021/ic801067g
PDF
Supramolecular Luminescent Gold(I)−Copper(I) Complexes: Self-Assembly of the AuxCuy Clusters inside the [Au3(diphosphine)3]3+ Triangles
Igor O. Koshevoy, Antti J. Karttunen, Sergey P. Tunik, Matti Haukka, Stanislav I. Selivanov, Alexei S. Melnikov, Pavel Yu. Serdobintsev, Mikhail A. Khodorkovskiy, and Tapani A. Pakkanen
pp 9478 - 9488; DOI:
10.1021/ic801073k
PDF
SnxPt4SnySb12−y: A Skutterudite with Covalently Bonded Filler
Y. Liang, H. Borrmann, M. Baenitz, W. Schnelle, S. Budnyk, J. T. Zhao, and Yu. Grin
pp 9489 - 9496; DOI:
10.1021/ic801154a
PDF
Metallacarboranes as Building Blocks for Polyanionic Polyarmed Aryl-Ether Materials
Pau Farràs, Francesc Teixidor, Raikko Kivekäs, Reijo Sillanpää, Clara Viñas, Bohumir Grüner, and Ivana Cisarova
pp 9497 - 9508; DOI:
10.1021/ic801139x
PDF
Uniform Colloidal Alkaline Earth Metal Fluoride Nanocrystals: Nonhydrolytic Synthesis and Luminescence Properties
Zewei Quan, Dongmei Yang, Piaoping Yang, Xiaoming Zhang, Hongzhou Lian, Xiaoming Liu, and Jun Lin
pp 9509 - 9517; DOI:
10.1021/ic8014207
PDF
Modeling of the Various Minima on the Potential Energy Surface of Bispidine Copper(II) Complexes: A Further Test for Ligand Field Molecular Mechanics
Alexander Bentz, Peter Comba, Robert J. Deeth, Marion Kerscher, Björn Seibold, and Hubert Wadepohl
pp 9518 - 9527; DOI:
10.1021/ic8011052
PDF
Hydrothermal Synthesis, Structures, and Physical Properties of Four New Flexible Multicarboxylate Ligands-Based Compounds
Zhaorui Pan, Hegen Zheng, Tianwei Wang, You Song, Yizhi Li, Zijian Guo, and Stuart R. Batten
pp 9528 - 9536; DOI:
10.1021/ic801221r
PDF
Thermally Induced Magnetic Anomalies in Solvates of the Bis(hexafluoroacetylacetonate)copper(II) Complex with Pyrazolyl-Substituted Nitronyl Nitroxide
Victor I. Ovcharenko, Galina V. Romanenko, Ksenia Yu. Maryunina, Artem S. Bogomyakov, and Elena V. Gorelik
pp 9537 - 9552; DOI:
10.1021/ic8011074
PDF
Synthesis, Structure, and Magnetism of Hexanuclear Copper(II) Phosphonates
Vadapalli Chandrasekhar, Tapas Senapati, and E. Carolina Sañudo
pp 9553 - 9560; DOI:
10.1021/ic8011525
PDF
Spacer-Directed Coordination Polymers-of-Oligomers (POLO) of Silver
Peili Teo, L. L. Koh, and T. S. Andy Hor
pp 9561 - 9568; DOI:
10.1021/ic801311j
PDF
Molecular Wheels: New Mn12 Complexes as Single-Molecule Magnets
Sonali J. Shah, Christopher M. Ramsey, Katie J. Heroux, Antonio G. DiPasquale, Naresh S. Dalal, Arnold L. Rheingold, Enrique del Barco, and David N. Hendrickson
pp 9569 - 9582; DOI:
10.1021/ic801374u
PDF
High-Connectivity Networks and Hybrid Inorganic Rod Materials Built from Potassium and Rubidium p-Halide-Substituted Aryloxides
J. Jacob Morris, Bruce C. Noll, and Kenneth W. Henderson
pp 9583 - 9591; DOI:
10.1021/ic801140u
PDF
Synthesis and Reactivity of Ir(I) and Ir(III) Complexes with MeNH2, Me2CNR (R = H, Me), C,N-C6H4{C(Me)N(Me)}-2, and N,N′-RNC(Me)CH2C(Me2)NHR (R = H, Me) Ligands
José Vicente, María Teresa Chicote, Inmaculada Vicente-Hernández, and Delia Bautista
pp 9592 - 9605; DOI:
10.1021/ic801184v
PDF
The Layered Thiostannate (dienH2)Cu2Sn2S6: a Photoconductive Inorganic−Organic Hybrid Compound
Nicole Pienack, Angela Puls, Christian Näther, and Wolfgang Bensch
pp 9606 - 9611; DOI:
10.1021/ic800118z
PDF
Syntheses, Structures, and Properties of Copper(II) Complexes of Bis(2-pyridylmethyl) Derivatives of o-, m-, and p-Phenylenediamine and Aniline
Sabrina Turba, Olaf Walter, Siegfried Schindler, Lars Preuss Nielsen, Alan Hazell, Christine J. McKenzie, Francesc Lloret, Joan Cano, and Miguel Julve
pp 9612 - 9623; DOI:
10.1021/ic800244g
PDF
Synthesis, Structure, and Reactivity of Ruthenium Carboxylato and 2-Oxocarboxylato Complexes Bearing the Bis(3,5-dimethylpyrazol-1-yl)acetato Ligand
Stefan Tampier, Rainer Müller, Andrea Thorn, Eike Hübner, and Nicolai Burzlaff
pp 9624 - 9641; DOI:
10.1021/ic8000224
PDF
Multimetallic Assemblies Using Piperazine-Based Dithiocarbamate Building Blocks
James D. E. T. Wilton-Ely, Dina Solanki, Edward R. Knight, Katherine B. Holt, Amber L. Thompson, and Graeme Hogarth
pp 9642 - 9653; DOI:
10.1021/ic800398b
PDF
Preparation and Upconversion Luminescence of Three-Dimensionally Ordered Macroporous ZrO2: Er3+, Yb3+
Xuesong Qu, Hongwei Song, Xue Bai, Guohui Pan, Biao Dong, Haifeng Zhao, Fang Wang, and Ruifei Qin
pp 9654 - 9659; DOI:
10.1021/ic800575f
PDF
Amidolithium and Amidoaluminum Catalyzed Synthesis of Substituted Guanidines: An Interplay of DFT Modeling and Experiment
Christopher N. Rowley, Tiow-Gan Ong, Jessica Priem, Tom K. Woo, and Darrin S. Richeson
pp 9660 - 9668; DOI:
10.1021/ic801028m
PDF
The Metal Loading Ability of β-Amyloid N-Terminus: A Combined Potentiometric and Spectroscopic Study of Copper(II) Complexes with β-Amyloid(1−16), Its Short or Mutated Peptide Fragments, and Its Polyethylene Glycol (PEG)-ylated Analogue
Chiara A. Damante, Katalin Ösz, Zoltán Nagy, Giuseppe Pappalardo, Giulia Grasso, Giuseppe Impellizzeri, Enrico Rizzarelli, and Imre Sóvágó
pp 9669 - 9683; DOI:
10.1021/ic8006052
PDF
Direct Solvothermal Synthesis of Early Transition Metal Nitrides
Baishakhi Mazumder, Pietro Chirico, and Andrew L. Hector
pp 9684 - 9690; DOI:
10.1021/ic800767m
PDF
Preparation, Characterization, and Structural Systematics of Diphosphane and Diarsane Complexes of Indium(III) Halides
Fei Cheng, Sarah I. Friend, Andrew L. Hector, William Levason, Gillian Reid, Michael Webster, and Wenjian Zhang
pp 9691 - 9700; DOI:
10.1021/ic801091n
PDF
Synthetic Route to Dinuclear Platinum(II) Complexes [{trans-PtCl(NH3)2}2(μ-L)]2+ (L = Aliphatic or Heterocyclic Diamine) as Potential Antitumor Agents, Exploiting the Mutual Activation of Hydroxido Ligands and Ammonium Groups
Claude Chopard, Christine Lenoir, Silvia Rizzato, Michel Vidal, Jorma Arpalahti, Laure Gabison, Alberto Albinati, Christiane Garbay, and Jiří Kozelka
pp 9701 - 9705; DOI:
10.1021/ic801251k
PDF
Organocadmium Aminoalcoholates: Synthesis, Structure, and Materials Chemistry
Andrew L. Johnson, Nathan Hollingsworth, Gabriele Kociok-Köhn, and Kieran C. Molloy
pp 9706 - 9715; DOI:
10.1021/ic800897t
PDF
Novel Heterometallic Fe−Ru2−Fe Arrays via “Complex of Complexes” Approach
Cai-Feng Wang, Jing Lin Zuo, Jie-Wen Ying, Tong Ren, and Xiao-Zeng You
pp 9716 - 9722; DOI:
10.1021/ic8011684
PDF

Issue 21


Organization of Tetrahedral Chalcogenide Clusters Using a Tetrahedral Quadridentate Linker
Qichun Zhang, Xianhui Bu, Zhien Lin, Tao Wu, and Pingyun Feng
pp 9724 - 9726; DOI:
10.1021/ic800588q
PDF
Reversible CO-Induced Chloride Shuttling in RhI Tweezer Complexes Containing Urea-Functionalized Hemilabile Ligands
Hyojong Yoo, Chad A. Mirkin, Antonio G. DiPasquale, Arnold L. Rheingold, and Charlotte L. Stern
pp 9727 - 9729; DOI:
10.1021/ic8008909
PDF
First Paramagnetic 4d Transition-Metal Complex with a Redox-Active Tetrathiafulvalene Derivative, [Ru(salen)(PPh3)(TTF-CHCH-Py)]BF4 [salen2− = N,N′-Ethan-1,2-diylbis(salicylidenamine), PPh3 = Triphenylphosphine, TTF-CHCH-Py = 4-(2-Tetrathiafulvalenylethenyl)pyridine]
Fabrice Pointillart, Yann Le Gal, Stéphane Golhen, Olivier Cador, and Lahcène Ouahab
pp 9730 - 9732; DOI:
10.1021/ic801340k
PDF
A Unique Mn2Gd2 Tetranuclear Compound of p-tert-Butylthiacalix[4]arene
Yanfeng Bi, Yanling Li, Wuping Liao, Hongjie Zhang, and Deqian Li
pp 9733 - 9735; DOI:
10.1021/ic801086n
PDF
Electrical Conductivity in Platinum-Dimer Columns
Alejandro Guijarro, Oscar Castillo, Arrigo Calzolari, Pablo J. Sanz Miguel, Carlos J. Gómez-García, Rosa di Felice, and Félix Zamora
pp 9736 - 9738; DOI:
10.1021/ic801211m
PDF
1,2,4-Diazaphospholide Complexes of Samarium(III)
Chengfu Pi, Li Wan, Yingying Gu, Wenjun Zheng, Linhong Weng, Zhenxia Chen, and Limin Wu
pp 9739 - 9741; DOI:
10.1021/ic801247t
PDF
Bis-Tris Propane as a New Polydentate Linker in the Synthesis of Iron(III) and Manganese(II/III) Complexes
Alan Ferguson, Amiera Darwish, Kristoffer Graham, Marc Schmidtmann, Andrew Parkin, and Mark Murrie
pp 9742 - 9744; DOI:
10.1021/ic8015386
PDF
Magnetic Spongelike Behavior of 3D Ferrimagnetic {[MnII(imH)]2[NbIV(CN)8]}n with Tc = 62 K
Dawid Pinkowicz, Robert Podgajny, Maria Bałanda, Magdalena Makarewicz, Bartłomiej Gaweł, Wiesław Łasocha, and Barbara Sieklucka
pp 9745 - 9747; DOI:
10.1021/ic801248f
PDF
Turn-on Fluorescence Detection of H2O2 and TATP
Meaghan E. Germain and Michael J. Knapp
pp 9748 - 9750; DOI:
10.1021/ic801317x
PDF
Reluctance of 4-Chloro-5-metalla-1,3,2-diazaborolines To Undergo Metal Halide β-Elimination: An Opportunity for C-Functionalization of 1,3,2-Diazaborolines
Emrah Giziroglu, Bruno Donnadieu, and Guy Bertrand
pp 9751 - 9753; DOI:
10.1021/ic801424k
PDF
A Chiral Self-Catenated Dual-Ligand Coordination Polymer Constructed from Three Distinct Interwoven Helical Motifs Interconnected by One-Dimensional Chains
David P. Martin, Richard J. Staples, and Robert L. LaDuca
pp 9754 - 9756; DOI:
10.1021/ic801471e
PDF
Crystal Structure of Li2B12H12: a Possible Intermediate Species in the Decomposition of LiBH4
Jae-Hyuk Her, Muhammed Yousufuddin, Wei Zhou, Satish S. Jalisatgi, James G. Kulleck, Jason A. Zan, Son-Jong Hwang, Robert C. Bowman Jr., and Terrence J. Udovic
pp 9757 - 9759; DOI:
10.1021/ic801345h
PDF
The Zero-Field-Splitting Parameter D in Binuclear Copper(II) Carboxylates Is Negative
Andrew Ozarowski
pp 9760 - 9762; DOI:
10.1021/ic801560e
PDF
Ferromagnetic Dy−Ni and Antiferromagnetic Dy−Cu Couplings in Single-Molecule Magnets [Dy2Ni] and [Dy2Cu]
Atsushi Okazawa, Takashi Nogami, Hiroyuki Nojiri, and Takayuki Ishida
pp 9763 - 9765; DOI:
10.1021/ic801686z
PDF
Low-Temperature and Template-Free Synthesis of ZnIn2S4 Microspheres
Zhixin Chen, Danzhen Li, Wenjuan Zhang, Chun Chen, Wenjuan Li, Meng Sun, Yunhui He, and Xianzhi Fu
pp 9766 - 9772; DOI:
10.1021/ic800752t
PDF
Compounds of Superatom Clusters: Preferred Structures and Significant Nonlinear Optical Properties of the BLi6-X (X = F, LiF2, BeF3, BF4) Motifs
Ying Li, Di Wu, and Zhi-Ru Li
pp 9773 - 9778; DOI:
10.1021/ic800184z
PDF
Site Selectivity in the Protonation of a Phosphinito Bridged PtI−PtI Complex: a Combined NMR and Density-Functional Theory Mechanistic Study
Mario Latronico, Flavia Polini, Vito Gallo, Piero Mastrorilli, Beatrice Calmuschi-Cula, Ulli Englert, Nazzareno Re, Timo Repo, and Minna Räisänen
pp 9779 - 9796; DOI:
10.1021/ic800508t
PDF
Trianionic Organoborate Triangles
Brendan F. Abrahams, Berin A. Boughton, Haozhen Choy, Oliver Clarke, Martin J. Grannas, David J. Price, and Richard Robson
pp 9797 - 9803; DOI:
10.1021/ic800544j
PDF
24- and 26-Membered Macrocyclic Diorganotin(IV) Bis-Dithiocarbamate Complexes with N,N′-Disubstituted 1,3- and 1,4-Bis(aminomethyl)benzene and 1,1′-Bis(aminomethyl)ferrocene as Spacer Groups
Ericka Santacruz-Juárez, Jorge Cruz-Huerta, Irán Fernando Hernández-Ahuactzi, Reyna Reyes-Martínez, Hugo Tlahuext, Hugo Morales-Rojas, and Herbert Höpfl
pp 9804 - 9812; DOI:
10.1021/ic801464s
PDF
Solid-State Changes in Ligand-to-Metal Charge-Transfer Spectra of (NH3)5RuIII(2,4-dihydroxybenzoate) and (NH3)5RuIII(xanthine) Chromophores
Karsten Krogh-Jespersen, Robert T. Stibrany, Elizabeth John, John D. Westbrook, Thomas J. Emge, Michael J. Clarke, Joseph A. Potenza, and Harvey J. Schugar
pp 9813 - 9827; DOI:
10.1021/ic800511g
PDF
Synthesis, Reactivity, and Characterization of Sodium and Rare-Earth Metal Complexes Bearing a Dianionic N-Aryloxo-Functionalized β-Ketoiminate Ligand
Hongmei Peng, Zhenqin Zhang, Ruipeng Qi, Yingming Yao, Yong Zhang, Qi Shen, and Yanxiang Cheng
pp 9828 - 9835; DOI:
10.1021/ic8011469
PDF
Mononuclear and Binuclear Rhenium Carbonyl Nitrosyls: Comparison with Their Manganese Analogues
Bing Xu, Qian-shu Li, Yaoming Xie, R. Bruce King, and Henry F. Schaefer III
pp 9836 - 9847; DOI:
10.1021/ic800681y
PDF
Axial Ligand Coordination in Sterically Strained Vanadyl Porphyrins: Synthesis, Structure, and Properties
Sudip Kumar Ghosh, Ranjan Patra, and Sankar Prasad Rath
pp 9848 - 9856; DOI:
10.1021/ic800714w
PDF
Probing the Solvent Dependent Photophysics of fac-[Re(CO)3(dppz-X2)Cl] (dppz-X2 = 11,12-X2-dipyrido[3,2-a:2′,3′-c]phenazine); X = CH3, H, F, Cl, CF3)
Marina K. Kuimova, Wassim Z. Alsindi, Alexander J. Blake, E. Stephen Davies, Daniele J. Lampus, Pavel Matousek, Jonathan McMaster, Anthony W. Parker, Michael Towrie, Xue-Zhong Sun, Claire Wilson, and Michael W. George
pp 9857 - 9869; DOI:
10.1021/ic800753f
PDF
Synthesis of High-Density Nanocavities inside TiO2−B Nanoribbons and Their Enhanced Electrochemical Lithium Storage Properties
Quanjun Li, Jingwei Zhang, Bingbing Liu, Ming Li, Ran Liu, Xianglin Li, Honglei Ma, Shidan Yu, Lin Wang, Yonggang Zou, Zepeng Li, Bo Zou, Tian Cui, and Guangtian Zou
pp 9870 - 9873; DOI:
10.1021/ic800758d
PDF
Macrocyclic Diorganotin Complexes of γ-Amino Acid Dithiocarbamates as Hosts for Ion-Pair Recognition
Jorge Cruz-Huerta, Manuel Carillo-Morales, Ericka Santacruz-Juárez, Irán F. Hernández-Ahuactzi, Jaime Escalante-García, Carolina Godoy-Alcantar, Jorge A. Guerrero-Alvarez, Herbert Höpfl, Hugo Morales-Rojas, and Mario Sánchez
pp 9874 - 9885; DOI:
10.1021/ic8007987
PDF
Formation of P−C Bonds under Unexpectedly Mild Conditions. Phosphoryl Migration and Metal Coordination of Diphenylphosphinomethyl-oxazolines and -thiazolines
Roberto Pattacini, Günter Margraf, Abdelatif Messaoudi, Nicola Oberbeckmann-Winter, and Pierre Braunstein
pp 9886 - 9897; DOI:
10.1021/ic800934h
PDF
High-Pressure Structural and Vibrational Study of PbZr0.40Ti0.60O3
J. Rouquette, J. Haines, G. Fraysse, A. Al-Zein, V. Bornand, M. Pintard, Ph. Papet, S. Hull, and F. A. Gorelli
pp 9898 - 9904; DOI:
10.1021/ic8008688
PDF
X-ray Absorption Spectroscopy of Hemes and Hemeproteins in Solution: Multiple Scattering Analysis
Paola D’Angelo, Andrea Lapi, Valentina Migliorati, Alessandro Arcovito, Maurizio Benfatto, Otello Maria Roscioni, Wolfram Meyer-Klaucke, and Stefano Della-Longa
pp 9905 - 9918; DOI:
10.1021/ic800982a
PDF
Crystallographic, Electrochemical, and Electronic Structure Studies of the Mononuclear Complexes of Au(I)/(II)/(III) with [9]aneS2O ([9]aneS2O = 1-oxa-4,7-dithiacyclononane)
Deguang Huang, Xiaofeng Zhang, Eric J. L. McInnes, Jonathan McMaster, Alexander J. Blake, E. Stephen Davies, Joanna Wolowska, Claire Wilson, and Martin Schröder
pp 9919 - 9929; DOI:
10.1021/ic8010037
PDF
Triplet Energy Transfers in Electrostatic Host−Guest Assemblies of Unsaturated Organometallic Cluster Cations and Carboxylate-Containing Porphyrin Pigments
Shawkat M. Aly, Charfedinne Ayed, Christine Stern, Roger Guilard, Alaa S. Abd-El-Aziz, and Pierre D. Harvey
pp 9930 - 9940; DOI:
10.1021/ic801006g
PDF
Crystal Growth of Two New Photoluminescent Oxides: Sr3Li6Nb2O11 and Sr3Li6Ta2O11
M. Bharathy, V. A. Rassolov, S. Park, and H.-C. zur Loye
pp 9941 - 9945; DOI:
10.1021/ic801102t
PDF
Cubic Nonlinear Optical Properties of Platinum-Terminated Polyynediyl Chains
Marek Samoc, Gulliver T. Dalton, John A. Gladysz, Qinglin Zheng, Yasen Velkov, Hans Ågren, Patrick Norman, and Mark G. Humphrey
pp 9946 - 9957; DOI:
10.1021/ic801145c
PDF
Tetravalent Silicon Connectors MenSi(p-C6H4CO2H)4−n (n = 0, 1, 2) for the Construction of Metal−Organic Frameworks
R. P. Davies, R. J. Less, P. D. Lickiss, K. Robertson, and A. J. P. White
pp 9958 - 9964; DOI:
10.1021/ic801174d
PDF
Persistent Radicals of Trivalent Tin and Lead
Marco Becker, Christoph Förster, Christian Franzen, Johannes Hartrath, Enzio Kirsten, Jörn Knuth, Karl W. Klinkhammer, Ajay Sharma, and Dariush Hinderberger
pp 9965 - 9978; DOI:
10.1021/ic801198p
PDF
Anionic Layered Networks Reconstructed from [Cd(SCN)3] Chains in Pseudo One-Dimensional Conducting Salts of Halogenated Tetrathiafulvalenes
Marc Fourmigué and Pascale Auban-Senzier
pp 9979 - 9986; DOI:
10.1021/ic801207v
PDF
Carboxyl-Functionalized Task-Specific Ionic Liquids for Solubilizing Metal Oxides
Peter Nockemann, Ben Thijs, Tatjana N. Parac-Vogt, Kristof Van Hecke, Luc Van Meervelt, Bernard Tinant, Ingo Hartenbach, Thomas Schleid, Vu Thi Ngan, Minh Tho Nguyen, and Koen Binnemans
pp 9987 - 9999; DOI:
10.1021/ic801213z
PDF
Mechanistic Insight into the Initiation Step of the Coupling Reaction of Oxetane or Epoxides and CO2 Catalyzed by (salen)CrX Complexes
Donald J. Darensbourg and Adriana I. Moncada
pp 10000 - 10008; DOI:
10.1021/ic801231p
PDF
Temperature Driven Reactant Solubilization Synthesis of BiCuOSe
Evan S. Stampler, William C. Sheets, Mariana I. Bertoni, Wilfrid Prellier, Thomas O. Mason, and Kenneth R. Poeppelmeier
pp 10009 - 10016; DOI:
10.1021/ic801267m
PDF
Racemic Atropisomeric N,N-Chelate Ligands for Recognizing Chiral Carboxylates via Zn(II) Coordination: Structure, Fluorescence, and Circular Dichroism
Theresa M. McCormick and Suning Wang
pp 10017 - 10024; DOI:
10.1021/ic801269z
PDF
Acetonimine and 4-Imino-2-methylpentan-2-amino Platinum(II) Complexes: Synthesis and in Vitro Antitumor Activity
José Ruiz, Venancio Rodríguez, Natalia Cutillas, Gregorio López, and Delia Bautista
pp 10025 - 10036; DOI:
10.1021/ic8012359
PDF
Computational Study of Iron Bis(dithiolene) Complexes: Redox Non-Innocent Ligands and Antiferromagnetic Coupling
Heiko Jacobsen and James P. Donahue
pp 10037 - 10045; DOI:
10.1021/ic801277r
PDF
Fluorinated β-Diketonates of the First Row Divalent Transition Metals: New Approach to the Synthesis of Unsolvated Species
Haitao Zhang, Bo Li, Jinyu Sun, Rodolphe Clérac, and Evgeny V. Dikarev
pp 10046 - 10052; DOI:
10.1021/ic801320p
PDF
Four Zinc(II) Helical Coordination Polymers and 78-Membered Six-Node Zinc Metallacycle Assembled from Diastereopure N,N′-Bis(acetylacetone)cyclohexanediimine
Bi-Xue Zhu, Qi-Long Zhang, Yun-Qian Zhang, Tao Zhu, Jack K. Clegg, Leonard F. Lindoy, and Gang Wei
pp 10053 - 10061; DOI:
10.1021/ic801329g
PDF
Hydrothermal Synthesis, Crystal Structure, and Magnetic Properties of a New Inorganic Vanadium(III) Phosphate with a Chain Structure
Stanislav Ferdov, Mario S. Reis, Zhi Lin, and Rute A. Sá Ferreira
pp 10062 - 10066; DOI:
10.1021/ic801318c
PDF
Bonding and Structure of Copper Nitrenes
Thomas R. Cundari, Adriana Dinescu, and Abul B. Kazi
pp 10067 - 10072; DOI:
10.1021/ic801337f
PDF
Boraguanidinates: Synthesis, X-ray Structures, and Reactions of {Li2[iPr2NB(NDipp)2]}2 with p-Block and Group 12 Element Halides
Andrea M. Corrente and Tristram Chivers
pp 10073 - 10080; DOI:
10.1021/ic801336t
PDF
High Nuclearity Single-Molecule Magnets: a Mixed-Valence Mn26 Cluster Containing the Di-2-pyridylketone Diolate Dianion
Theocharis C. Stamatatos, Vassilios Nastopoulos, Anastasios J. Tasiopoulos, Eleni E. Moushi, Wolfgang Wernsdorfer, George Christou, and Spyros P. Perlepes
pp 10081 - 10089; DOI:
10.1021/ic801342f
PDF
A Rational Basis for the Axial Ligand Effect in C−H Oxidation by [MnO(porphyrin)(X)]+ (X = H2O, OH, O2−) from a DFT Study
David Balcells, Christophe Raynaud, Robert H. Crabtree, and Odile Eisenstein
pp 10090 - 10099; DOI:
10.1021/ic8013706
PDF
Heavy Atom Analogues of 1,2,3-Dithiazolylium Salts: Preparation, Structures and Redox Chemistry
Maarit Risto, Abdeljalil Assoud, Stephen M. Winter, Raija Oilunkaniemi, Risto S. Laitinen, and Richard T. Oakley
pp 10100 - 10109; DOI:
10.1021/ic8013738
PDF
Spectroscopic, Electrochemical, and Computational Aspects of the Charge Distribution in Ru(acac)2(R-o-benzoquinonediimine) Complexes
Daria Kalinina, Christopher Dares, Harini Kaluarachchi, Pierre G. Potvin, and A. B. P. Lever
pp 10110 - 10126; DOI:
10.1021/ic8014496
PDF
Aqueous Uranium(VI) Hydrolysis Species Characterized by Attenuated Total Reflection Fourier-Transform Infrared Spectroscopy
Katharina Müller, Vinzenz Brendler, and Harald Foerstendorf
pp 10127 - 10134; DOI:
10.1021/ic8005103
PDF
Pentavalent Uranium Oxide via Reduction of [UO2]2+ Under Hydrothermal Reaction Conditions
Nebebech Belai, Mark Frisch, Eugene S. Ilton, Bruce Ravel, and Christopher L. Cahill
pp 10135 - 10140; DOI:
10.1021/ic801534m
PDF
The First Dinitrile Frameworks of the Rare Earth Elements: 3[LnCl3(1,4-Ph(CN)2)] and 3[Ln2Cl6(1,4-Ph(CN)2)], Ln = Sm, Gd, Tb, Y; Access to Novel Metal-Organic Frameworks by Solvent Free Synthesis in Molten 1,4-Benzodinitrile
Christoph J. Höller and Klaus Müller-Buschbaum
pp 10141 - 10149; DOI:
10.1021/ic800635u
PDF
A New Class of Sulfido/Oxo(dithiolene)−Molybdenum(IV) Complexes Derived from Sulfido/Oxo-Bis(tetrasulfido)molybdenum(IV) Anions
Hideki Sugimoto, Koichiro Suyama, Kunihisa Sugimoto, Hiroyuki Miyake, Isao Takahashi, Shun Hirota, and Shinobu Itoh
pp 10150 - 10157; DOI:
10.1021/ic800832a
PDF
Cu(I) Complexes Bearing the New Sterically Demanding and Coordination Flexible Tris(3-phenyl-1-pyrazolyl)methanesulfonate Ligand and the Water-Soluble Phosphine 1,3,5-Triaza-7-phosphaadamantane or Related Ligands
Riccardo Wanke, Piotr Smoleński, M. Fátima C. Guedes da Silva, Luísa M. D. R. S. Martins, and Armando J. L. Pombeiro
pp 10158 - 10168; DOI:
10.1021/ic801254b
PDF
Synthesis of (C5Me5)2(C5Me4H)UMe, (C5Me5)2(C5H5)UMe, and (C5Me5)2UMe[CH(SiMe3)2] from Cationic Metallocenes for the Evaluation of Sterically Induced Reduction
William J. Evans, Justin R. Walensky, Filipp Furche, Joseph W. Ziller, Antonio G. DiPasquale, and Arnold L. Rheingold
pp 10169 - 10176; DOI:
10.1021/ic801232e
PDF
C−H Bond Activation of Coordinated Pyridine: Ortho-Pyridyl-Ditechnetiumhydridocarbonyl Metal Cyclus. Crystal Structure and Dynamic Behavior in Solution
Maaz Zuhayra, Ulf Lützen, Arne Lützen, Laszlo Papp, Eberhard Henze, Gernot Friedrichs, and Franz Oberdorfer
pp 10177 - 10182; DOI:
10.1021/ic8015063
PDF

Issue 22


A [MnIII3O]7+ Single-Molecule Magnet: the Anisotropy Barrier Enhanced by Structural Distortion
Chen-I Yang, Wolfgang Wernsdorfer, Kai-Hung Cheng, Motohiro Nakano, Gene-Hsiang Lee and Hui-Lien Tsai
pp 10184–10186 DOI: 10.1021/ic8012238
Reductive Cleavage of O-, S-, and N-'Organonitroso Compounds by Nickel(I) β-Diketiminates
Marie M. Melzer, Sarah Jarchow-Choy, Elzbieta Kogut and Timothy H. Warren
pp 10187–10189 DOI: 10.1021/ic8014332
Anion−π−π Interactions in a Dinuclear M2L2 Metallocycle
Magdalena Cap, Jordi Benet-Buchholz and Pablo Ballester
pp 10190–10192 DOI: 10.1021/ic801282r
Na3PbII[B(O3POH)4]: An Alkali-Metal Lead Borophosphate with Heterocubane-like Units Na3PbO4
Stefan Hoffmann, Harold B. Tanh Jeazet, Prashanth W. Menezes, Yurii Prots and Rdiger Kniep
pp 10193–10195 DOI: 10.1021/ic801334g
Remarkably Bent, Ethane-Linked, Diiron(III) μ-Oxobisporphyrin: Synthesis, Structure, Conformational Switching, and Photocatalytic Oxidation
Sudip Kumar Ghosh, Ranjan Patra and Sankar Prasad Rath
pp 10196–10198 DOI: 10.1021/ic801423g
Nickel Dithiolene Chelate Rings in a New Role as η5-Coordinating Ligands: Synthesis, Structural Characterization, and Redox Reactivity of an “Fe2Ni” Bis-Double-Decker
Daniel J. Harrison, Antonio G. De Crisci, Alan J. Lough, Mitchell J. Kerr and Ulrich Fekl
pp 10199–10201 DOI: 10.1021/ic801487f
Control of 1D Wave versus 2D Honeycomb CoIIICdIICuI Heterotrimetallic Architectures by ΔL−ΛL Diastereoisomerism of l-Cysteinatocobalt(III) Building Units
Takashi Aridomi, Asako Igashira-Kamiyama and Takumi Konno
pp 10202–10204 DOI: 10.1021/ic801495h
An Arene-Stabilized Cobalt(I) Aryl: Reactions with CO and NO
Hao Lei, Bobby D. Ellis, Chengbao Ni, Fernande Grandjean, Gary J. Long and Philip P. Power
pp 10205–10207 DOI: 10.1021/ic8015782
Easily Prepared Chiral Scorpionates: Tris(2-oxazolinyl)boratoiridium(I) Compounds and Their Interactions with MeOTf
Benjamin Baird, Andrew V. Pawlikowski, Jiachun Su, Jerzy W. Wiench, Marek Pruski and Aaron D. Sadow
pp 10208–10210 DOI: 10.1021/ic801637s
Chiral-Layered Metal Phosphonate Formed via Spontaneous Resolution Showing Dehydration-Induced Antiferromagnetic to Ferromagnetic Transformation
Shou-Zeng Hou, Deng-Ke Cao, Yi-Zhi Li and Li-Min Zheng
pp 10211–10213 DOI: 10.1021/ic801655a
Intermolecular Contact-Tuned Magnetic Nature in One-Dimensional 3d−5d Bimetallic Systems: From a Metamagnet to a Single-Chain Magnet
Seok Woo Choi, Hyun Young Kwak, Jung Hee Yoon, Hyoung Chan Kim, Eui Kwan Koh and Chang Seop Hong
pp 10214–10216 DOI: 10.1021/ic801699p
Effects of Chemically Induced Contraction of a Coordination Polyhedron on the Dynamical Magnetism of Bis(phthalocyaninato)disprosium, a Single-4f-Ionic Single-Molecule Magnet with a Kramers Ground State
Naoto Ishikawa, Yoshifumi Mizuno, Satoshi Takamatsu, Tadahiko Ishikawa and Shin-ya Koshihara
pp 10217–10219 DOI: 10.1021/ic8014892
Formation of a Bridging-Imido d6 Rhodium Compound by Nitrene Capture. Insertion and Cycloaddition Reactions
Cristina Tejel, Miguel A. Ciriano, Sonia Jimnez, Vincenzo Passarelli and Jos A. Lpez
pp 10220–10222 DOI: 10.1021/ic801703d
An Example of Node-Based Postassembly Elaboration of a Hydrogen-Sorbing, Metal−Organic Framework Material
Omar K. Farha, Karen L. Mulfort and Joseph T. Hupp
pp 10223–10225 DOI: 10.1021/ic8018452
Molybdenum Tris(2,5-dimethylpyrrolide), a Rare Homoleptic Molybdenum(III) Monomer
Keith M. Wampler and Richard R. Schrock
pp 10226–10228 DOI: 10.1021/ic801695j
Self-Assembly of a Chiral Carbonate- and Cytidine-Containing Dodecanuclear Copper(II) Complex: a Multiarm-Supplied Globular Capsule
Donatella Armentano, Nadia Marino, Teresa F. Mastropietro, Jos Martnez-Lillo, Joan Cano, Miguel Julve, Francesc Lloret and Giovanni De Munno
pp 10229–10231 DOI: 10.1021/ic801815s
One-Dimensional Iron(II) Compounds Exhibiting Spin Crossover and Liquid Crystalline Properties in the Room Temperature Region
M. Seredyuk, A. B. Gaspar, V. Ksenofontov, Y. Galyametdinov, M. Verdaguer, F. Villain and P. Gtlich
pp 10232–10245 DOI: 10.1021/ic8006266
Bimetallic Coordination Polymers via Combination of Substitution-Inert Building Blocks and Labile Connectors
Malgorzata Kondracka and Ulli Englert
pp 10246–10257 DOI: 10.1021/ic800748f
Efficient Sensitization of Europium, Ytterbium, and Neodymium Functionalized Tris-Dipicolinate Lanthanide Complexes through Tunable Charge-Transfer Excited States
Anthony D’Alo, Alexandre Picot, Andrew Beeby, J. A. Gareth Williams, Boris Le Guennic, Chantal Andraud and Olivier Maury
pp 10258–10268 DOI: 10.1021/ic8012969
Design of Dipicolinic Acid Ligands for the Two-Photon Sensitized Luminescence of Europium Complexes with Optimized Cross-Sections
Anthony D’Alo, Alexandre Picot, Patrice L. Baldeck, Chantal Andraud and Olivier Maury
pp 10269–10279 DOI: 10.1021/ic8012975
A Family of New Glutarate Compounds: Synthesis, Crystal Structures of: Co(H2O)5L(1), Na2[CoL2] (2), Na2[L(H2L)4/2] (3), {[Co3(H2O)6L2](HL)2}·4H2O (4), {[Co3(H2O)6L2](HL)2}·10H2O (5), {[Co3(H2O)6L2]L2/2}·4H2O (6), and Na2{[Co3(H2O)2]L8/2]·6H2O (7), and Magnetic Properties of 1 and 2 with H2L = HOOC-(CH2)3-COOH
Yue-Qing Zheng, Jian-Li Lin, Wei Xu, Hong-Zhen Xie, Jie Sun and Xian-Wen Wang
pp 10280–10287 DOI: 10.1021/ic801053p
Optical Properties of the (CrF6)3− Complex in A2BMF6:Cr3+ Elpasolite Crystals: Variation with M−F Bond Distance and Hydrostatic Pressure
Ignacio Hernndez, Fernando Rodrguez and Alain Tressaud
pp 10288–10298 DOI: 10.1021/ic800606h
Electronic Structure of Six-Coordinate Iron(III) Monoazaporphyrins
Kenichiro Nakamura, Akira Ikezaki, Yoshiki Ohgo, Takahisa Ikeue, Saburo Neya and Mikio Nakamura
pp 10299–10307 DOI: 10.1021/ic800674d
Spectroscopic Studies and Structures of trans-Ruthenium(II) and Ruthenium(III) Bis(cyanide) Complexes Supported by a Tetradentate Macrocyclic Tertiary Amine Ligand
Chun-Yuen Wong, Fu-Wa Lee, Chi-Ming Che, Yung Fong Cheng, David Lee Phillips and Nianyong Zhu
pp 10308–10316 DOI: 10.1021/ic800743a
Metal-Dependent Assembly of a Helical-[Co3L3] Cluster versus a Meso-[Cu2L2] Cluster with O,N,N′,O′-Schiff Base Ligand: Structures and Magnetic Properties
Yuanyuan Pang, Shuxin Cui, Bo Li, Jingping Zhang, Yu Wang and Hong Zhang
pp 10317–10324 DOI: 10.1021/ic800856m
Physical and Electrical Properties of Chemical Vapor Grown GaN Nano/Microstructures
Jianye Li, Jie Liu, Lung-Shen Wang and Robert P. H. Chang
pp 10325–10329 DOI: 10.1021/ic702427u
Ni(II) and hs-Fe(II) Complexes of a Paramagnetic Thiazyl Ligand, and Decomposition Products of the Iron Complex, Including an Fe(III) Tetramer
Nigel G. R. Hearns, Elisabeth M. Fatila, Rodolphe Clrac, Michael Jennings and Kathryn E. Preuss
pp 10330–10341 DOI: 10.1021/ic800749b
Metal Ion Complexing Properties of the Highly Preorganized Ligand 2,9-bis(Hydroxymethyl)-1,10-phenanthroline: A Crystallographic and Thermodynamic Study
Raymond T. Gephart, , Neil J. Williams, Joseph H. Reibenspies, Alvaro S. De Sousa and Robert D. Hancock
pp 10342–10348 DOI: 10.1021/ic8008656
Ag4L2 Nanocage as a Building Unit toward the Construction of Silver Metal Strings
Jing-Yun Wu, Yu-Fang Lin, Chuan-Hung Chuang, Tien-Wen Tseng, Yuh-Sheng Wen and Kuang-Lieh Lu
pp 10349–10356 DOI: 10.1021/ic800883x
Bioinorganic Chemistry Modeled with the TPSSh Density Functional
Kasper P. Jensen
pp 10357–10365 DOI: 10.1021/ic800841t
Synthesis and Electrochemical Reaction with Lithium of Mesoporous Iron Oxalate Nanoribbons
Mara Jos Aragón, Bernardo León, Carlos Pérez Vicente and Jos L. Tirado
pp 10366–10371 DOI: 10.1021/ic8008927
Favorable Hydrogen Storage Properties of M(HBTC)(4,4′-bipy)·3DMF (M = Ni and Co)
Yaoqi Li, Lei Xie, Yang Liu, Rong Yang and Xingguo Li
pp 10372–10377 DOI: 10.1021/ic800919k
Homogeneous Catalytic System for Photoinduced Hydrogen Production Utilizing Iridium and Rhodium Complexes
Eric D. Cline, Samantha E. Adamson and Stefan Bernhard
pp 10378–10388 DOI: 10.1021/ic800988b
1-D Polymers with Alternate Cu2 and Ln2 Units (Ln = Gd, Er, Y) and Carboxylate Linkages
Rafael Calvo, Raul E. Rapp, Edson Chagas, Rosana P. Sartoris, Ricardo Baggio, Mara T. Garland and Mireille Perec
pp 10389–10397 DOI: 10.1021/ic8014089
Structural Diversity in Neodymium Bipyrimidine Compounds with Near Infrared Luminescence: from Mono- and Binuclear Complexes to Metal-Organic Frameworks
Gal Zucchi, Olivier Maury, Pierre Thury and Michel Ephritikhine
pp 10398–10406 DOI: 10.1021/ic800967x
Structural and Photophysical Characterization of Multichromophoric Pyridylporphyrin-Rhenium(I) Conjugates
Massimo Casanova, Ennio Zangrando, Elisabetta Iengo, Enzo Alessio, Maria Teresa Indelli, Franco Scandola and Michele Orlandi
pp 10407–10418 DOI: 10.1021/ic800971e
On the Strongly Correlated Electron Hydride Ce2Ni2MgH7.7
Bernard Chevalier, Aleksandra A. Krolak, Jean-Louis Bobet, Etienne Gaudin, Franois Weill, Wilfried Hermes and Rainer Pttgen
pp 10419–10424 DOI: 10.1021/ic801076b
Effects of Nucleobase Metalation on Frontier Molecular Orbitals: Potential Implications for π-Stacking Interactions with Tryptophan
Atilio I. Anzellotti, Craig A. Bayse and Nicholas P. Farrell
pp 10425–10431 DOI: 10.1021/ic801004a
Excited State Dynamics of a PtII Diimine Complex bearing a Naphthalene-Diimide Electron Acceptor
Igor V. Sazanovich, Mohammed A. H. Alamiry, Jonathan Best, Robert D. Bennett, Oleg V. Bouganov, E. Stephen Davies, Vyacheslav P. Grivin, Anthony J. H. M. Meijer, Victor F. Plyusnin, Kate L. Ronayne, Alexander H. Shelton, Sergei A. Tikhomirov, Michael Towrie and Julia A. Weinstein
pp 10432–10445 DOI: 10.1021/ic801022h
Synthesis and Characterization of Dicyclopalladated Complexes of Azobenzene Derivatives by Experimental and Computational Methods
Darko Babi, Manda uri, Kreimir Molanov, Gregor Ilc and Janez Plavec
pp 10446–10454 DOI: 10.1021/ic8010234
Crystal Structures, Phase-Transition, and Photoluminescence of Rare Earth Carbodiimides
Jochen Glaser, Leonid Unverfehrt, Helga Bettentrup, Gunter Heymann, Hubert Huppertz, Thomas Jstel and H.-Jrgen Meyer
pp 10455–10460 DOI: 10.1021/ic800985k
Construction of Symmetric and Asymmetric Mo/S/Cu Clusters from a Cluster Precursor [Et4N]2[(edt)2Mo2S2(μ-S)2] (edt = Ethanedithiolate)
Zhen-Hong Wei, Hong-Xi Li, Wen-Hua Zhang, Zhi-Gang Ren, Yong Zhang, Jian-Ping Lang and Brendan F. Abrahams
pp 10461–10468 DOI: 10.1021/ic801100g
Copper β-Octakis(trifluoromethyl)corroles: New Paradigms for Ligand Substituent Effects in Transition Metal Complexes
Kolle Ekaney Thomas, Ingar H. Wasbotten and Abhik Ghosh
pp 10469–10478 DOI: 10.1021/ic801101k
A Dinuclear Ni(I) System Having a Diradical Ni2N2 Diamond Core Resting State: Synthetic, Structural, Spectroscopic Elucidation, and Reductive Bond Splitting Reactions
Debashis Adhikari, Susanne Mossin, Falguni Basuli, Benjamin R. Dible, Mircea Chipara, Hongjun Fan, John C. Huffman, Karsten Meyer and Daniel J. Mindiola
pp 10479–10490 DOI: 10.1021/ic801137p
The Mn2+−Bicarbonate Complex in a Frozen Solution Revisited by Pulse W-Band ENDOR
Alexey Potapov and Daniella Goldfarb
pp 10491–10498 DOI: 10.1021/ic8011316
Magnetic Circular Dichroism Study of a Dicobalt(II) Methionine Aminopeptidase/Fumagillin Complex and Dicobalt II−II and II−III Model Complexes
James A. Larrabee, Seung-An Chyun and Adam S. Volwiler
pp 10499–10508 DOI: 10.1021/ic8011553
Essential Role of the Ancillary Ligand in the Color Tuning of Iridium Tetrazolate Complexes
Stefano Stagni, Silvia Colella, Antonio Palazzi, Giovanni Valenti, Stefano Zacchini, Francesco Paolucci, Massimo Marcaccio, Rodrigo Q. Albuquerque and Luisa De Cola
pp 10509–10521 DOI: 10.1021/ic801157k
Group IV Imino-Semiquinone Complexes Obtained by Oxidative Addition of Halogens
Karen J. Blackmore, Michael B. Sly, Mason R. Haneline, Joseph W. Ziller and Alan F. Heyduk
pp 10522–10532 DOI: 10.1021/ic801127r
Diamidodipyrrins: Versatile Bipyrrolic Ligands with Multiple Metal Binding Modes
Van S. Thoi, Jay R. Stork, Edwards T. Niles, Ezra C. Depperman, David L. Tierney and Seth M. Cohen
pp 10533–10541 DOI: 10.1021/ic8011876
Four-Coordinate Mo(II) as (silox)2Mo(PMe3)2 and Its W(IV) Congener (silox)2HW(η2-CH2PMe2)(PMe3) (silox = tBu3SiO)
David S. Kuiper, Peter T. Wolczanski, Emil B. Lobkovsky and Thomas R. Cundari
pp 10542–10553 DOI: 10.1021/ic8011958
Strong Intramolecular Si−N Interactions in the Chlorosilanes Cl3−nHnSiOCH2CH2NMe2 (n = 1−3)
Michael Hagemann, Andreas Mix, Raphael J. F. Berger, Tania Pape and Norbert W. Mitzel
pp 10554–10564 DOI: 10.1021/ic801205q
Stabilization of Copper(II) Thiosulfonate Coordination Complexes Through Cooperative Hydrogen Bonding Interactions
Adam J. Fischmann, Craig M. Forsyth and Leone Spiccia
pp 10565–10574 DOI: 10.1021/ic801234c
Chiral, Hemilabile Palladium(II) Complexes of Tridentate Oxazolidines, Including C2-Symmetric “Pincers”
Elizabeth T. J. Strong, Steven A. Cardile, Allison L. Brazeau, Michael C. Jennings, Robert McDonald and Nathan D. Jones
pp 10575–10586 DOI: 10.1021/ic8011926
Mechanism of Pyridine−Ligand Exchanges at the Different Labile Sites of 3d Heterometallic and Mixed Valence μ3-oxo Trinuclear Clusters
Ghenadie Novitchi, Fabrice Riblet, Rosario Scopelliti, Lothar Helm, Aurelian Gulea and Andr E. Merbach
pp 10587–10599 DOI: 10.1021/ic801206m
Self-Assembly of 2D→2D Interpenetrating Coordination Polymers Showing Polyrotaxane- and Polycatenane-like Motifs: Influence of Various Ligands on Topological Structural Diversity
Ya-Qian Lan, Shun-Li Li, Jun-Sheng Qin, Dong-Ying Du, Xin-Long Wang, Zhong-Min Su and Qiang Fu
pp 10600–10610 DOI: 10.1021/ic801275w
CsB3GeO7 and K2B2Ge3O10: Explorations of New Second-Order Nonlinear Optical Materials in the Borogermanate Systems
Fang Kong, Hai-Long Jiang, Ting Hu and Jiang-Gao Mao
pp 10611–10617 DOI: 10.1021/ic801292p
Trithiatetrazocine Cations, [RCN4S3]+; Planar Sulfur−Nitrogen 10π Aromatics
Carsten Knapp, Paul G. Watson, Enno Lork, Daniel H. Friese, Rdiger Mews and Andreas Decken
pp 10618–10625 DOI: 10.1021/ic801253f
High Resolution Mass Spectrometry for Studying the Interactions of Cisplatin with Oligonucleotides
Alexander E. Egger, Christian G. Hartinger, Hisham Ben Hamidane, Yury O. Tsybin, Bernhard K. Keppler and Paul J. Dyson
pp 10626–10633 DOI: 10.1021/ic801371r
Experimental and Theoretical Investigations of the Redox Behavior of the Heterodichalcogenido Ligands [(EPiPr2)(TePiPr2)N] (E = S, Se): Cyclic Cations and Acyclic Dichalcogenide Dimers
Stuart D. Robertson, Tristram Chivers and Heikki M. Tuononen
pp 10634–10643 DOI: 10.1021/ic801384c
Low-Temperature N−O Bond Cleavage of Nitrogen Monoxide in Heterometallic Carbonyl Complexes. An Experimental and Theoretical Study
M. Esther Garca, Sonia Meln, Miguel A. Ruiz, Ramn Lpez, Toms Sordo, Luciano Marchi and Antonio Tiripicchio
pp 10644–10655 DOI: 10.1021/ic801356m
Ferromagnetic Interactions in Heterobimetallic Chains Formed through the Secondary Coordination of Dithiolene Complexes
Olivier Jeannin, Rodolphe Clrac, Thomas Cauchy and Marc Fourmigu
pp 10656–10661 DOI: 10.1021/ic801343b
Dinuclear Copper(I) and Copper(I)/Silver(I) Complexes with Condensed Dithiolato Ligands1
Jos Vicente, Pablo Gonzlez-Herrero, Yolanda Garca-Snchez and Delia Bautista
pp 10662–10673 DOI: 10.1021/ic8014139
Slow Magnetic Relaxation of a Ferromagnetic NiII5 Cluster with an S = 5 Ground State
Athanassios K. Boudalis, Michael Pissas, Catherine P. Raptopoulou, Vassilis Psycharis, Beln Abarca and Rafael Ballesteros
pp 10674–10681 DOI: 10.1021/ic801441d
Mono(cycloheptatrienyl) Tantalum Chemistry: Synthesis and Characterization of New Tantalum Halide, Hydride, and Alkyl Species
Wontae Noh and Gregory S. Girolami
pp 10682–10691 DOI: 10.1021/ic8015035
Self-Assembly of Triple Helical and meso-Helical Cylindrical Arrays Tunable by Bis-Tripodal Coordination Converters
Ji-Jun Jiang, Sheng-Run Zheng, Yu Liu, Mei Pan, Wei Wang and Cheng-Yong Su
pp 10692–10699 DOI: 10.1021/ic801516b
Influence of Ligand Electronic Effects on the Structure of Monovalent Cobalt Complexes
Julie A. DuPont, Glenn P. A. Yap and Charles G. Riordan
pp 10700–10707 DOI: 10.1021/ic800813u
Stepwise Modification of Titanium Alkoxy Chloride Compounds by Pyridine Carbinol
Timothy J. Boyle, Leigh Anna M. Ottley, Mark A. Rodriguez, Robin M. Sewell, Todd M. Alam and Sarah K. McIntyre
pp 10708–10717 DOI: 10.1021/ic801249b
Manganese(III) Corrole-Oxidant Adduct as the Active Intermediate in Catalytic Hydrogen Atom Transfer
Michael J. Zdilla and Mahdi M. Abu-Omar
pp 10718–10722 DOI: 10.1021/ic801182q
Submicrosized Rods, Cables, and Tubes of ZnE (E = S, Se, Te): Exterior−Interior Boron-Chalcogen Conversions and Optical Properties
Yi-Zhi Huang, Ling Chen and Li-Ming Wu
pp 10723–10728 DOI: 10.1021/ic8005053
Factors Influencing Tetranuclear [2 × 2] Grid vs Dinuclear Side-by-Side Structures for Silver(I) Complexes of Pyridazine-Based Bis-Bidentate Ligands
Jason R. Price, Nicholas G. White, Alejandro Perez-Velasco, Geoffrey B. Jameson, Christopher A. Hunter and Sally Brooker
pp 10729–10738 DOI: 10.1021/ic800959s
Interaction of Uranium(VI) with Phthalic Acid
Gustavo J. Vazquez, Cleveland J. Dodge and Arokiasamy J. Francis
pp 10739–10743 DOI: 10.1021/ic801230s
Conformation Changes and Luminescent Properties of Au-Ln (Ln = Nd, Eu, Er, Yb) Arrays with 5-Ethynyl-2,2′-Bipyridine
Hai-Bing Xu, Li-Yi Zhang, Jun Ni, Hsiu-Yi Chao and Zhong-Ning Chen
pp 10744–10752 DOI: 10.1021/ic800733x
La8Br7Ni4: Ribbons of Ni Hexagons in Condensed La6 Trigonal Prisms
Chong Zheng, Hansjrgen Mattausch, Constantin Hoch and Arndt Simon
pp 10753–10757 DOI: 10.1021/ic801227e
CuO Particles from Ionic Liquid/Water Mixtures: Evidence for Growth via Cu(OH)2 Nanorod Assembly and Fusion
Andreas Taubert, Annett Uhlmann, Annett Hedderich and Katrin Kirchhoff
pp 10758–10764 DOI: 10.1021/ic801335k
Use of 73Ge NMR Spectroscopy for the Study of Electronic Interactions
Claude H. Yoder, Tamara M. Agee, Charles D. Schaeffer, , Mary J. Carroll, Adam J. Fleisher and Alaina S. DeToma
pp 10765–10770 DOI: 10.1021/ic801341t
Functional Evaluation of Iron Oxypyriporphyrin in Protein Heme Pocket
Saburo Neya, Masaaki Suzuki, Hirotaka Ode, Tyuji Hoshino, Yuji Furutani, Hideki Kandori, Hiroshi Hori, Kiyohiro Imai and Teruyuki Komatsu
pp 10771–10778 DOI: 10.1021/ic801406x
Synthesis and Characterization of a Dinuclear Iron(II) Spin Crossover Complex with Wide Hysteresis
Birgit Weber, Eike S. Kaps, Jaroslava Obel, Klaus Achterhold and Fritz G. Parak
pp 10779–10787 DOI: 10.1021/ic801388a
Mechanisms of ZnII-Activated Magnetic Resonance Imaging Agents
Jody L. Major, Rene M. Boiteau and Thomas J. Meade
pp 10788–10795 DOI: 10.1021/ic801458u
Synthesis and Platinum Coordination Chemistry of the Perfluoroalkyl Acceptor Pincer Ligand 1,3-(CH2P(CF3)2)2C6H4
Jeramie J. Adams, Ade Lau, Navamoney Arulsamy and Dean M. Roddick
p 10796 DOI: 10.1021/ic8019217

Issue 23


Photoluminescent Mn4 Single-Molecule Magnet
Christopher C. Beedle, Casey J. Stephenson, Katie J. Heroux, Wolfgang Wernsdorfer and David N. Hendrickson
pp 10798–10800 DOI: 10.1021/ic801485k
A Novel Tripodal Ligand, Tris[(4′-methyl-2,2′-bipyridyl-4-yl)methyl]carbinol and Its Trinuclear RuII/ReI Mixed-Metal Complexes: Synthesis, Emission Properties, and Photocatalytic CO2 Reduction
Zhao-Yong Bian, Katsuhiro Sumi, Masaoki Furue, Shunsuke Sato, Kazuhide Koike and Osamu Ishitani
pp 10801–10803 DOI: 10.1021/ic801527y
Facile Synthesis of Monoazidotitanium Isopropoxides
Sukesh Shekar, Brendan Twamley and Rudolf J. Wehmschulte
pp 10804–10806 DOI: 10.1021/ic8012415
Anion-Controlled Endo- and Exocyclic Disilver(I) Complexes of an S2O3 Macrocycle
Hyun Jee Kim and Shim Sung Lee
pp 10807–10809 DOI: 10.1021/ic801316e
Observation of Ferroelectricity in Paramagnetic Copper Octacyanomolybdate
Kosuke Nakagawa, Hiroko Tokoro and Shin-ichi Ohkoshi
pp 10810–10812 DOI: 10.1021/ic8016563
Anion-Perturbed Magnetic Slow Relaxation in Planar {Dy4} Clusters
Yan-Zhen Zheng, Yanhua Lan, Christopher E. Anson and Annie K. Powell
pp 10813–10815 DOI: 10.1021/ic8016722
Probing the Electronic Communication of the Isocyanide Bridge Through the Luminescence Properties of the d9−d9 [ClPt(μ-dppm)2Pt(CNPCP)]+ and A-Frame [ClPd(μ-dppm)2(μ-CNPCP)PdCl] Complexes
Sbastien Clment, Shawkat Mohammed Aly, Daniel Fortin, Laurent Guyard, Michael Knorr, Alaa S. Abd-El-Aziz and Pierre D. Harvey
pp 10816–10824 DOI: 10.1021/ic800811j
Li14.7Mg36.8Cu21.5Ga66: An Intermetallic Representative of a Type IV Clathrate
Qisheng Lin and John D. Corbett
pp 10825–10831 DOI: 10.1021/ic8003245
A Trinuclear Nickel(II) Enediolate Complex: Synthesis, Characterization, and O2 Reactivity
Katarzyna Rudzka, Atta M. Arif and Lisa M. Berreau
pp 10832–10840 DOI: 10.1021/ic800947z
Theoretical Investigation of One- and Two-Photon Absorption Properties of Platinum Acetylide Chromophores
Zhao-Di Yang, Ji-Kang Feng and Ai-Min Ren
pp 10841–10850 DOI: 10.1021/ic800417g
Photoswitches and Luminescent Rigidity Sensors Based on fac-[Re(CO)3(Me4phen)(L)]+
Antonio Otvio T. Patrocnio and Neyde Y. Murakami Iha
pp 10851–10857 DOI: 10.1021/ic800504a
The Supramolecular Isomerism Based on Argentophilic Interactions: The Construction of Helical Chains with Defined Right-Handed and Left-Handed Helicity
Xiao-Dan Zheng, Long Jiang, Xiao-Long Feng and Tong-Bu Lu
pp 10858–10865 DOI: 10.1021/ic8009578
Magnetostructural Relationship in the Spin-Crossover Complex t-{Fe(abpt)2[N(CN)2]2}: Polymorphism and Disorder Phenomenon
Chou-Fu Sheu, Sbastien Pillet, Yen-Chen Lin, Szu-Miao Chen, I-Jui Hsu, Claude Lecomte and Yu Wang
pp 10866–10874 DOI: 10.1021/ic800879c
Design of Thiolate Rich Metal Binding Sites within a Peptidic Framework
Marek Łuczkowski, Monika Stachura, Virgil Schirf, Borries Demeler, Lars Hemmingsen and Vincent L. Pecoraro
pp 10875–10888 DOI: 10.1021/ic8009817
Selectivity in the Oxidative Addition of C−S Bonds of Substituted Thiophenes to the (C5Me5)Rh(PMe3) Fragment: A Comparison of Theory with Experiment
Tlay A. Atein and William D. Jones
pp 10889–10894 DOI: 10.1021/ic8009892
Neutron Powder Diffraction, Multinuclear, and Multidimensional NMR Structural Investigation of Pb5Ga3F19
Charlotte Martineau, Franck Fayon, Christophe Legein, Jean-Yves Buzar, Franois Goutenoire and Emmanuelle Suard
pp 10895–10905 DOI: 10.1021/ic801044j
Cyclic Boron Clusters Enclosing Planar Hypercoordinate Cobalt, Iron, and Nickel
Keigo Ito, Zhifeng Pu, Qian-Shu Li and Paul von Ragu Schleyer
pp 10906–10910 DOI: 10.1021/ic800993b
Molecular and Electronic Structure of the Square Planar Bis(o-amidobenzenethiolato)iron(III) Anion and Its Bis(o-quinoxalinedithiolato)iron(III) Analogue
Nabarun Roy, Stephen Sproules, Eckhard Bill, Thomas Weyhermller and Karl Wieghardt
pp 10911–10920 DOI: 10.1021/ic801109n
Metal-to-Metal Electron-Transfer Emission in Cyanide-Bridged Chromium−Ruthenium Complexes: Effects of Configurational Mixing Between Ligand Field and Charge Transfer Excited States
Yuan-Jang Chen, Onduru S. Odongo, Patrick G. McNamara, Konrad T. Szacilowski and John F. Endicott
pp 10921–10934 DOI: 10.1021/ic8011266
One- and Two-Electron Reduced 1,2-Diketone Ligands in [CrIII(L)3] (S = 0) and Na2(Et2O)2[VIV(LRed)3] (S = 1/2)
Geoffrey H. Spikes, Stephen Sproules, Eckhard Bill, Thomas Weyhermller and Karl Wieghardt
pp 10935–10944 DOI: 10.1021/ic801122m
Comparison of the Structure and Magnetic Order in a Series of Layered Ni(II) Organophosphonates, Ni[(RPO3)(H2O)] (R = C6H5, CH3, C18H37)
Elvira M. Bauer, Carlo Bellitto, Guido Righini, Marcello Colapietro, Gustavo Portalone, Marc Drillon and Pierre Rabu
pp 10945–10952 DOI: 10.1021/ic801124z
Effect of Charge and Composition on the Structural Fluxionality and Stability of Nine Atom Tin−Bismuth Zintl Analogues
Ujjwal Gupta, Arthur C. Reber, Penee A. Clayborne, Joshua J. Melko, Shiv N. Khanna and A. W. Castleman,
pp 10953–10958 DOI: 10.1021/ic8011712
Room Temperature Antiferromagnetic Order in the Mn(II) Oxide 4H-Ba0.5Sr0.5MnO2+δ
Josephine J. Adkin and Michael A. Hayward
pp 10959–10964 DOI: 10.1021/ic801185z
Application of Symmetry Operation Measures in Structural Inorganic Chemistry
Jorge Echeverra and Santiago Alvarez
pp 10965–10970 DOI: 10.1021/ic801264n
Comparative Behavior of Britholites and Monazite/Brabantite Solid Solutions during Leaching Tests: A Combined Experimental and DFT Approach
E. Veilly, E. du Fou de Kerdaniel, J. Roques, N. Dacheux and N. Clavier
pp 10971–10979 DOI: 10.1021/ic801169d
Synthesis, Electrochemistry, and Photophysical Properties of a Series of Luminescent Pyrene-Thiophene Dyads and the Corresponding Co2(CO)6 Complexes
Anthony Coleman and Mary T. Pryce
pp 10980–10990 DOI: 10.1021/ic801226p
Theoretical Investigation of the Uranyl Ion Sorption on the Rutile TiO2(110) Face
Hadrien Perron, Jrme Roques, Christophe Domain, Romuald Drot, Eric Simoni and Hubert Catalette
pp 10991–10997 DOI: 10.1021/ic801246k
Metalloradical Complexes of Manganese and Chromium Featuring an Oxidatively Rearranged Ligand
Remle elenligil-etin, Patrina Paraskevopoulou, Nikolia Lalioti, Yiannis Sanakis, Richard J. Staples, Nigam P. Rath and Pericles Stavropoulos
pp 10998–11009 DOI: 10.1021/ic801219u
Ruthenium(II) Coordination Chemistry of a Fused Donor−Acceptor Ligand: Synthesis, Characterization, and Photoinduced Electron-Transfer Reactions of [{Ru(bpy)2}n(TTF-ppb)](PF6)2n (n = 1, 2)
Christine Goze, Nathalie Dupont, Elvira Beitler, Claudia Leiggener, Hongpeng Jia, Philippe Monbaron, Shi-Xia Liu, Antonia Neels, Andreas Hauser and Silvio Decurtins
pp 11010–11017 DOI: 10.1021/ic801252t
Construction of Copper Halide-Triiron Selenide Carbonyl Complexes: Synthetic, Electrochemical, and Theoretical Studies
Minghuey Shieh, Chia-Yeh Miu, Chang-Ju Lee, Wei-Cheng Chen, Yen-Yi Chu and Hui-Lung Chen
pp 11018–11031 DOI: 10.1021/ic8012552
An Electrochemical Study of Antineoplastic Gallium, Iron and Ruthenium Complexes with Redox Noninnocent α-N-Heterocyclic Chalcogensemicarbazones
Christian R. Kowol, Erwin Reisner, Ion Chiorescu, Vladimir B. Arion, Markus Galanski, Dirk V. Deubel and Bernhard K. Keppler
pp 11032–11047 DOI: 10.1021/ic8013249
Magnetic Properties and Negative Colossal Magnetoresistance of the Rare Earth Zintl phase EuIn2As2
Andrea M. Goforth, Peter Klavins, James C. Fettinger and Susan M. Kauzlarich
pp 11048–11056 DOI: 10.1021/ic801290u
Structures and Magnetic Properties of Ferromagnetic Coupling 2D Ln−M Heterometallic Coordination Polymers (Ln = Ho, Er; M = Mn, Zn)
Hong-Ling Gao, Bin Zhao, Xiao-Qing Zhao, You Song, Peng Cheng, Dai-Zheng Liao and Shi-Ping Yan
pp 11057–11061 DOI: 10.1021/ic801332a
Oxidative ortho-C-N Fusion of Aniline by OsO4. Isolation, Characterization of Oxo-Amido Osmium(VI) Complexes, and their Catalytic Activities for Oxidative C−C Bond Cleavage of Unsaturated Hydrocarbons
Subhas Samanta, Laksmikanta Adak, Ranjan Jana, Golam Mostafa, Heikki M. Tuononen, Brindaban C. Ranu and Sreebrata Goswami
pp 11062–11070 DOI: 10.1021/ic801352d
Optical Effects of S-Oxidation and Mn+ Binding in meso-Thienyl Dipyrrin Systems and of Stepwise Bromination of 4,4-Difluoro-8-(2,5-dibromo-3-thienyl)-4-bora-3a,4a-diaza-s-indacene
Shin Hei Choi, Kibong Kim, June Jeon, Bhupal Meka, Daniela Bucella, Keliang Pang, Snehadrinarayan Khatua, Junseong Lee and David G. Churchill
pp 11071–11083 DOI: 10.1021/ic801354y
Synthesis and Characterization of Metallomacrocyclic Palladium(II) Complexes with New Hybrid Pyrazole Ligands. Diffusion NMR Studies and Theoretical Calculations
Miguel Guerrero, Josefina Pons, Vicen Branchadell, Teodor Parella, Xavier Solans, Merc Font-Bardia and Josep Ros
pp 11084–11094 DOI: 10.1021/ic8013915
Role of Inner- and Outer-Sphere Bonding in the Sensitization of EuIII-Luminescence Deciphered by Combined Analysis of Experimental Electron Density Distribution Function and Photophysical Data
Lada N. Puntus, Konstantin A. Lyssenko, Mikhail Yu. Antipin and Jean-Claude G. Bünzli
pp 11095–11107 DOI: 10.1021/ic801402u
One-Dimensional Manganese Coordination Polymers Composed of Polynuclear Cluster Blocks and Polypyridyl Linkers: Structures and Properties
Svetlana G. Baca, Iurii L. Malaestean, Tony D. Keene, Harry Adams, Michael D. Ward, Jrg Hauser, Antonia Neels and Silvio Decurtins
pp 11108–11119 DOI: 10.1021/ic8014145
Octa- and Nonanuclear Nickel(II) Polyoxometalate Clusters: Synthesis and Electrochemical and Magnetic Characterizations
Cline Pichon, Pierre Mialane, Anne Dolbecq, Jrme Marrot, Eric Rivire, Bassem S. Bassil, Ulrich Kortz, Bineta Keita, Louis Nadjo and Francis Scheresse
pp 11120–11128 DOI: 10.1021/ic801431f
Cyclometalated Platinum(II) Complexes of Pyrazole-Based, NCN-Coordinating, Terdentate Ligands: the Contrasting Influence of Pyrazolyl and Pyridyl Rings on Luminescence
Stphanie Develay, Octavia Blackburn, Amber L. Thompson and J. A. Gareth Williams
pp 11129–11142 DOI: 10.1021/ic8014157
Synthesis and Characterization of Bismuth(III) and Antimony(III) Calixarene Complexes
Lihua Liu, Lev N. Zakharov, James A. Golen, Arnold L. Rheingold and Tracy A. Hanna
pp 11143–11153 DOI: 10.1021/ic801445m
Tricarbonyl Rhenium(I) Complexes Containing a Bridging 2,5-Diphenyl-1,3,4-oxadiazole Ligand: Structural, Spectroscopic, Electrochemical, and Computational Characterization
Matteo Mauro, Monica Panigati, Daniela Donghi, Pierluigi Mercandelli, Patrizia Mussini, Angelo Sironi and Giuseppe D’Alfonso
pp 11154–11165 DOI: 10.1021/ic801447z
A Novel Ligand Modification and Diamond-core Molybdenum(IV) 2,6-Bis(2,2-diphenyl-2-thioethyl)pyridinate(2-) Complex
Craig Gourlay, Christian J. Doonan, Jonathan M. White and Charles G. Young
pp 11166–11170 DOI: 10.1021/ic8014354
Synthesis, Crystal Structure, Studies in Solution and Cytotoxicity of Two New Fluorescent Platinum(II) Compounds Containing Anthracene Derivatives as a Carrier Ligand
Patricia Marqus-Gallego, Hans den Dulk, Jaap Brouwer, Huub Kooijman, Anthony L. Spek, Olivier Roubeau, Simon J. Teat and Jan Reedijk
pp 11171–11179 DOI: 10.1021/ic8014767
Synthesis, Magnetism, and High-Frequency EPR Spectroscopy of a Family of Mixed-Valent Cuboctahedral Mn13 Complexes with 1,8-Naphthalenedicarboxylate Ligands
Christos Lampropoulos, Changhyun Koo, Stephen O. Hill, Khalil Abboud and George Christou
pp 11180–11190 DOI: 10.1021/ic801484g
Carbonyl Olefination Using Readily Prepared Tungsten Metallacycles
Kapil S. Lokare and Aaron L. Odom
pp 11191–11196 DOI: 10.1021/ic8014964
An Approach to the Synthesis of Polyoxometalate Encapsulating Different Kinds of Oxoanions as Heteroions: Bisphosphitopyrophosphatotriacontamolybdate [(HPO3)2(P2O7)Mo30O90]8−
Sayuri Maeda, Takuya Goto, Masayo Takamoto, Kazuo Eda, Sadayuki Himeno, Hiroki Takahashi and Toshitaka Hori
pp 11197–11201 DOI: 10.1021/ic801499y
Probing Single-Chain Magnets in a Family of Linear Chain Compounds Constructed by Magnetically Anisotropic Metal-Ions and Cyclohexane-1,2-Dicarboxylate Analogues
Yan-Zhen Zheng, Wei Xue, Ming-Liang Tong, Xiao-Ming Chen and Shao-Liang Zheng
pp 11202–11211 DOI: 10.1021/ic801498n
Structural Chemistry and Magnetic Properties of Nd18Li8Fe5O39 and Nd18Li8Co4O39: the Interplay of Cation and Spin Ordering
Sin E. Dutton, Peter D. Battle, Fernande Grandjean, Gary J. Long and Katsuyoshi Oh-ishi
pp 11212–11222 DOI: 10.1021/ic801529m
Synthesis and Characterization of Open-Framework Niobium Silicates: Rb2(Nb2O4)(Si2O6)·H2O and the Dehydrated Phase Rb2(Nb2O4)(Si2O6)
Jhen-Ming Tasi, Po-Tao Tu, Ting-Shan Chan and Kwang-Hwa Lii
pp 11223–11227 DOI: 10.1021/ic801525d
Properties of Square-Pyramidal Alkyl−Thiolate FeIII Complexes, Including an Analogue of the Unmodified Form of Nitrile Hydratase
Priscilla Lugo-Mas, Wendy Taylor, Dirk Schweitzer, Roslyn M. Theisen, Liang Xu, Jason Shearer, Rodney D. Swartz, Morgan C. Gleaves, Antonio DiPasquale, Werner Kaminsky and Julie A. Kovacs
pp 11228–11236 DOI: 10.1021/ic801704n
Synthesis, Structure, and Bonding of the Zintl Phase Ba3Cd2Sb4
Bayrammurad Saparov, Sheng-qing Xia and Svilen Bobev
pp 11237–11244 DOI: 10.1021/ic801530d
Investigation of Silver-Containing Layered Materials and Their Interactions with Primary Amines Using Solid-State 109Ag and 15N NMR Spectroscopy and First Principles Calculations
Hiyam Hamaed, Andy Y. H. Lo, Leslie J. May, Jared M. Taylor, George H. Shimizu and Robert W. Schurko
pp 11245–11256 DOI: 10.1021/ic801549p
Second-Order Self-Organization in Coordination-Driven Self-Assembly: Exploring the Limits of Self-Selection
Brian H. Northrop, Hai-Bo Yang and Peter J. Stang
pp 11257–11268 DOI: 10.1021/ic801711q
The Creutz−Taube Complex Revisited: DFT Study of the Infrared Frequencies
Teodora Todorova and Bernard Delley
pp 11269–11277 DOI: 10.1021/ic8018748
A Fluorinated Ruthenium Porphyrin as a Potential Photodynamic Therapy Agent: Synthesis, Characterization, DNA Binding, and Melanoma Cell Studies
Sandya Rani-Beeram, Kyle Meyer, Anna McCrate, Yiling Hong, Mark Nielsen and Shawn Swavey
pp 11278–11283 DOI: 10.1021/ic8015589
When Arsine Makes the Difference: Chelating Phosphino and Bridging Arsinoarylthiolato Gallium Complexes
Ana Maria Vlean, Santiago Gmez-Ruiz, Peter Lnnecke, Ioan Silaghi-Dumitrescu, Luminia Silaghi-Dumitrescu and Evamarie Hey-Hawkins
pp 11284–11293 DOI: 10.1021/ic801582b
A Multifrequency HYSCORE Study of Weakly Coupled Nuclei in Frozen Solutions of High-Spin Aquometmyoglobin
Ins Garca-Rubio, Maria Fittipaldi, Florin Trandafir and Sabine Van Doorslaer
pp 11294–11304 DOI: 10.1021/ic8016886
Synthesis of N-Confused Tetraphenylporphyrin Rhodium Complexes Having Versatile Metal Oxidation States
Alagar Srinivasan, Motoki Toganoh, Teppei Niino, Atsuhiro Osuka and Hiroyuki Furuta
pp 11305–11313 DOI: 10.1021/ic061093+
Reversible Core-Interconversion of an Iron(III) Dihydroxo Bridged Complex
Athanassios K. Boudalis, Juan Modesto Clemente-Juan, Franoise Dahan, Vassilis Psycharis, Catherine P. Raptopoulou, Bruno Donnadieu, Yiannis Sanakis and Jean-Pierre Tuchagues
pp 11314–11323 DOI: 10.1021/ic800716r
Halide LigandsMore Than Just σ-Donors? A Structural and Spectroscopic Study of Homologous Organonickel Complexes
Axel Klein, Andr Kaiser, Wolfram Wielandt, Ferdinand Belaj, Eric Wendel, Helmut Bertagnolli and Stanislav Zli
pp 11324–11333 DOI: 10.1021/ic8007365
PtII-Promoted [2 + 3] Cycloaddition of Azide to Cyanopyridines: Convenient Tool toward Heterometallic Structures
Suman Mukhopadhyay, Bhaswati Ghosh Mukhopadhyay, M. Ftima C. Guedes da Silva, Jamal Lasri, M. Adlia Janurio Charmier and Armando J. L. Pombeiro
pp 11334–11341 DOI: 10.1021/ic8014223
Ruthenium(II)-Polyazine Light Absorbers Bridged to Reactive cis-Dichlororhodium(III) Centers in a Bimetallic Molecular Architecture
David F. Zigler, Jing Wang and Karen J. Brewer
pp 11342–11350 DOI: 10.1021/ic8007602
Synthesis, Characterization, and Sorption Properties of Amorphous Titanium Phosphate and Silica-Modified Titanium Phosphates
Marina V. Maslova, Daniela Rusanova, Valeri Naydenov, Oleg N. Antzutkin and Lidia G. Gerasimova
pp 11351–11360 DOI: 10.1021/ic801274z
Oxidation of Catechin and Rutin by Pentaammineruthenium(III) Complexes
Jay Sung, Kai-Sheng Huang, Tan-Ju Lai, Yu-Yi Chen, Chih-Yeh Lin, Andrew Yeh and Dacheng Wu
pp 11361–11366 DOI: 10.1021/ic801419k
Synthesis and Structural Characterization of Tin Analogues of N-Heterocyclic Carbenes
Stephen M. Mansell, Christopher A. Russell and Duncan F. Wass
pp 11367–11375 DOI: 10.1021/ic801479g
Lanthanide Metallocene Complexes of the 1,3,4,6,7,8-Hexahydro-2H-pyrimido[1,2-a]pyrimidinato Ligand, (hpp)1−
William J. Evans, Elizabeth Montalvo, Dustin J. Dixon, Joseph W. Ziller, Antonio G. DiPasquale and Arnold L. Rheingold
pp 11376–11381 DOI: 10.1021/ic801029v
Reactivity of a Sterically Hindered Fe(II) Thiolate Dimer with Amines and Hydrazines
Michael J. Zdilla, Atul K. Verma and Sonny C. Lee
pp 11382–11390 DOI: 10.1021/ic801349y
Gold(I) Complexes with Hydrogen-Bond Supported Heterocyclic Carbenes as Active Catalysts in Reactions of 1,6-Enynes
Camino Bartolom, Zoraida Ramiro, Patricia Prez-Galn, Christophe Bour, Mihai Raducan, Antonio M. Echavarren and Pablo Espinet
pp 11391–11397 DOI: 10.1021/ic801446v
2,2,6,6-Tetramethylpiperidinogallium as a Terminal and Bridging Ligand in Homo- and Heteroleptic Chromium, Nickel, and Cobalt Complexes
Annekathrin Seifert and Gerald Linti
pp 11398–11404 DOI: 10.1021/ic801437n
Synthesis, Characterization, and Thermal Properties of Homoleptic Rare-Earth Guanidinates: Promising Precursors for MOCVD and ALD of Rare-Earth Oxide Thin Films
Andrian P. Milanov, Roland A. Fischer and Anjana Devi
pp 11405–11416 DOI: 10.1021/ic801432b
Cleavage of the Indium(III) Octaethyloxophlorin Dimer, {InIII(OEPO)}2, with Lewis Bases. Importance of Outer-Sphere Hydrogen Bonding in Adduct Structures
Thelma Y. Garcia, Marilyn M. Olmstead, James C. Fettinger and Alan L. Balch
pp 11417–11422 DOI: 10.1021/ic801605b
Electrochemical and Spectroscopic Characterization of a Series of Mixed-Ligand Diruthenium Compounds
Karl M. Kadish, Rachel Garcia, Tuan Phan, Julien Wellhoff, Eric Van Caemelbecke and John L. Bear
pp 11423–11428 DOI: 10.1021/ic8017369
Catalytic Desulfurization of Dibenzothiophene with Palladium Nanoparticles
Jorge Torres-Nieto, Alma Arvalo and Juventino J. Garca
pp 11429–11434 DOI: 10.1021/ic801550j
Monoanionic {Mn(NO)}5 and Dianionic {Mn(NO)}6 Thiolatonitrosylmanganese Complexes: [(NO)Mn(L)2] and [(NO)Mn(L)2]2− (LH2 = 1,2-Benzenedithiol and Toluene-3,4-dithiol)
Chia-Huei Lin, Chien-Ge Chen, Ming-Li Tsai, Gene-Hsiang Lee and Wen-Feng Liaw
pp 11435–11443 DOI: 10.1021/ic801553s
Syntheses, X-ray Structures, Solid State High-Field Electron Paramagnetic Resonance, and Density-Functional Theory Investigations on Chloro and Aqua MnII Mononuclear Complexes with Amino-Pyridine Pentadentate Ligands
Christelle Hureau, Sihem Groni, Rgis Guillot, Genevive Blondin, Carole Duboc and Elodie Anxolabhre-Mallart
p 11444 DOI: 10.1021/ic801943n

Issue 24


Hierarchically Ordered Homochiral Metal−Organic Frameworks Built from Exceptionally Large Rectangles and Squares
Chuan-De Wu, Liqing Ma and Wenbin Lin
pp 11446–11448 DOI: 10.1021/ic800514f
Vibrational Assignments of Six-Coordinate Ferrous Heme Nitrosyls: New Insight from Nuclear Resonance Vibrational Spectroscopy
Florian Paulat, Timothy C. Berto, Serena DeBeer George, Lauren Goodrich, V. K. K. Praneeth, Corinne D. Sulok and Nicolai Lehnert
pp 11449–11451 DOI: 10.1021/ic801626w
Emissive Chromium(III) Complexes with Substituted Arylethynyl Ligands
David L. Grisenti, W. Walsh Thomas, Christopher R. Turlington, Matthew D. Newsom, Christopher J. Priedemann, Donald G. VanDerveer and Paul S. Wagenknecht
pp 11452–11454 DOI: 10.1021/ic801376p
Bond Length and Bond Order in One of the Shortest Cr−Cr Bonds
Giovanni La Macchia, Francesco Aquilante, Valera Veryazov, Bjrn O. Roos and Laura Gagliardi
pp 11455–11457 DOI: 10.1021/ic801537w
Proton-Coupled Electron-Transfer Oxidation of Phenols by Hexachloroiridate(IV)
Na Song and David M. Stanbury
pp 11458–11460 DOI: 10.1021/ic8015595
Synthesis, Characterization, and O2 Reactivity of Iridium(I) Complexes Supported by Guanidinato Ligands
Jan-Uwe Rohde, Matthew R. Kelley and Wei-Tsung Lee
pp 11461–11463 DOI: 10.1021/ic801867r
Dimensional Caging of Polyiodides
Per H. Svensson, Mikhail Gorlov and Lars Kloo
pp 11464–11466 DOI: 10.1021/ic801820s
Putting Group 13 Elements onto Perylenes: Highly Fluorescent N−B−N- and N−Al−N-substituted Polycyclic Aromatics
Till Riehm, Hubert Wadepohl and Lutz H. Gade
pp 11467–11469 DOI: 10.1021/ic8017453
The Contrasting Chemistry and Cancer Cell Cytotoxicity of Bipyridine and Bipyridinediol Ruthenium(II) Arene Complexes
Tijana Bugarcic, Abraha Habtemariam, Jana Stepankova, Pavla Heringova, Jana Kasparkova, Robert J. Deeth, Russell D. L. Johnstone, Alessandro Prescimone, Andrew Parkin, Simon Parsons, Viktor Brabec and Peter J. Sadler
pp 11470–11486 DOI: 10.1021/ic801361m
Novel Tailoring Reaction for Two Adjacent Coordinated Nitriles Giving Platinum 1,3,5-Triazapentadiene Complexes
Pavel V. Gushchin, Marina R. Tyan, Nadezhda A. Bokach, Mikhail D. Revenco, Matti Haukka, Meng-Jiy Wang, Cheng-Hsuan Lai, Pi-Tai Chou and Vadim Yu. Kukushkin
pp 11487–11500 DOI: 10.1021/ic702483w
Synthesis, Structures, and Luminescence Properties of Lanthanide Complexes with Structurally Related New Tetrapodal Ligands Featuring Salicylamide Pendant Arms
Xueqin Song, Xiaoyan Zhou, Weisheng Liu, Wei Dou, Jingxin Ma, Xiaoliang Tang and Jiangrong Zheng
pp 11501–11513 DOI: 10.1021/ic8008267
A Noncentrosymmetric 3D Coordination Polymer of Metallocalix[4]arene
Yu-Juan Liu, Jie-Sheng Huang, Stephen Sin-Yin Chui, Cheng-Hui Li, Jing-Lin Zuo, Nianyong Zhu and Chi-Ming Che
pp 11514–11518 DOI: 10.1021/ic8008859
Photochemical Reactions of fac-[Mn(CO)3(phen)imidazole]+: Evidence for Long-Lived Radical Species Intermediates
Inara de Aguiar, Simone D. Inglez, Francisco C. A. Lima, Juliana F. S. Daniel, Bruce R. McGarvey, Antnio C. Tedesco and Rose M. Carlos
pp 11519–11526 DOI: 10.1021/ic8002004
Lanthanide Complexes of the Heterochiral Nonaaza Macrocycle: Switching the Orientation of the Helix Axis
Janusz Gregoliski, Tadeusz Lis, Marta Cyganik and Jerzy Lisowski
pp 11527–11534 DOI: 10.1021/ic8005986
Tossing and Turning: Guests in the Flexible Frameworks of Metal(III) Dicarboxylates
Marie Vougo-Zanda, Jin Huang, Ekaterina Anokhina, Xiqu Wang and Allan J. Jacobson
pp 11535–11542 DOI: 10.1021/ic800008f
Geometric Structure Determination of N694C Lipoxygenase: A Comparative Near-Edge X-Ray Absorption Spectroscopy and Extended X-Ray Absorption Fine Structure Study
Ritimukta Sarangi, Rosalie K. Hocking, Michael L. Neidig, Maurizio Benfatto, Theodore R. Holman, Edward I. Solomon, Keith O. Hodgson and Britt Hedman
pp 11543–11550 DOI: 10.1021/ic800580f
Self-Assembly of Electroactive Thiacrown Ruthenium(II) Complexes into Hydrogen-Bonded Chain and Tape Networks
Naz Shan, Samuel M. Hawxwell, Harry Adams, Lee Brammer and Jim A. Thomas
pp 11551–11560 DOI: 10.1021/ic8007359
Synthesis and Characterization of Cyclotriphosphazenes Containing Silicon as Single Solid-State Precursors for the Formation of Silicon/Phosphorus Nanostructured Materials
Carlos Daz, Maria Luisa Valenzuela, Daniel Bravo, Vladimir Lavayen and Colm O’Dwyer
pp 11561–11569 DOI: 10.1021/ic8009805
Group VIII Coordination Chemistry of a Pincer-Type Bis(8-quinolinyl)amido Ligand
Theodore A. Betley, Baixin A. Qian and Jonas C. Peters
pp 11570–11582 DOI: 10.1021/ic801047s
Computational Density Functional Study of Polypyrrolic Macrocycles: Analysis of Actinyl-Oxo to 3d Transition Metal Bonding
Joel J. Berard and Georg Schreckenbach, Polly L. Arnold, Dipti Patel and Jason B. Love
pp 11583–11592 DOI: 10.1021/ic8010772
Synthesis and Intramolecular and Interionic Structural Characterization of Half-Sandwich (Arene)Ruthenium(II) Derivatives of Bis(Pyrazolyl)Alkanes
Fabio Marchetti, Claudio Pettinari, Riccardo Pettinari, Adele Cerquetella, Corrado Di Nicola, Alceo Macchioni, Daniele Zuccaccia, Magda Monari and Fabio Piccinelli
pp 11593–11603 DOI: 10.1021/ic801150c
Facile Ligand Oxidation and Ring Nitration in Ruthenium Complexes Derived from a Ligand with Dicarboxamide-N and Phosphine-P Donors
Nicole L. Fry, Michael J. Rose, Crystal Nyitray and Pradip K. Mascharak
pp 11604–11610 DOI: 10.1021/ic801243a
Rare Example of μ-Nitrito-1κ2O,O′:2κO Coordinating Mode in Copper(II) Nitrite Complexes with Monoanionic Tridentate Schiff Base Ligands: Structure, Magnetic, and Electrochemical Properties
Biswarup Sarkar, Sanjit Konar, Carlos J. Gmez-Garca and Ashutosh Ghosh
pp 11611–11619 DOI: 10.1021/ic8011519
Targeted Oxidase Reactivity with a New Redox-Active Ligand Incorporating N2O2 Donor Atoms. Complexes of Cu(II), Ni(II), Pd(II), Fe(III), and V(V)
Chandan Mukherjee, Thomas Weyhermller, Eberhard Bothe and Phalguni Chaudhuri
pp 11620–11632 DOI: 10.1021/ic8011734
Mixed Valence Creutz−Taube Ion Analogues Incorporating Thiacrowns: Synthesis, Structure, Physical Properties, and Computational Studies
Harry Adams, Paulo J. Costa, Mike Newell, Steven J. Vickers, Michael D. Ward, Vtor Flix and Jim A. Thomas
pp 11633–11643 DOI: 10.1021/ic801193r
Large Amplitude, Proton- and Cation-Activated Latch-Type Mechanical Switches: O-Protonated Amides Stabilized by Intramolecular, Low-Barrier Hydrogen Bonds within Macrocycles
Mariappan Kadarkaraisamy, Gerald Caple, Andrea R. Gorden, Marie A. Squire and Andrew G. Sykes
pp 11644–11655 DOI: 10.1021/ic801238a
Circular Dichroism of Trigonal Dihedral Chromium(III) Complexes: A Theoretical Study based on Open-Shell Time-Dependent Density Functional Theory
Jing Fan, Michael Seth, Jochen Autschbach and Tom Ziegler
pp 11656–11668 DOI: 10.1021/ic801229c
Dimanganese and Diiron Complexes of a Binucleating Cyclam Ligand: Four-Electron, Reversible Oxidation Chemistry at High Potentials
Louise A. Berben and Jonas C. Peters
pp 11669–11679 DOI: 10.1021/ic801289x
β-Nitro Derivatives of Germanium(IV) Corrolates
Marco Mastroianni, Weihua Zhu, Manuela Stefanelli, Sara Nardis, Frank R. Fronczek, Kevin M. Smith, Zhongping Ou, Karl M. Kadish and Roberto Paolesse
pp 11680–11687 DOI: 10.1021/ic801421a
Electronic Structure of a Binuclear Nickel Complex of Relevance to [NiFe] Hydrogenase
Maurice van Gastel, Jennifer L. Shaw, Alexander J. Blake, Marco Flores, Martin Schrder, Jonathan McMaster and Wolfgang Lubitz
pp 11688–11697 DOI: 10.1021/ic801383x
Vanadium(V) Compounds with the Bis-(hydroxylamino)-1,3,5-triazine Ligand, H2bihyat: Synthetic, Structural, and Physical Studies of [V2VO3(bihyat)2] and of the Enhanced Hydrolytic Stability Species cis-[VVO2(bihyat)]
Vladimiros A. Nikolakis, John T. Tsalavoutis, Marios Stylianou, Evgenios Evgeniou, Tamas Jakusch, Artem Melman, Michael P. Sigalas, Tamas Kiss, Anastasios D. Keramidas and Themistoklis A. Kabanos
pp 11698–11710 DOI: 10.1021/ic801411x
Dinuclear Zinc Complexes Using Pentadentate Phenolate Ligands
Paul D. Knight, Andrew J. P. White and Charlotte K. Williams
pp 11711–11719 DOI: 10.1021/ic8014173
Organometallic and Conjugated Organic Polymers Held Together by Strong Electrostatic Interactions to Form Luminescent Hybrid Materials
Diana Bellows, milie Gingras, Shawkat M. Aly, Alaa S. Abd-El-Aziz, Mario Leclerc and Pierre D. Harvey
pp 11720–11733 DOI: 10.1021/ic801461j
A Mixed-Valence Octanuclear Iron−Oxo Pyrazolate: Assessment of Electronic Delocalization by Structural and Spectroscopic Analysis
Indranil Chakraborty, Peter Baran, Yiannis Sanakis, Athanassios Simopoulos, Esteban Fachini and Raphael G. Raptis
pp 11734–11737 DOI: 10.1021/ic801459s
Application of Electron Microscopy in the Observation of Technetium and Technetium Dioxide Nanostructures
G. W. Chinthaka Silva, Frederic Poineau, Longzhou Ma and Kenneth R. Czerwinski
pp 11738–11744 DOI: 10.1021/ic8014628
One- and Two-Electron Reduced 1,2-Diketone Ligands in [ZnII(L)2(Et2O)], [CoII(L)2(Et2O)], and Na2(Et2O)4[CoII(LRed)2]
Geoffrey H. Spikes, Carsten Milsmann, Eckhard Bill, Thomas Weyhermller and Karl Wieghardt
pp 11745–11754 DOI: 10.1021/ic801470p
Synthesis, Molecular Structures, and Reactivity of Mono- and Binuclear Neutral Copper(I) Carbenes
Peter Hofmann, Igor V. Shishkov and Frank Rominger
pp 11755–11762 DOI: 10.1021/ic801443y
Mononuclear Ruthenium(II) Complexes That Catalyze Water Oxidation
Huan-Wei Tseng, Ruifa Zong, James T. Muckerman and Randolph Thummel
pp 11763–11773 DOI: 10.1021/ic8014817
The Crystal Chemistry of Ferric Oxyhydroxyapatite
H. R. Low, N. Phonthammachai, A. Maignan, G. A. Stewart, T. J. Bastow, L. L. Ma and T. J. White
pp 11774–11782 DOI: 10.1021/ic801491t
Characterizations of Chloro and Aqua Mn(II) Mononuclear Complexes with Amino-Pyridine Ligands. Comparison of Their Electrochemical Properties With Those of Fe(II) Counterparts
Sihem Groni, Christelle Hureau, Rgis Guillot, Genevive Blondin, Guillaume Blain and Elodie Anxolabhre-Mallart
pp 11783–11797 DOI: 10.1021/ic8015172
Lewis-Acid-Assisted Methyl Exchange Reactions In Silylated Aminodichloroarsanes
Dirk Michalik, Axel Schulz and Alexander Villinger
pp 11798–11806 DOI: 10.1021/ic801526n
A Continuous Symmetry Measure of [4Fe−4S]+ Core Distortions and Analysis of Supramolecular Synthons in Crystal Structures of (Et4N)3[Fe4S4Cl4]·Et4NCl at 100 and 295 K
Karl S. Hagen and Mohammad Uddin
pp 11807–11815 DOI: 10.1021/ic801533q
New Nitrosyl Derivatives of Diiron Dithiolates Related to the Active Site of the [FeFe]-Hydrogenases
Matthew T. Olsen, Aaron K. Justice, Frdric Gloaguen, Thomas B. Rauchfuss and Scott R. Wilson
pp 11816–11824 DOI: 10.1021/ic801542w
Unusual Structural Types in Nickel Cluster Chemistry from the Use of Pyridyl Oximes: Ni5, Ni12Na2, and Ni14 Clusters
Theocharis C. Stamatatos, Albert Escuer, Khalil A. Abboud, Catherine P. Raptopoulou, Spyros P. Perlepes and George Christou
pp 11825–11838 DOI: 10.1021/ic801555e
Observation of Staging during Intercalation in Layered α-Cobalt Hydroxides: A Synthetic and Kinetic Study
Yi Du and Dermot O’Hare
pp 11839–11846 DOI: 10.1021/ic801639e
Mimicking the Intradiol Catechol Cleavage Activity of Catechol Dioxygenase by High-Spin Iron(III) Complexes of a New Class of a Facially Bound [N2O] Ligand
Manas K. Panda, Alex John, Mobin M. Shaikh and Prasenjit Ghosh
pp 11847–11856 DOI: 10.1021/ic801576f
Carba-closo-dodecaborates with One or Two Alkynyl Substituents Bonded to Boron
Maik Finze
pp 11857–11867 DOI: 10.1021/ic801610b
An Exploration of the Coupling Reactions of Epoxides and Carbon Dioxide Catalyzed by Tetramethyltetraazaannulene Chromium(III) Derivatives: Formation of Copolymers versus Cyclic Carbonates
Donald J. Darensbourg and Shawn B. Fitch
pp 11868–11878 DOI: 10.1021/ic801728e
Probing the Chemistry, Electronic Structure and Redox Energetics in Organometallic Pentavalent Uranium Complexes
Christopher R. Graves, Anthony E. Vaughn, Eric J. Schelter, Brian L. Scott, Joe D. Thompson, David E. Morris and Jaqueline L. Kiplinger
pp 11879–11891 DOI: 10.1021/ic8017375
The Kagom Topology of the Gallium and Indium Metal-Organic Framework Types with a MIL-68 Structure: Synthesis, XRD, Solid-State NMR Characterizations, and Hydrogen Adsorption
Christophe Volkringer, Mohamed Meddouri, Thierry Loiseau, Nathalie Guillou, Jrme Marrot, Grard Frey, Mohamed Haouas, Francis Taulelle, Nathalie Audebrand and Michel Latroche
pp 11892–11901 DOI: 10.1021/ic801624v
Tetradentate Bis(hydroxamate) and Hydroxamate-Diketonate Ligands and Their Titanium(IV) Complexes
Natcharee Kongprakaiwoot, Bruce C. Noll and Seth N. Brown
pp 11902–11909 DOI: 10.1021/ic8016479
Effects of Metal Coordination Geometry on Stabilization of Human Telomeric Quadruplex DNA by Square-Planar and Square-Pyramidal Metal Complexes
Anna Arola-Arnal, Jordi Benet-Buchholz, Stephen Neidle and Ramn Vilar
pp 11910–11919 DOI: 10.1021/ic8016547
Straightforward Route to the Adamantane Clusters [Sn4Q10]4− (Q = S, Se, Te) and Use in the Assembly of Open-Framework Chalcogenides (Me4N)2M[Sn4Se10] (M = MnII, FeII, CoII, ZnII) Including the First Telluride Member (Me4N)2Mn[Ge4Te10]
Konstantina Tsamourtzi, Jung-Hwan Song, Thomas Bakas, Arthur J. Freeman, Pantelis N. Trikalitis and Mercouri G. Kanatzidis
pp 11920–11929 DOI: 10.1021/ic801762h
Structures and Physical Properties of Rare-Earth Zinc Antimonides Pr6Zn1+xSb14+y and RE6Zn1+xSb14 (RE = Sm, Gd−Ho)
Yi Liu, Ling Chen, Long-Hua Li and Li-Ming Wu, Oksana Ya. Zelinska and Arthur Mar
pp 11930–11941 DOI: 10.1021/ic800524d
Reactivity of the Oxime/Oximato Group in Ruthenium(II) Complexes
Sanjay Kumar Singh, Sanjeev Sharma, Sudhakar Dhar Dwivedi, Ru-Qiang Zou, Qiang Xu and Daya Shankar Pandey
pp 11942–11949 DOI: 10.1021/ic8009699
Controlled Solvothermal Synthesis of Nanosheets, Nanobelts, and Ultralong Nanobelt Arrays with Honeycomb-Like Micropatterns of ZnSe on Zinc Substrate
Lihui Zhang, Heqing Yang, Li Li, Ruigang Zhang, Ruini Liu, Junhu Ma, Xiaoli Xie and Fei Gao
pp 11950–11957 DOI: 10.1021/ic801054e
Real-Space Pairing through Charge Transfer Excitons in High-TC Cuprates
Michel Pouchard, Jean-Pierre Doumerc and Antoine Villesuzanne
pp 11958–11964 DOI: 10.1021/ic801266q
Cu2+-Controlled Hybridization of Peptide Nucleic Acids
Jnos Kovcs, Elmar Jentzsch and Andriy Mokhir
pp 11965–11971 DOI: 10.1021/ic8012377
Technetium and Rhenium in Five-Coordinate Symmetrical and Dissymmetrical Nitrido Complexes with Alkyl Phosphino-thiol Ligands. Synthesis and Structural Characterization
Cristina Bolzati, Mario Cavazza-Ceccato, Stefania Agostini, Francesco Tisato and Giuliano Bandoli
pp 11972–11983 DOI: 10.1021/ic801436d
Synthesis of Zinc Hydrazonide Complexes
Saba Javed and David M. Hoffman
pp 11984–11992 DOI: 10.1021/ic801451v
Silyl-Substituted Thioether Ligands and Their Ag(I) Complexes
Chinwon Rim, Hongming Zhang and David Y. Son
pp 11993–12003 DOI: 10.1021/ic801580t
Experimental and Theoretical Characterization of the Hexaazidophosphate(V) Ion
P. Portius, P. W. Fowler, H. Adams and T. Z. Todorova
pp 12004–12009 DOI: 10.1021/ic801536z
Syntheses, Structures, and Reactivities of Novel Palladium β-Diiminato−Acetate Complexes
Alen Hadzovic and Datong Song
pp 12010–12017 DOI: 10.1021/ic801557c
Nitridogermanate Nitrides Sr7[GeN4]N2 and Ca7[GeN4]N2: Synthesis Employing Sodium Melts, Crystal Structure, and Density-Functional Theory Calculations
Sebastian C. Junggeburth, Oliver Oeckler, Dirk Johrendt and Wolfgang Schnick
pp 12018–12023 DOI: 10.1021/ic801562c
Analysis of the Critical Step in Catalytic Carbodiimide Transformation: Proton Transfer from Amines, Phosphines, and Alkynes to Guanidinates, Phosphaguanidinates, and Propiolamidinates with Li and Al Catalysts
Christopher N. Rowley, Tiow-Gan Ong, Jessica Priem, Darrin S. Richeson and Tom K. Woo
pp 12024–12031 DOI: 10.1021/ic801739a
H2O2-Reactivity of Copper(II) Complexes Supported by Tris[(pyridin-2-yl)methyl]amine Ligands with 6-Phenyl Substituents
Atsushi Kunishita, Minoru Kubo, Hirohito Ishimaru, Takashi Ogura, Hideki Sugimoto and Shinobu Itoh
pp 12032–12039 DOI: 10.1021/ic801568g
Organozinc Aminoalcoholates: Synthesis, Structure, and Materials Chemistry
Andrew L. Johnson, Nathan Hollingsworth, Gabriele Kociok-Khn and Kieran C. Molloy
pp 12040–12048 DOI: 10.1021/ic801591d
Synthesis, Structures and Reactivity of Group 4 Hydrazido Complexes Supported by Calix[4]arene Ligands
Andrew J. Clulow, Jonathan D. Selby, Michael G. Cushion, Andrew D. Schwarz and Philip Mountford
pp 12049–12062 DOI: 10.1021/ic801735c